HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Sample cuvette, 1/2
Print date : 22.02.2006 Product code : LCK311-1 Page 1 of 6
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation
LCK 311 Chlorid/Chloride/Chlorure, Sample cuvette, 1/2
Use of the substance/preparation
Water analysis
1.2 Company/undertaking identification
Company name HACH LANGE GmbH
Street Willst盲tterstr. 11
D-40549 D眉sseldorf
Place
Telephone +49(0)2115288 0
Telefax +49(0)2115288143
e-mail info@hach-lange.de
Inquiry office
HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - England
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk
2. Composition/information on ingredients
( preparation )
Chemical characterization
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
213-791-2 7732-18-5 Water 50,0-52,0 %
200-659-6 67-56-1 methanol <45 % F, T R11-23/24/25-39/23/24/25
231-714-2 7697-37-2 nitric acid ... % <6 % O, C R8-35
209-773-0 592-85-8 Mercury(II) thiocyanate <0,1 % T+, N R33-26/27/28-50-53
Full text of each relevant R phrase can be found in heading 16.
3. Hazards identification
Classification
Symbols : Toxic, Corrosive
R-phrases :
Flammable.
Causes burns.
Toxic by inhalation, in contact with skin and if swallowed.
Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
4. First aid measures
General information
Take off contaminated clothing and shoes immediately. Show this safety data sheet to the doctor in
attendance.
After inhalation
Move to fresh air. Consult a physician.
After contact with skin
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Sample cuvette, 1/2
Print date : 22.02.2006 Product code : LCK311-1 Page 2 of 6
Wash off immediately with plenty of water for at least 15 minutes. Immediate medical treatment is
necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an
unconscious person. Consult a physician.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
water, carbon dioxide (CO2), foam, dry powder
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. In order to avoid contact with skin, keep
a safety distance and wear suitable protective clothing.
Additional information
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material and dispose of as hazardous waste.
7. Handling and storage
7.1 Handling
Advice on safe handling
Use only in well-ventilated areas.
7.2 Storage
Requirements for storage rooms and vessels
Keep tightly closed in a dry, cool and well-ventilated place. Keep locked up or in an area accessible
only to qualified or authorised persons.
Further information on storage conditions
Keep refrigerated.
8. Exposure controls/personal protection
8.1 Exposure limit values
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Sample cuvette, 1/2
Print date : 22.02.2006 Product code : LCK311-1 Page 3 of 6
Exposure limits (EH40)
CAS No. Substance ml/m鲁 mg/m鲁 F/ml Category Origin
592-85-8 Mercury(II) thiocyanate 0,1 TWA (8 h)
STEL (15 min)
67-56-1 Methanol 200 266 TWA (8 h) WEL
250 333 STEL (15 min) WEL
7697-37-2 Nitric acid 2 5.2 TWA (8 h) WEL
4 10 STEL (15 min) WEL
BAT values (TRGS 903)
CAS No. Substance Value Parameter Test material Sampling time
67-56-1 Methanol 30 mg/l Methanol U c,b
8.2 Exposure controls
Occupational exposure controls
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Protective and hygiene measures
Wash hands before breaks and at the end of workday.
Respiratory protection
Breathing apparatus only if aerosol or dust is formed.
Hand protection
Use barrier skin cream. The selected protective gloves have to satisfy the specifications of EU
Directive 89/689/EEC and the standard EN 374 derived from it.
Eye protection
safety glasses with side-shields
9. Physical and chemical properties
9.1 General information
Physical state liquid
Colour pink
Odour sweet
9.2 Important health, safety and environmental information
Test method
0,5
pH-Value (at 20 掳C) :
Changes in the physical state
Boiling point 65 掳C
Flash point 24 掳C
Vapour pressure : 128 hPa
at (20 掳C)
Density (at 20 掳C) : 0,92 g/cm鲁
completely miscible
Water solubility :
at (20 掳C)
10. Stability and reactivity
Materials to avoid
oxidizing agents,
alkali metals
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Sample cuvette, 1/2
Print date : 22.02.2006 Product code : LCK311-1 Page 4 of 6
Hazardous decomposition products
No dangerous reaction known under conditions of normal use.
11. Toxicological information
Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.
Severe effects after repeated or prolonged exposure
Concentration above the admissible concentration at the workplace may cause dizziness, headache
and inebriation.
12. Ecological information
Ecotoxicity
May cause long-term adverse effects in the aquatic environment.
Do not flush into surface water or sanitary sewer system.
13. Disposal considerations
Advice on disposal
Our local agencies will accept used cuvettes to ensure their proper disposal.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
ADR/RID class 9
Warning plate
UN number 3316
ADR/RID packing group II
Description of the goods
Chemical kit
Inland waterways transport
Remarks (inland waterways transport)
not tested
Marine transport
IMDG code 9
UN number 3316
Marine pollutant --
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Sample cuvette, 1/2
Print date : 22.02.2006 Product code : LCK311-1 Page 5 of 6
EmS F-A, S-P
IMDG packing group II
Description of the goods
Chemical kit
Air transport
ICAO/IATA-DGR 9
UN/ID number 3316
ICAO packing group II
Description of the goods
Chemical kit
Futher Information
This product forms part of a kit. Information in this section relates to the kit as a whole.
15. Regulatory information
15.1 Labelling
Indication of danger T - Toxic; C - Corrosive
T - Toxic C - Corrosive
Labelling according to EC-guidelines Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
methanol
nitric acid ... %
R phrases
10 Flammable.
34 Causes burns.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
S phrases
07 Keep container tightly closed.
16 Keep away from sources of ignition - No smoking.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
36/37 Wear suitable protective clothing and gloves.
Special labelling for certain preparations
Restricted to professional users.
15.2 National regulations
Employment restrictions Observe employment restrictions for young people.
Water contaminating class 2 - water contaminating
16. Other information
List of relevant R phrases
08 Contact with combustible material may cause fire.
10 Flammable.
11 Highly flammable.
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Sample cuvette, 1/2
Print date : 22.02.2006 Product code : LCK311-1 Page 6 of 6
33 Danger of cumulative effects.
34 Causes burns.
35 Causes severe burns.
50 Very toxic to aquatic organisms.
53 May cause long-term adverse effects in the aquatic environment.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
Other data
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Zero solution, 2/2
Print date : 22.02.2006 Product code : LCK311-2 Page 1 of 6
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation
LCK 311 Chlorid/Chloride/Chlorure, Zero solution, 2/2
Use of the substance/preparation
Water analysis
1.2 Company/undertaking identification
Company name HACH LANGE GmbH
Street Willst盲tterstr. 11
D-40549 D眉sseldorf
Place
Telephone +49(0)2115288 0
Telefax +49(0)2115288143
e-mail info@hach-lange.de
Inquiry office
HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - England
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk
2. Composition/information on ingredients
( preparation )
Chemical characterization
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
213-791-2 7732-18-5 Water <60 %
200-659-6 67-56-1 methanol <36 % F, T R11-23/24/25-39/23/24/25
231-714-2 7697-37-2 nitric acid ... % <5 % O, C R8-35
209-773-0 592-85-8 Mercury(II) thiocyanate <0,1 % T+, N R33-26/27/28-50-53
Full text of each relevant R phrase can be found in heading 16.
3. Hazards identification
Classification
Symbols : Toxic, Corrosive
R-phrases :
Flammable.
Toxic by inhalation, in contact with skin and if swallowed.
Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
4. First aid measures
General information
Take off contaminated clothing and shoes immediately. Show this safety data sheet to the doctor in
attendance.
After inhalation
Move to fresh air. Consult a physician.
After contact with skin
Wash off immediately with plenty of water for at least 15 minutes. Immediate medical treatment is
necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty.
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Zero solution, 2/2
Print date : 22.02.2006 Product code : LCK311-2 Page 2 of 6
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an
unconscious person. Consult a physician.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
water, carbon dioxide (CO2), foam, dry powder
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. In order to avoid contact with skin, keep
a safety distance and wear suitable protective clothing.
Additional information
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material and dispose of as hazardous waste.
7. Handling and storage
7.1 Handling
Advice on safe handling
Use only in well-ventilated areas.
7.2 Storage
Requirements for storage rooms and vessels
Keep tightly closed in a dry, cool and well-ventilated place. Keep locked up or in an area accessible
only to qualified or authorised persons.
8. Exposure controls/personal protection
8.1 Exposure limit values
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Zero solution, 2/2
Print date : 22.02.2006 Product code : LCK311-2 Page 3 of 6
Exposure limits (EH40)
CAS No. Substance ml/m鲁 mg/m鲁 F/ml Category Origin
592-85-8 Mercury(II) thiocyanate 0,1 TWA (8 h)
STEL (15 min)
67-56-1 Methanol 200 266 TWA (8 h) WEL
250 333 STEL (15 min) WEL
7697-37-2 Nitric acid 2 5.2 TWA (8 h) WEL
4 10 STEL (15 min) WEL
BAT values (TRGS 903)
CAS No. Substance Value Parameter Test material Sampling time
67-56-1 Methanol 30 mg/l Methanol U c,b
8.2 Exposure controls
Occupational exposure controls
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Protective and hygiene measures
Wash hands before breaks and at the end of workday.
Respiratory protection
Breathing apparatus only if aerosol or dust is formed.
Hand protection
Use barrier skin cream. The selected protective gloves have to satisfy the specifications of EU
Directive 89/689/EEC and the standard EN 374 derived from it.
Eye protection
safety glasses with side-shields
9. Physical and chemical properties
9.1 General information
Physical state liquid
Colour pink
Odour sweet
9.2 Important health, safety and environmental information
Test method
0,3
pH-Value (at 20 掳C) :
Changes in the physical state
Boiling point 65 掳C
Flash point 24 掳C
Vapour pressure : 128 hPa
at (20 掳C)
Density (at 20 掳C) : ~1 g/cm鲁
completely miscible
Water solubility :
at (20 掳C)
10. Stability and reactivity
Materials to avoid
oxidizing agents,
alkali metals
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Zero solution, 2/2
Print date : 22.02.2006 Product code : LCK311-2 Page 4 of 6
Hazardous decomposition products
No dangerous reaction known under conditions of normal use.
11. Toxicological information
Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.
Severe effects after repeated or prolonged exposure
Concentration above the admissible concentration at the workplace may cause dizziness, headache
and inebriation.
12. Ecological information
Ecotoxicity
May cause long-term adverse effects in the aquatic environment.
Do not flush into surface water or sanitary sewer system.
13. Disposal considerations
Advice on disposal
Our local agencies will accept used cuvettes to ensure their proper disposal.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
ADR/RID class 9
Warning plate
UN number 3316
ADR/RID packing group II
Description of the goods
Chemical kit
Inland waterways transport
Remarks (inland waterways transport)
not tested
Marine transport
IMDG code 9
UN number 3316
Marine pollutant --
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Zero solution, 2/2
Print date : 22.02.2006 Product code : LCK311-2 Page 5 of 6
IMDG packing group II
Description of the goods
Chemical kit
Air transport
ICAO/IATA-DGR 9
UN/ID number 3316
ICAO packing group II
Description of the goods
Chemical kit
Futher Information
This product forms part of a kit. Information in this section relates to the kit as a whole.
15. Regulatory information
15.1 Labelling
Indication of danger T - Toxic
T - Toxic
Labelling according to EC-guidelines Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
methanol
R phrases
10 Flammable.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
S phrases
07 Keep container tightly closed.
16 Keep away from sources of ignition - No smoking.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
36/37 Wear suitable protective clothing and gloves.
15.2 National regulations
Employment restrictions Observe employment restrictions for young people.
Water contaminating class 1 - slightly water contaminating
16. Other information
List of relevant R phrases
08 Contact with combustible material may cause fire.
10 Flammable.
11 Highly flammable.
33 Danger of cumulative effects.
35 Causes severe burns.
50 Very toxic to aquatic organisms.
53 May cause long-term adverse effects in the aquatic environment.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 311 Chlorid/Chloride/Chlorure, Zero solution, 2/2
Print date : 22.02.2006 Product code : LCK311-2 Page 6 of 6
26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
Other data
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
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