World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00487
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: PAN Indicator Solution 0,3%
Catalog Number: 2150232
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00487
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of nickel
CAS No.: Not applicable
Hazard: Causes severe eye irritation. May be embryotoxic.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
N,N-Dimethylformamide
EEC Number: 2006795
CAS No.: 68122
--
Percent Range: 55,0 - 65,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: T - TOXIC
Ingredient R phrase(s) (R phrase details given in Heading 16): R 20/21 R 61 R 36
TLV: 10 ppm (skin)
PEL: 10 ppm (skin)
EU Occupational Exposure Limits: 10 ppm (30 mg/m3)
1-(2-Pyridylazo)-2-naphthol
EEC Number: 2016379
CAS No.: 85858
--
Percent Range: 0,1 - 1,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Octylphenoxypolyethoxyethanol
EEC Number: Not Applicable
CAS No.: Not Applicable
Percent Range: 25,0 - 35,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: 5,0 - 15,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, red-orange liquid
Odor: Amine
EU Symbols: T - TOXIC
R PHRASES: R 61: May cause harm to the unborn child. R 20/21: Harmful by inhalation and in contact with skin. R
36: Irritating to eyes.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): Harmful if absorbed through the skin May cause kidney damage May cause liver damage May
cause nausea May cause vomiting
Target Organs (SA E): Liver Kidneys
Ingestion (EC): May cause: abdominal pain nausea vomiting diarrhea blood pressure problems kidney damage
liver damage
Target Organs (Ing E): Liver Kidneys
Inhalation: Harmful Effects similar to those of ingestion. May cause: respiratory tract irritation
Target Organs (Inh E): Liver Kidneys
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions Liver
conditions Kidney conditions
Chronic Effects: Dimethylformamide is capable of producing cumulative systemic injury when repeatedly inhaled or
absorbed through the skin.
Cancer / Reproductive Toxicity Information:
IARC Group 3: Non-classifiable
Dimethylformamide
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental carcinogen. an experimental
mutagen. an experimental teratogen. In laboratory tests, application of DMF to the skin of pregnant rats caused fetal
deaths when the dosages were close to the lethal dose level for the mother.
Toxicologically Synergistic Products: Exposure to and/or consumption of alcohol may increase toxic effects of this
product. Reports of increased possibilities of facial flushing from inhalation of vapors after ingestion of alcohol. Effects
resemble porphyria.
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water.
Ingestion (First Aid): Give a slurry of powdered activated charcoal. Induce vomiting using syrup of ipecac or by sticking
finger down throat. Never give anything by mouth to an unconscious person. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Combustible Liquid This material does NOT sustain combustion when tested according to the
UN Recommendation's "Methods of Testing for Combustibility".
Hazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide. dimethylamine
Fire / Explosion Hazards: Combustible liquid
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Water. Carbon dioxide Dry chemical.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand an full protective
d
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Remove all combustible material
from spill area. Remove all ignition and spark-creating sources from the spill area. Cover spilled liquid with a
commercially available flammable liquid sorbent such as vapor barrier blanket or activated carbon to avoid evolution of
fumes. Vapors may travel to a source of ignition and flash back. May be ignited by: heat, sparks, or flames.
Clean-up Technique: Eliminate all sources of ignition. Do not breathe the fumes. Cover with an inert material, such as
sand. Use only non-sparking tools. Sweep up material. Incinerate material at an E.P.A. approved hazardous waste facility.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.
Maintain general industrial hygiene practices when using this product.
Storage: Protect from: oxidizers heat halogenated hydrocarbons metals
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of nickel
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Use a fume hood to avoid exposure to dust, mist or vapor.
Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: lab coat neoprene latex gloves
Inhalation Protection: laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
handling. Protect from: heat halogenated hydrocarbons oxidizers metals
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, red-orange liquid
Physical State: Liquid
Odor: Amine
pH: 9,45
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: 103掳C (217,4掳F)
Melting Point: Not determined
Flash Point: 61 - 63 掳 C ( 141 - 145 掳 F )
Method: Closed cup
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not determined
Upper Explosion Limits: Not determined
Specific Gravity (water = 1): 1,006
Evaporation Rate (water = 1): 0,594
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,0007 in/yr
Aluminum: Not determined
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Contact with heat, sparks, open flames or other ignition sources. Extreme temperatures
Reactivity / Incompatibility: Incompatible with: halogenated organic compounds May react violently in contact with:
oxidizers
Hazardous Decomposition: Toxic fumes of: carbon monoxide carbon dioxide
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: Dimethylformamide: Cytogenic analysis - human - inhalation - 12300 碌g/m3/Y, Cytogenetic analysis -
human - lymphocytes - 100 nmol/l
Reproductive Effects Data: Dimethylformamide: Inhalation rat TCLo= 4 mg/m3/4H 1-19 days after conception - Pre-
implantation mortality, fetotoxicity, embryo death
--
Ingredient Toxicological Data: Dimethylformamide: Oral rat LD50 = 2800 mg/kg, Skin rabbit LD50 = 4720 mg/kg;
Octylphenoxypolyethoxyethanol: Oral rat LD50 = 1800 mg/kg
IARC Group 3: Non-classifiable
Dimethylformamide
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: Octylphenoxypolyethoxyethanol: Bluegill sunfish (Lepomis macrochirus) 96 hour
dynamic > 10 mg/l (Slightly toxic)
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: T - TOXIC
R PHRASES: R 61: May cause harm to the unborn child. R 20/21: Harmful by inhalation and in contact with skin. R
36: Irritating to eyes.
S PHRASES: S 25: Avoid contact with eyes. S 53: Avoid exposure - obtain special instructions before use. S 45: In
case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. Technical Judgment. In-house
information. IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans. World Health Organization
(Volumes 1-42) Supplement 7. France: 1987. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA:
National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection
Association, 1991. CCINFO RTECS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada:
30 June 1993.
R PHRASES: R 61: May cause harm to the unborn child. R 20/21: Harmful by inhalation and in contact with skin. R
36: Irritating to eyes.
Use of the substance/preparation: Determination of nickel
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00099
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Phthalate-Phosphate Reagent
Catalog Number: 2615199
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00099
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of nickel Determination of cobalt
CAS No.: Not applicable
Hazard: Causes irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Pyrophosphate
EEC Number: 2317671
CAS No.: 13472-36-1
Percent Range: 20,0 - 30,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 5 mg/m3
PEL: 5 mg/m3
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Potassium Acid Phthalate
EEC Number: 2128894
CAS No.: 877-24-7
Percent Range: 70,0 - 80,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White powder
Odor: Not determined
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): Very large doses may cause: nausea vomiting paresthesias (tingling or burning sensation) of the
hands and feet diarrhea abdominal cramps abdominal pain irritation of the mouth and esophagus
Target Organs (Ing E): None Reported
Inhalation: May cause: coughing choking respiratory tract irritation
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: phosphorus oxides sodium monoxide carbon monoxide, carbon
dioxide.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain with a large excess of water.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Do not breathe dust. Wash thoroughly after handling. Maintain general
industrial hygiene practices when using this product.
Storage: Protect from: heat Keep away from: oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of nickel Determination of cobalt
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash thoroughly after handling. Protect
from: heat Keep away from: oxidizers
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Physical State: Solid
Odor: Not determined
pH: 5% solution = 4,9
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 230掳C; 446掳F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not available
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,74
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,009 in/year
Aluminum: 0,014 in/year
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture Extreme temperatures
Reactivity / Incompatibility: None reported
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: phosphorus oxides
carbon monoxide carbon dioxide
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sodium Pyrophosphate Oral rat LD50 = 4000 mg/kg; Potassium Acid Phthalate Oral rat
LDLo = 3200 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992-1993. American Conference of Governmental Industrial Hygienists, 1992. In-house information. Technical
Judgment.
R PHRASES: Not applicable
Use of the substance/preparation: Determination of nickel Determination of cobalt
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00043
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: EDTA Reagent Powder
Catalog Number: 700599
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00043
Chemical Name: Glycine, N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, Tetrasodium Salt
Chemical Formula: C10H12N2Na4O8 2H2O
Chemical Family: Substituted organic acid
Use of the substance/preparation: Laboratory Reagent
CAS No.: 64-02-8
Hazard: May cause irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
EDTA Tetrasodium Salt
EEC Number: 2005739
CAS No.: 64028
--
Percent Range: 100,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xi - IRRITATING
Ingredient R phrase(s) (R phrase details given in Heading 16): R 36/37/38
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White powder
Odor: None
EU Symbols: Xi - IRRITATING
R PHRASES: R 36/37/38: Irritating to eyes, respiratory system and skin.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes moderate irritation
Skin Contact (EC): Causes moderate irritation
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): May cause: calcium deficiency in the blood Very large doses may cause: gastrointestinal tract
irritation fever kidney damage
Target Organs (Ing E): Kidneys
Inhalation: May cause: irritation of nose and throat
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: None reported
Chronic Effects: Chronic overexposure may cause kidney damage
Cancer / Reproductive Toxicity Information:
IARC Listed: No
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide. nitrogen oxides. sodium
monoxide
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment. Cover spilled solid material with
sand or other inert material.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an acid, such as sulfuric or citric. Flush reacted material to the drain with a large excess of water. Decontaminate
the area of the spill with a weak acid solution.
Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of the
evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Do not breathe dust. Wash thoroughly after handling. Maintain general
industrial hygiene practices when using this product.
Storage: Protect from: heat moisture
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash thoroughly after handling. Protect
from: heat moisture
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Physical State: Solid
Odor: None
pH: of a 1% solution = 11
Vapor Pressur : Not applicable
e
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: > 300 掳C >572 掳F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): Not determined
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Not determined
Other: Soluble in alcohol
Metal Corrosivity:
Steel: 0,000 in/yr
Aluminum: 0,000 in/yr
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures Excess moisture
Reactivity / Incompatibility: Incompatible with: oxidizers
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: carbon dioxide carbon
monoxide nitrogen oxides
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Skin rabbit 500mg/24H, MODERATE; Eye rabbit 1900碌g; Eye rabbit 100mg/24H,
MODERATE
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Not applicable
IARC Listed: No
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: BOD 0.02 g/g; COD 0.54 g/g; Fish toxicity: Bluegill LC50 = 410 mg/l for 96 hours.
Ingredient Ecological Information: --
Not applicable
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name:Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: EINECS Listed: Yes
EEC Number: 2005739
EEC LABEL COPY:
EU Symbols: Xi - IRRITATING
R PHRASES: R 36/37/38: Irritating to eyes, respiratory system and skin.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36:
Wear suitable protective clothing.
______________________________________
16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of
Governmental Industrial Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19,
1989. pp. 2332-2983. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. Sax, N. Irving.
Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. Technical Judgment.
Gosselin, R. E. et al. Clinical Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co.,
1984. In-house information. Vendor Information.
R PHRASES: R 36/37/38: Irritating to eyes, respiratory system and skin.
Use of the substance/preparation: Laboratory Reagent
Revision Summary: European MSDS Only Updates in Heading(s) 2,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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