World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00698
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Ascorbic Acid Titrant
Catalog Number: 2308232
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00698
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of ascorbic acid
CAS No.: Not applicable
Hazard: Causes eye burns. May cause irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Propylene Glycol
EEC Number: 2003380
CAS No.: 57556
--
Percent Range: 15,0 - 25,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Potassium Hydroxide
EEC Number: 2151813
CAS No.: 1310583
--
Percent Range: < 0,5
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 2 mg/m3 Ceiling
PEL: 2 mg/m3 Ceiling
EU Occupational Exposure Limits: 2 mg/m3
Potassium Iodide
EEC Number: 2316594
CAS No.: 7681110
--
Percent Range: 1,0 - 5,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: 70,0 - 80,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: Not determined
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): None reported
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause iodism, which symptoms include skin rash, conjunctivitis, runny nose, sneezing, bronchitis,
headache, fever and irritation of mucous membranes. May cause: abdominal pain nausea
Target Organs (Ing E): None Reported
Inhalation: No data reported.
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions
Chronic Effects: Iodines overdose, 'iodism', may cause skin rash, runny nose, headaches, fever and bronchitis.
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen. an experimental
teratogen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Call physician immediately.
Inhalation: None required.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, this product decomposes to form toxic gases.
Hazardous Combustion Products: Toxic fumes of: iodine compounds carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear. Evacuate area and fight fire from a safe distance.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Stop spilled material from being
released to the environment. Absorb spilled liquid with non-reactive sorbent material. Dike the spill to contain material for
later disposal.
Clean-up Technique: Cover spilled material with a dry acid, such as citric or boric. Scoop up slurry into a large beaker.
Adjust to a pH between 6 and 9 with an acid, such as sulfuric or citric. Flush reacted material to the drain with a large
excess of water. Decontaminate the area of the spill with a weak acid solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Maintain general industrial hygiene practices when using this product. Wash
thoroughly after handling.
Storage: Keep container tightly closed when not in use.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of ascorbic acid
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Use general ventilation to minimize exposure to mist, vapor or
dust. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves
Inhalation Protection: adequate ventilation
Precautionary Measures: Use with adequate ventilation. Wash thoroughly after handling.
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: Not determined
pH: 11,1
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: 97掳C
Melting Point: freezes at -7掳C
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,03
Evaporation Rate (water = 1): 1,05
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Miscible
Acid: Miscible
Other: Not determined
Metal Corrosivity:
Steel: 0,015 in/yr
Aluminum: None
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures
Reactivity / Incompatibility: Incompatible with: acids
Hazardous Decomposition: Heating to decomposition releases: iodine compounds
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Propylene glycol: Skin human 500 mg/7D - MILD; Eye rabbit 500 mg/24H - MILD
Mutation Data: Propylene glycol:Cytogenic analysis, DNA inhibition mouse - subcutaneous - 8000 mg/kg.
Reproductive Effects Data: Propylene glycol: Intraperitoneal mouse TDLo = 100 mg/kg-fetoxicity, post implantation
mortality. Potassium Iodide: Oral human wmn TDLo = 2700 mg/kg (endocrine abnormalities in offspring)
--
Ingredient Toxicological Data: Potassium hydroxide: Oral rat LD50 = 365 mg/kg; Potassium Iodide: Oral mouse LDLo =
1862 mg/kg; Propylene glycol: oral rat LD50 = 20 g/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). CCINFO RTECS. Canadian Centre for
Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. IARC Monographs on the Evaluation of the
Carcinogenic Risks to Humans. World Health Organization (Volumes 1-42) Supplement 7. France: 1987. In-house
information. Technicl Judgment.
a
R PHRASES: Not applicable
Use of the substance/preparation: Determination of ascorbic acid
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00437
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Sulfuric Acid Standard Solution, 5,25 N
Catalog Number: 244932
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00437
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Laboratory Reagent
CAS No.: Not applicable
Hazard: Harmful if inhaled. Carcinogen. Causes eye burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: 70,0 - 80,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Sulfuric Acid
EEC Number: 2316395
CAS No.: 7664939
--
Percent Range: 20,0 - 30,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 35
TLV: 1 mg/m鲁 (TWA); 3 mg/m鲁 (STEL)
PEL: 1 mg/m鲁
EU Occupational Exposure Limits: 0,1 mg/m3
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: None
EU Symbols: C - CORROSIVE
R PHRASES: R 35: Causes severe burns.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe burns
Skin Contact (EC): Causes severe burns
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): Causes: severe burns May cause: circulatory disturbances diarrhea nausea vomiting rapid pulse
and respirations
Target Organs (Ing E): None Reported
Inhalation: Causes: severe burns May cause: difficult breathing teeth erosion mouth soreness
Target Organs (Inh E): Lungs
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions
Chronic Effects: Chronic overexposure may cause erosion of the teeth chronic irritation or inflammation of the lungs
cancer
Cancer / Reproductive Toxicity Information:
An ingredient of this mixture is: IARC Group 1: Recognized Carcinogen
Sulfuric Acid - The IARC evaluation was based on exposure to the mist or vapor of concentrated sulfuric acid
generated during chemical processes.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Never give anything by mouth to an
unconscious person. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Not Flammable, but reacts with most metals to form flammable hydrogen gas. During a fire,
corrosive and toxic gases may be generated by thermal decomposition.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: Contact with metals gives off hydrogen gas which is flammable May react violently with:
strong bases water
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Dry chemical. Do NOT use water.
Extinguishing Media NOT To Be Used: Not applicable Do NOT use water.
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non-reactive sorbent material. Stop spilled material from being
released to the environment.
Clean-up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Scoop up slurry into
a large beaker. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Dispose of material
in an E.P.A. approved hazardous waste facility. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling. Use
with adequate ventilation. Maintain general industrial hygiene practices when using this product.
Storage: Keep container tightly closed when not in use. Protect from: heat Keep away from: alkalies oxidizers
reducers metals
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Maintain general industrial
hygiene practices when using this product. Use a fume hood to avoid exposure to dust, mist or vapor.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
handling. Use with adequate ventilation. Protect from: heat Keep away from: alkalies metals oxidizers reducers
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: None
pH: < 0,5
Vapor Pressure: Not determined.
Vapor Density (air = 1): Not determined.
Boiling Point: Not determined.
Melting Point: Not applicable
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,149
Evaporation Rate (water = 1): 0,85
Volatile Organic Compounds Content: None.
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Miscible.
Acid: Miscible.
Other: Not determined.
Metal Corrosivity:
Steel: 0,230 in/yr (5,842 mm/yr)
Aluminum: >0,25 in/yr
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures Heating to decomposition.
Reactivity / Incompatibility: May react violently in contact with: strong bases oxidizers reducers Incompatible with:
metals
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: sulfur oxides Contact
with metals may release flammable hydrogen gas.
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported.
LC50: None reported.
Dermal Toxicity Data: None reported.
Skin and Eye Irritation Data: This product is not corrosive to skin. Absent to very slight erythema. No edema. (OECD
Number 404, Acute Dermal Irritation/Corrosion)
Mutation Data: None reported.
Reproductive Effects Data: None reported.
--
Ingredient Toxicological Data: Sulfuric Acid: Oral rat LD50 = 2140 mg/kg; Inhalation rat LC50 = 347 ppm/1hr.
An ingredient of this mixture is: IARC Group 1: Recognized Carcinogen
Sulfuric Acid - The IARC evaluation was based on exposure to the mist or vapor of concentrated sulfuric acid generated
during chemical processes.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: Sulfuric Acid: The 48-Hour TLm in flounder is 100-300 ppm.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(<45% Sulfuric Acid in Solution)
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN3264
ICAO Packing Group: III
I.M.O.:
I.M.O. Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(<45% Sulfuric Acid in Solution)
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN3264
I.M.O. Packing Group: III
A.D.R.:
A.D.R. Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(<45% Sulfuric Acid in Solution)
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 3264
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: C - CORROSIVE
R PHRASES: R 35: Causes severe burns.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S
37/39: Wear suitable gloves and eye / face protection. S 45: In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. CCINFO RTECS. Canadian Centre for Occupational Health and
Safety. Hamilton, Ontario Canada: 30 June 1993. IARC Monographs on the Evaluation of the Carcinogenic Risks to
Humans. World Health Organization (Volumes 1-42) Supplement 7. France: 1987. List of Dangerous Substances
Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of Dangerous Substances,
Amended July 1992. Sixth Annual Report on Carcinogens, 1991. U.S. Department of Health and Human Services.
Rockville, MD: Technical Resources, Inc. 1991. Technical Judgment. TLV's Threshold Limit Values and Biological
Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992.
R PHRASES: R 35: Causes severe burns.
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00294
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Starch Indicator Solution
Catalog Number: 34932
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00294
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Oxidation-reduction indicator
CAS No.: Not applicable
Hazard: May cause irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: >95,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Salicylic Acid
EEC Number: 2007123
CAS No.: 69727
--
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Starch
EEC Number: 2326864
CAS No.: 9005849
--
Percent Range: < 1,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 10 mg/m3 total dust
PEL: 15 mg/m3 total dust
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear to slightly turbid, colorless solution
Odor: None
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): No effects are anticipated
Skin Contact (EC): No effects are anticipated
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): No Effects Anticipated
Target Organs (Ing E): Not applicable
Inhalation: No effects anticipated
Target Organs (Inh E): Not applicable
Medical Conditions Aggravated: Allergies or sensitivity to aspirin or salicylates.
Chronic Effects: No effects anticipated
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen. an experimental
teratogen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: None required.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Material will not burn.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non-reactive sorbent material. Dike large spills to keep spilled
material from entering sewage and drainage systems or bodies of water.
Clean-up Technique: Cover spilled material with a dry acid, such as citric or boric. Scoop up slurry into a large beaker.
Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain
with a large excess of water. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of the
evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes Do not breathe mist or vapors. Wash thoroughly after handling. Maintain general
industrial hygiene practices when using this product.
Storage: Store between 10掳 and 25掳C.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Oxidation-reduction indicator
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes Do not breathe: mist/vapor Wash thoroughly after handling.
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear to slightly turbid, colorless solution
Physical State: Liquid
Odor: None
pH: 3,1
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: ~100 掳C (~212 掳F)
Melting Point: Not applicable
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 0,986
Evaporation Rate (water = 1): 0,53
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures
Reactivity / Incompatibility: None reported
Hazardous Decomposition: No hazardous decomposition products known.
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Salicylic Acid: Oral rat LD50 =891 mg/kg, Oral mouse LD50 = 480 mg/kg, Oral cat
LD50 = 400 mg/kg, Oral rabbit LD50 = 1300 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
______________________________________
16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of
Governmental Industrial Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19,
1989. pp. 2332-2983. In-house information. Technical Judgment. Vendor Information. CCINFO RTECS. Canadian
Centre for Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993.
R PHRASES: Not applicable
Use of the substance/preparation: Oxidation-reduction indicator
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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