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File Name: espi-metals_com---osmium.asp
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MATERIAL SAFETY DATA SHEET


I PRODUCT IDENTIFICATION

Osmium Metallic element
Trade Name: Chem ical Nature:
Os 7440-0 4-2
Molecu lar F orm ula: CAS #:


II HAZAR DOUS INGRED IENTS

Haz ardous C omp onents % OSHA/PEL ACGIH/TLV
Osmium 0-100 N/E N/E


III PHYSICAL DATA

5027 oC 3045 oC
Boiling Point: Melting Point:
N/A Essentially 0
Vapo r Density: Vapor Pressure:
22.6 gm/cc 0
Specific Gravity: % V olatiles:
Bluish-white metal, no odo r. Insoluble
Appearance and Odor: Solubility in H 2O:


IV FIRE AND EXPLOSION H AZARDS DATA

Flash Point: N/A Autoignition Temperature: No data
Flam mab le Limits: Upper: N/A Lower: N/A

Extingu ishing Media: Flamma ble solid. If involved in a fire do not use water, carbon d ioxide or halogenated ex tinguishers. Use dry
chemical extinguishing agents, dry sand or dry ground dolomite.
Special Fire Fighting Procedures: Firefighters must wear NIOSH/MSHA approved self contained breathing apparatus, flame and
chemical resistant clothing; hats, boots and gloves. If without risk, remove material from fire area.

Unusual Fire and Explosion Hazards: May emit toxic fumes upon decomposition.


V HEALTH HAZARD INFORMATION

Effects of Exposure:

Osm ium is considered poisono us and shou ld be handled w ith caution. Effects include ocular disturbances, respiratory
difficulties, heavy metal poisoning.

Acute E ffects:

Inhalation: Irritating to mucous m embranes and u pper respiratory tract. M ay cau se asthm atic cond ition, bronc hitis.
Ingestion: May cause gastrointestinal irritation. No other effects known.
Skin : Causes irritation, dermatitis, ulceration of the skin.
Eye: Causes sev ere eye irritation, oc ular disturbances, con junctivitis. May cause blindness.
Chro nic Effects:

Inhalation: Bron chitis
Ingestion: None known
Skin : Derma titis
Eye: May cause blindness.

Other Health Hazards: Adverse health effects are due ma inly to OsO 4
Most Likely Routes of Entry: Ingestion
Target Organs: May cause kidney damage, route of overexposure not known.

Medical Conditions Generally Aggravated by Exposure: None known
Carcino genicity: NTP: No IARC: No OSHA: No EPA: No

EMERG ENCY AND FIRST AID PROCEDURES:

INHALATION: No specific information available, one should obtain medical attention.
INGESTION: No data available but one should obtain medical attention.
SK IN: Remove contaminated clothing, flood skin with large amounts of water. If irritation persists seek medical attention.
EYE: Imm ediately flush eyes, including under eyelids, with large amounts of water for at least 15 minutes. Call a physician.


VI REACTIVITY DATA

Stability: Stable

Co nditio ns to Av oid: Extre me heat.
Inco mp atible Materials: ClF 3, OF2, halogens, phosphorus, oxygen, oxidizers, acids, organic solvents, NH4.

Haz ardous D ecomposition Produc ts: Oxides of osm ium . Osm ium dust re acts vio lently w ith ClF 3 and OF 2. On heatin g in air it
gives off poisonous fumes of osmium tetraoxide.
Hazardous Polymerization: Will not occur


VII SPILL OR LEAK PROC EDURES

Steps to be taken if Spilled or Released: Wearing full protective equipment, cover spill with dry sand or vermiculite. Mix well and
carefully transfer to a container.

Waste Disposal Method: Dispose o f in accord ance w ith State, Federal and L ocal regu lations.


VIII SPECIAL PROTECTION INFORMATION

Respiratory Protection: NIOSH /MSH A app roved high efficiency particle respirator.
Ventilation: Handle in a glove box under a dry, inert atmosphere to prevent oxidation.

Protective Gloves: Rub ber fo r all con tact.
Eye/Face Protection: ANSI app roved safety goggles.

Other Protective Equipment: Protective gear suitable to prevent contamination.


IX SPECIAL PRECAUTIONS

Precautions to Be Taken in Handling and Storage: Keep containe r tightly closed. Sto re in coo l, dry, well-ventilated area. W ash
thoroughly after use.


-Osmium 2-
Wo rk Practices: Lab coat and apron, flame and chemical resistant coveralls, eyewash capable of sustained flushing, safety drench
shower and hygienic facilities for washing.

Danger: Flam ma ble, irritates lung s and ey es.

The abo ve inform ation is believ ed to be co rrect, but do es no t purp ort to b e all inclu sive an d sha ll be used only as a gu ide.
ESPI shall not be held liab le for any d am age resulting from h and ling o r from contact with the abov e pro duc t.


Issued by: S. Dierks
Date: October 2002




-Osmium 3-

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