World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00075
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Ascorbic Acid
Catalog Number: 1457799
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00075
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Laboratory Reagent
CAS No.: Not applicable
Hazard: Practically non-toxic.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Ascorbic Acid
EEC Number: 2000662
CAS No.: 50817
--
Percent Range: > 99,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Other component
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White to light yellow crystals
Odor: Sweet
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): No effects are anticipated
Skin Contact (EC): No effects are anticipated
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): Very large doses may cause: gastrointestinal tract irritation diarrhea
Target Organs (Ing E): None Reported
Inhalation: No effects anticipated
Target Organs (Inh E): Not applicable
Medical Conditions Aggravated: None reported
Chronic Effects: No effects anticipated
Cancer / Reproductive Toxicity Information:
IARC Listed: No
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Flush eyes with water. Call physician if irritation develops.
Skin Contact (First Aid): Wash skin with soap and plenty of water.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: May react violently with: strong oxidizers
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Carbon dioxide Dry chemical. Water.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain with a large excess of water.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of the
evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrial
hygiene practices when using this product.
Storage: Keep away from: oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling. Keep away
from: oxidizers
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White to light yellow crystals
Physical State: Solid
Odor: Sweet
pH: 5% solution = 2,3
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 192掳C; 378掳F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not available
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,65
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Not determined
Other: Soluble in alcohol, glycerol
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture
Reactivity / Incompatibility: Incompatible with: oxidizers alkalies copper iron
Hazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: Ascorbic acid - DNA damage human fibroblast 200 碌mol/L; DNA damage human cell types 200
碌mol/L; DNA inhibition human HeLa cell 2500 碌mol/L
Reproductive Effects Data: Ascorbic acid - Oral guinea pig TDLo 19500 mg/kg effects on newborn - biochemical and
metabolic; Oral guinea pig TDLo 5800 mg/kg effects on newborn - stillbirth; Oral guinea pig TDLo 2471 mg/kg effects
on newborn - growth statistics
--
Ingredient Toxicological Data: Ascorbic acid Oral rat LD50 = 11900 mg/kg
IARC Listed: No
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: No information available on this product.
Ingredient Ecological Information: No ingredient information available.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Invntory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
e
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. The Merck Index, 11th Ed. Rahway,
New Jersey: Merck and Co., Inc., 1989. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York:
Van Nostrand Reinhold Co., 1989. Gosselin, R. E. et al. Clinical Toxicology of Commercial Products, 5th Ed. Baltimore:
The Williams and Wilkins Co., 1984. Vendor Information. In-house information. Technical Judgment.
R PHRASES: Not applicable
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00379
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Alkaline Cyanide Reagent
Catalog Number: 2122326
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00379
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of manganese
CAS No.: Not applicable
Hazard: Toxic. Causes burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Hydroxide
EEC Number: 2151855
CAS No.: 1310732
--
Percent Range: 1,0 - 5,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 34
TLV: 2 mg/m鲁
PEL: 2 mg/m鲁
EU Occupational Exposure Limits: 2 mg/m3
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: 90,0 - 100,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Sodium Cyanide
EEC Number: 2055994
CAS No.: 143-33-9
Percent Range: 5,0 - 15,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: T - TOXIC N - Dangerous for the Environment
Ingredient R phrase(s) (R phrase details given in Heading 16): R 23/24/25 R 32 R 51/53
TLV: 5 mg/m3 (skin)
PEL: 5 mg/m3 (skin)
EU Occupational Exposure Limits: None found. Cyanides are on the Priority List for OELs.
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: None
EU Symbols: T - TOXIC N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 23/24/25: Toxic by inhalation, in contact with skin and if swallowed. R 32: Contact with acids
liberates very toxic gas. R 34: Causes burns. R 51/53: Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Emergency response to cyanide exposure should be planned and practiced prior to work with cyanides. First
responders should start treatment and get medical attention immediately. Antidote: break an amyl nitrite pearl in cloth
and hold lightly under nose for 15 seconds. Repeat 5 times at 15 second intervals. Transport to hospital immediately.
Note to Physician: Have a cyanide first aid kit available. If patient has not responded to amyl nitrite, inject
intraveneously 10 ml of a 3% solution of sodium nitrite at a rate not greater than 2,5 - 5 ml/min. Follow directly with 50
ml of a 25 % solution of sodium thiosulfate at the same rate by the same route. Keep patient under observation. If signs
of poisoning persist or reappear, repeat nitrite and thiosulfate injections 1 hour later in one-half the original doses.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes burns
Skin Contact (EC): Causes burns
Skin Absorption (EC): Toxic Will be absorbed through the skin. Effects similar to those of ingestion
Target Organs (SA E): Central nervous system
Ingestion (EC): Toxic May be rapidly fatal. Causes: cyanosis ( a reduction of the blood's ability to carry oxygen,
giving a bluish discoloration) burns of the mouth and esophagus May cause: anxiety headache confusion irregular
heartbeat convulsions coma death
Target Organs (Ing E): Central nervous system Brain
Inhalation: Toxic Effects similar to those of ingestion.
Target Organs (Inh E): Central nervous system Brain
Medical Conditions Aggravated: Pre-existing: Skin conditions
Chronic Effects: Chronic overexposure may cause central nervous system effects
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Break an amyl nitrite pearl in cloth and hold lightly under nose for 15 seconds. Repeat every five
minutes. Administer artificial respiration with 100% oxygen. Transport to hospital immediately.
Inhalation: Break an amyl nitrite pearl in cloth and hold lightly under nose for 15 seconds. Repeat 5 times at 15 second
intervals. Transport to hospital immediately.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, irritating and highly toxic gases may be generated by thermal decomposition.
Hazardous Combustion Products: Toxic fumes of: cyanide compounds sodium monoxide
Fire / Explosion Hazards: May react violently with: strong acids
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand an full protective
d
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Stop spilled material from being
released to the environment. Absorb spilled liquid with non-reactive sorbent material.
Clean-up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Carefully mist spill
with bleach until saturated. Scoop up slurry into a large beaker. Oxidize spilled material with a 50% excess of bleach
containing at least 5% sodium hypochlorite. Allow to react for 24 hours in a fume hood. Flush reacted material to the drain
with a large excess of water. Decontaminate area with bleach solution.
Evacuation Procedure: Evacuate general area (50 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. Deny access to unnecessary and unprotected personnel. If conditions warrant, increase the
size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.
Maintain general industrial hygiene practices when using this product.
Storage: Keep away from: acids / acid fumes. Protect from: heat freezing
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of manganese
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have a safety shower nearby. Have an eyewash station nearby. Use a fume hood to avoid
exposure to dust, mist or vapor. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: neoprene latex gloves lab coat
Inhalation Protection: laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
handling. Keep away from: acids/acid fumes Protect from: heat freezing
TLV: Cyanide 5 mg/m3 (skin)
PEL: Cyanide 5 mg/m3 (skin)
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: None
pH: 12,3
Vapor Pressure: Not available
Vapor Density (air = 1): Not available
Boiling Point: 92 C
Melting Point: Not available
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not available
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,112
Evaporation Rate (water = 1): 0,57
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Miscible
Acid: Produces HCN
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures
Reactivity / Incompatibility: Incompatible with: acids
Hazardous Decomposition: Contact with acids/acid fumes releases toxic cyanide gas.
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: Oral rat LD50 = 69 mg/kg
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: Sodium Cyanide: oral rat TCLo = 2148 mg/kg male 13 week pre-mating
--
Ingredient Toxicological Data: Sodium Cyanide:Oral rat LD50 = 6440 碌g/kg; Oral human LDLo = 2857 碌g/kg Sodium
Hydroxide: Oral rabbit LDLo = 500 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S.
(Sodium Hydroxide/Sodium Cyanide Solution)
ICAO Hazard Class: 8
ICAO Subsidiary Risk: 6,1
ICAO UN/ID Number: UN2922
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S.
(Sodium Hydroxide/Sodium Cyanide Solution)
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: 6,1
I.M.O. UN Number: UN2922
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S.
(Sodium Hydroxide/Sodium Cyanide Solution)
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: 6,1
A.D.R. UN-Number:: 2922
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: T - TOXIC N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 23/24/25: Toxic by inhalation, in contact with skin and if swallowed. R 32: Contact with acids liberates
very toxic gas. R 34: Causes burns. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S PHRASES: S 7: Keep container tightly closed. S 26: In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. S 28a: After contact with skin, wash immediately with plenty of water. S 35: This
material and its cotainer must be disposed of in a safe way. S 36/39: Wear suitable protective clothing and eye/face
n
protection. S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Eposure Indices for
x
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. CCINFO RTECS. Canadian Centre for
Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Gosselin, R. E. et al. Clinical Toxicology of
Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Outside Testing. In-house information.
Technical Judgment. List of Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification,
Packaging and Labeling of Dangerous Substances, Amended July 1992.
R PHRASES: R 23/24/25: Toxic by inhalation, in contact with skin and if swallowed. R 32: Contact with acids liberates
very toxic gas. R 34: Causes burns. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Use of the substance/preparation: Determination of manganese
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00388
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
_____________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: PAN Indicator Solution 0,1%
Catalog Number: 2122426
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00388
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of manganese
CAS No.: Not applicable
Hazard: Toxic. May be embryotoxic. Causes severe eye irritation.
Date of MSDS Preparation:
Day: 22
Month: August
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245,
France: +33-(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-
(0)1-2515151
_____________________________________________________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Octylphenoxypolyethoxyethanol
EEC Number: 2645201
CAS No.: 9036-19-5
Percent Range: 5,0 - 15,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Glycol ethers are on the Priority List for OELs.
Demineralized Water
EEC Number: 2317912
CAS No.: 7732-18-5
Percent Range: 35,0 - 45,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Other component
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: Not applicable
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
N,N-Dimethylformamide
EEC Number: 2006795
CAS No.: 68-12-2
Percent Range: 25,0 - 35,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: T - TOXIC
Ingredient R phrase(s) (R phrase details given in Heading 16): R 61 R 36
TLV: 10 ppm (skin)
PEL: 10 ppm (skin)
EU Occupational Exposure Limits: 10 ppm (30 mg/m3)
Ammonium Acetate
EEC Number: 2111629
CAS No.: 631-61-8
Percent Range: 15,0 - 25,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: For ammoniag 20 ppm (14 mg/m3); STEL: 50 ppm (36 mg/m3)
Recommended.3 mg/m3, Inhalable dust.
_____________________________________________________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, red-orange liquid
Odor: Ammonia
EU Symbols: T - TOXIC
R PHRASES: R 61: May cause harm to the unborn child. R 36: Irritating to eyes.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): Harmful if absorbed through the skin May cause kidney damage May cause liver
damage May cause nausea May cause vomiting
Target Organs (SA E): Kidneys Liver
Ingestion (EC): May cause: abdominal pain nausea vomiting diarrhea blood pressure problems kidney
damage liver damage
Target Organs (Ing E): Kidneys Liver
Inhalation: Harmful Effects similar to those of ingestion. May cause: respiratory tract irritation
Target Organs (Inh E): Liver Kidneys
Medical Conditions Aggravated: Pre-existing: Liver conditions Kidney conditions
Chronic Effects: Dimethylformamide is capable of producing cumulative systemic injury when repeatedly
inhaled or absorbed through the skin. Chronic overexposure may cause kidney damage liver damage
Cancer / Reproductive Toxicity Information:
An ingredient of this mixture is: IARC Group 3: Non-classifiable
Dimethylformamide
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen. an
experimental teratogen. In laboratory tests, application of DMF to the skin of pregnant rats caused fetal
deaths when the dosages were close to the lethal dose level for the mother.
Toxicologically Synergistic Products: Exposure to and/or consumption of alcohol may increase toxic effects
of this product.
_____________________________________________________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing.
Call physician immediately.
Ingestion (First Aid): Give a slurry of powdered activated charcoal. Induce vomiting using syrup of ipecac or
by sticking finger down throat. Never give anything by mouth to an unconscious person. Call physician
immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
_____________________________________________________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: dimethylamine nitrogen oxides. carbon monoxide,
carbon dioxide.
Fire / Explosion Hazards: May react violently with: nitric acid metal nitrates strong oxidizers alkali metals
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Water. Alcohol foam. Dry chemical. Carbon dioxide
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full
protective gear.
_____________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond
to a spill involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Dike the material to
create a barrier to combustibles.
Clean-up Technique: Do not breathe the fumes. Cover with an inert material, such as sand. Sweep up
material. Incinerate material at an E.P.A. approved hazardous waste facility. Decontaminate the area of the
spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency
response plan) when: any quantity is spilled.
_____________________________________________________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after
handling. Maintain general industrial hygiene practices when using this product.
Storage: Keep away from: acids oxidizers alkali metals halogens Store between 10掳 and 25掳C. Protect
from: heat
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of manganese
_____________________________________________________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Maintain adequate
ventilation to keep vapor level below TWA for chemicals in this product. Maintain general industrial hygiene
practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: lab coat neoprene latex gloves
Inhalation Protection: laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash
thoroughly after handling. Protect from: heat Keep away from: acids/acid fumes alkali metals oxidizers
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
_____________________________________________________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, red-orange liquid
Physical State: Liquid
Odor: Ammonia
pH: 8,0
Vapor Pressure: Not available
Vapor Density (air = 1): Not available
Boiling Point: 101掳C; 214掳F
Melting Point: Not determined
Flash Point: >93掳C; >200掳F
Method: Closed cup
Autoignition Temperature: Not available
Flammability Limits:
Lower Explosion Limits: Not available
Upper Explosion Limits: Not available
Specific Gravity (water = 1): 1,044
Evaporation Rate (water = 1): 0,25
Volatile Organic Compounds Content: Not available
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Miscible
Acid: Miscible
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
_____________________________________________________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heat Heating to decomposition.
Reactivity / Incompatibility: Incompatible with: nitric acid metal nitrates halogens alkali metals oxidizers
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: nitrogen
oxides carbon dioxide carbon monoxide
Hazardous Polymerization: Will not occur.
_____________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: DMF Skin rabbit LD50 = 4720 mg/kg; Octylphenoxypolyethoxyethanol Skin rabbit
LD50 > 3000 mg/kg
Skin and Eye Irritation Data: DMF: Skin human 100%/24H - Standard Draize Test - MILD, Eye rabbit 100
mg - Rinsed Draize Test - SEVERE; Octylphenoxypolyethoxyethanol: Eye rabbit 1% SEVERE
Mutation Data: DMF: Cytogenetic analysis - human - inhalation - 12300 碌g/m3/Y; Cytogenetic analysis -
human lymphocytes - 100 nmol/l; Octylphenoxypolyethoxyethanol: DNA inhibition - human lymphocytes 5
ppm
Reproductive Effects Data: DMF: Inhalation rat TCLo = 4 mg/m3/4H 1-19 days after conception - Pre-
implantation mortality, fetotoxicity, embryo death
DMF: Skin rat TDLo = 7552 mg/kg 6-15 days after conception - fetotoxicity; oral mouse TDLo = 1820
mg/kg 6-15 days after conception - fetotoxicity
Ingredient Toxicological Data: DMF: Oral rat LD50 = 2800 mg/kg; Inhalation mouse LC50 = 9400
mg/m3/2H; Octylphenoxypolyethoxyethanol: Oral rat LD50 = 1800 mg/kg
An ingredient of this mixture is: IARC Group 3: Non-classifiable
Dimethylformamide
_____________________________________________________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: No product ecological information available.
Ingredient Ecological Information: Octylphenoxypolyethoxyethanol - Bluegill sunfish (Lepomis
macrochirus), 96 hour dynamic: > 10 mg/l
_____________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by
more stringent state or local requirements. Please consult your local environmental regulators for more
information. In Europe: Chemical and analysis solutions must be disposed of in compliance with the
respective national regulations. Product packaging must be disposed of in compliance with the country-specific
regulations or must be passed to a packaging return system.
_____________________________________________________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various
compatible dangerous goods for analytical or testing purposes. This kit would have the following
classification: Proper Shipping Name: Chemical Kit Hazard Class: 9 UN Number 3316
_____________________________________________________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: T - TOXIC
R PHRASES: R 61: May cause harm to the unborn child. R 36: Irritating to eyes.
S PHRASES: S 53: Avoid exposure - obtain special instructions before use. S 45: In case of accident or if
you feel unwell, seek medical advice immediately (show the label where possible).
_____________________________________________________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). TLV's Threshold Limit Values and
Biological Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists,
1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983.
CCINFO RTECS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada: 30 June
1993. Gosselin, R. E. et al. Clinical Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams
and Wilkins Co., 1984. IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans. World
Health Organization (Volumes 1-42) Supplement 7. France: 1987. List of Dangerous Substances Classified in
Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of Dangerous Substances,
Amended July 1992. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van
Nostrand Reinhold Co., 1989. Vendor Information. In-house information. Technical Judgment.
R PHRASES: R 61: May cause harm to the unborn child. R 36: Irritating to eyes.
Use of the substance/preparation: Determination of manganese
Revision Summary: Updates in Section(s) 14,
_____________________________________________________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual
site safety programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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