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File Name: espi-metals_com---molybdenumcarbonyl.asp
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MATERIAL SAFETY DATA SHEET


I PRODUCT IDENTIFICATION

Molybdenum Carbonyl Mo(CO) 6
Trade Name: Form ula:
Hexacarbonyl molybdenum
Synonyms:


II HAZAR DOUS INGRED IENTS

Haz ardous C omp onents % OSHA/PEL ACGIH/TLV
5 m g(M o)/m 3 5 m g(M o)/m 3
Molybdenum Carbonyl 0-100


III PHYSICAL DATA

156.4 oC 150 oC (dec om poses)
Boiling Point: Melting Point:
N/A 1.96 g/cc
Vapo r Density: Specific Gravity:
Colorless crystals to white powd er. Insoluble
Appearance and Odor: Solubility in H 2O:


IV FIRE AND EXPLOSION H AZARDS DATA

Flash Point (Method Used): N/A Autoignition Temperature: N/A
Flam mab le Limits: Upper: N/A Lower: N/A

Extingu ishing Media: CO2, sand, extinguishing po wder. Do not use water.
Special Fire Fighting Procedures: Firefighters m ust w ear fu ll face, self-con tained breathing apparatus and full pro tective clothing to
prevent contact with skin and eyes. Isolate runoff to prevent environmental pollution.

Unusual Fire and Explosion Hazards: Liberates carbon monoxide upon decomposition.


V HEALTH HAZARD INFORMATION

Effects of Over Expo sure:

To the best of our knowledge the acute and chronic toxicity of molybdenum carbonyl has not been thoroughly investigated
and reported.

Acute m olyb den um poiso ning ma y cau se severe gastroin testinal irritation, diarrhe a, com a and death from cardiac failure.
Chronic molybdenum poisoning in laboratory animals has caused loss of weight, anorexia, anemia, deficient lactation, male sterility,
osteoporosis and bone joint abnorm alities.

Carbonyl compoun ds are toxic due to decomposition yielding carbon mo noxide. Symptoms include asphyxia, headache,
me ntal co nfusion, d izziness, imp airm ent of vision and hearing, and fainting . High exposures can result in unco nscio usness and death
due to th e inability of he mo globin to carry oxygen to the tissues.
Acute E ffects:

Inhalation: Toxic by inhalation.
Ingestion: Toxic by ingestion.
Skin : Irritating to skin and mucous mem branes
Eye: Irritating

Carcino genicity: No data found

EMERG ENCY AND FIRST AID PROCEDURES:

INHALATION: Remove to fresh air. If required, provide artificial respiration. Keep patient warm; seek immediate medical advice.
INGESTION: Do not induce vomiting. Immediately call for medical help. Seek imm ediate medical advice.
SK IN: Immediately wash with soap and water and rinse thoroughly. Seek immediate medical advice.
EYE: Flush with water for at least 15 m inutes, including un der eyelids. Consult a doctor.


V REACTIVITY DATA

Stability: Stable

Conditions to be Avoided: To avoid therm al decom position do no t overheat.
Incompatibility (Materials to be Avoided): Oxidizing agents, halogens, bases.

Haz ardous D ecomposition Produc ts: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.


VII SPILL OR LEAK PROC EDURES

Steps to Be Taken in Case Material Is Released or Spilled: Wear protective equipm ent. Keep unp rotected persons away. En sure
adequate ventilation. Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Use sand or vermiculite.

Waste Disposal Method: Dispose o f in accord ance w ith all State, Federal and Lo cal regulation s.


VIII SPECIAL PROTECTION INFORMATION

Respiratory Protection: NIOSH /MSH A app roved filter - dust, fume, m ist. Use suitable respirator when high concen trations are
prese nt.
Ventilation: Use lo cal exhau st.

Eye Protection: Safety glasses.
Protective Gloves: Impe rious glov es.

Other Protective Equipment: Protective work clothing

IX SPECIAL PRECAUTIONS

Precautions to Be Taken in Handling and Storage: Handle under dry protective gas. Keep container tightly sealed. Store in a
cool, dry place in tightly closed containers. Ensure good ventilation at the workplace. Open and handle container with care.

Other Precautions: Store und er dry inert gas. Pro tect from h eat and dire ct sunlight. K eep container tightly sealed . Store in cool,
dry conditions in well sealed containers. Store und er lock and key and w ith access restricted to techn ical experts o r their assistants
only . Store away fro m o xidizing agen ts. Do not sto re tog ether with alkalies (caustic solutions). S tore away from h alogens.
Flam ma ble. K eep ignition sou rces away. Pro tect from h eat.

Wo rk Practices: The usual preca utionary mea sures for handling chem icals should be follow ed. Keep aw ay from foodstuffs,

-Molybdenum Carbonyl 2-
bev erages and feed. Remo ve all so iled an d contam inated clothing im me diately . Wa sh ha nds befo re bre aks and at the en d of wo rk.
Store protective clothing separately. Maintain eyewash capable of sustained flushing, safety drench shower and facilities for washing.

TSCA: Listed

The abo ve inform ation is believ ed to be co rrect, but do es no t purp ort to b e all inclu sive an d sha ll be used only as a gu ide.
ESPI shall not be held liab le for any d am age resulting from h and ling o r from contact with the abov e pro duc t.


Issued by: S. Dierks
Date: July 2001




-Molybdenum Carbonyl 3-

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