World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00511
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Ozone Reagent, Mid Range 0 - 0,75 mg/l O 3
Catalog Number: 2517025
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M00511
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of ozone in water
CAS No.: Not applicable
Hazard: Causes severe eye irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6 131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -0266101029, Netherlands: +31
- -(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Malonic Acid
EEC Number: 2055030
CAS No.: 141 -82-2
Percent Range: 50,0 - 60,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 22 R 36
TLV: Not established
PEL: Not established
3 mg/m 3, Inhalable dust
EU Occupational Exposure Limits:
Potassium Acid Malonate
EEC Number: None
CAS No.: 926 -71-6
Percent Range: 45,0 - 55,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
3 mg/m 3, Inhalable dust
EU Occupational Exposure Limits:
Other component
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White powder
Odor: Acidic
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowe d. R 36: Irritating to eyes.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: gastrointestinal tract irritation convulsions cyanosis ( a reduction of the blood's ability to
carry oxygen, giving a bluish discoloration) difficult breathing
Target Organs (Ing E): None Reported
Inhalation: May ca use: respiratory tract irritation difficult breathing
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre -existing: Eye conditions Respiratory conditions
Chronic Effects: None reported
Cancer / Reproductive Toxicity In formation:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Give 1 -2 glasses of w ater. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing to xic vapors.
Hazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriat e to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pressure -demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. Se e Section 13, Special Instructions for disposal assistance.
Containment Technique: Not applicable
Clean -up Technique: Flush the spilled material to the drain with a large excess of water.
Evacuation Procedure: Evacuate as needed to perform spill clean -up.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Wash thoroughly after handling. Maintain general industrial hygiene practices
when using this p roduct.
Storage: Protect from: light heat moisture Keep away from: oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of ozone in water
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8. EXPO SURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shie lds
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash thoroughly after handling. Protect
from: light hea t moisture Keep away from: oxidizers
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m 3, Inhalable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Phys ical State: Solid
Odor: Acidic
pH: 5% solution = 2,5
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 99掳C; 210掳F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not available
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,6
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n -octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: Not Applicable
Aluminum: Not Applicable
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heat Excess moisture Exposure to light.
Reactivity / Incompatibility: Incompatible with: oxidizers
Hazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFO RMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Malonic acid: Eye rabbit 100 mg - Draize - SEVERE; Skin rabbit 500 mg/24H - Draize -
MILD
Mutation Dat a: Malonic acid - Oncogenic transformation - oral rat - 10080 mg/kg/6W
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Malonic acid Oral rat LD50 = 1310 mg/kg
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of th is product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal re gulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective nati onal regulations. Product packaging must
be disposed of in compliance with the country -specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Sh ipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidia ry Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: NA
A.D.R. Packing Group: NA
Additional In formation: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS or are placed on the
market in quantities less than 10 kg per year.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallo wed. R 36: Irritating to eyes.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
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16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332 -2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992 -1993. American Conference of Governmental Industrial H ygienists, 1992. Vendor Information. CCINFO RTECS.
Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Technical Judgment.
Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989.
R PHRASES: R 22: Harmful if swallowed. R 36: Irritating to eyes.
Use of the substance/preparation: Determination of ozone in water
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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