Wor ld Headquarters
Hach Company
P.O.Box 389 MSDS No: M00494
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Sodium Hydroxide Standard Solution 1,00 N
Catalog Number: 104542
HACH LANGE GmbH Emergency Telephone Numbers:
Willstätterstrasse 11 (Poison Information Center Main)
40549 Düsseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M00494
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Standard solution
CAS No.: Not applicable
Hazard: Causes burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -0266101029, Netherlands: +31
- -(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Hydroxide
EEC Number: 2151855
CAS No.: 1310732
--
Percent Range: 1,0 - 5,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 35
TLV: 2 mg/m³
PEL: 2 mg/m³
2 mg/m 3
EU Occupational Exposure Limits:
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: >95,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: None
EU Symbols: C - CORROSIVE
R PHRASES: R 34: Causes burns.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes burns
Skin Contact (EC): Causes burns
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: burns of the mouth and esophagus vomiting rapi d pulse and respirations shock collapse
Target Organs (Ing E): None Reported
Inhalation: May cause: irritation of nose and throat
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre -existing: Eye conditions Skin con ditions
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic P roducts: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remov e contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Do not induce vomiting. Give 1 -2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Material will not burn.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pressure -demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emerg ency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non -reactive sorbent material. Stop spilled material fr om being
released to the environment.
Clean -up Technique: Cover spilled material with a dry acid, such as citric or boric. Scoop up slurry into a large beaker.
Dilute with a large excess of water. Adjust to a pH between 6 and 9 with an acid, such as sulfuric or citric. Flush reacted
material to the drain with a large excess of water. Decontaminate the area of the spill with a weak acid solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergenc y response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or v apors. Wash thoroughly after handling.
Maintain general industrial hygiene practices when using this product.
Storage: Protect from: heat Keep away from: acids
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Standard solution
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have a safety shower nearby. Have an eyewash station nearby. Maintain general industrial
hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after
handling. Protect from: heat Keep away from: acids/acid fumes
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: None
pH: >14
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: 100°C
Melting Point: Not determined
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,010
Evaporation Rate (water = 1): 0,93
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n -octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,00 in/yr
Aluminum: 20,156 in/yr
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heat Evaporation Exposure to air.
Reactivity / Incompatibility: May react violently in contact with: strong acids
Hazardous Decomposition: No hazardous decomposition products k nown.
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irrita tion Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sodium Hydroxide: Oral rabbit LD = 500 mg/kg
Lo
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this pr oduct.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local e nvironmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country -specific regulation s or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Sodium Hydroxide Solution
--
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1824
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Sodium Hydroxide Solution
--
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1824
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Sodium Hydroxide Solution
--
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: 1824
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: C - CORROSIVE
R PHRASES: R 34: Causes burns.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S
37/39: Wear suitable gloves and eye / face protection. S 45: In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
______________________________________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332 -2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992 -1993. American Conference of Governmental Industrial Hygienists, 1992. Technical Judgment. In -house
information. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Fire
Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: Na tional Fire Protection Association, 1991. List of
Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of
Dangerous Substances, Amended July 1992.
R PHRASES: R 34: Causes burns.
Use of th e substance/preparation: Standard solution
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume /volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BA SED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY ©2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00039
Lov eland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Potassium Persulfate
Catalog Number: 2084766
HACH LANGE GmbH Emergency Telephone Numbers:
Willstätterstrasse 11 (Poison Information Center Main)
40549 Düsseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M00039
Chemical Name: Peroxydisulfuric Acid, Dipotassium Salt
Chemical Formula: K 2S 2O 8
Chemical Family: Oxidizing Agents
Use of the substance/preparation: Laboratory Reagent
CAS No.: 7727 -21-1
Hazard: Causes severe eye irritation. Oxidizer. Allergen
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -0266101029, Netherlands: +31
- -(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
______________________ ________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Potassium Persulfate
EEC Number: 2317818
CAS No.: 7727211
--
Percent Range: 100,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: O - Oxidizing Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 8 R 22
TLV: 5 mg/m 3
PEL: Not established
3 mg/m 3, Inhalable dust
EU Occupational Exposure Limits:
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Ove rview:
Appearance: White to light yellow crystals
Odor: None
EU Symbols: Xn - HARMFUL O - OXIDIZER
R PHRASES: R 8: Contact with combustible material may cause fire. R 22: Harmful if swallowed. R 36/37/38:
Irritating to eyes, respirat ory system and skin. R 42/43: May cause sensitization by inhalation and skin contact.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe irritation
Skin Contact (EC): May cause irritation May cause allergic react ion
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): Harmful
Target Organs (Ing E): None Reported
Inhalation: Causes: irritation of nose and throat May cause: allergic respiratory reaction
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre -existing: Allergies or sensitivity to potassium persulfate.
Chronic Effects: Chronic overexposure may cause allergic skin reactions allergic respiratory reactions
Cancer / Reproductive Toxicity Information:
IARC Listed: No
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Do not induce vomiting. Give 1 -2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Strong oxidizer. Contact with combustible materials may cause a fire. During a fire, this product
decomposes to form toxic gases.
Hazardous Combustion Products: Toxic fumes of: sulfur oxides.
Fire / Explosion Hazards: M ay react violently with: strong reducers combustible materials
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Water.
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pressure -demand and full protective
gear. Evacuate area and fight fire from a safe distance.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
On ly persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from bein g released to the environment. Cover spilled solid material with
sand or other inert material.
Clean -up Technique: Remove all combustible materials from the spill area. Cover with an inert material, such as sand.
Sweep up material. Incinerate mater ial at an E.P.A. approved hazardous waste facility. Decontaminate the area of the spill
with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: a pound or more o f loose powder is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Do not breathe dust. Wash thoroughly after handling. M aintain general
industrial hygiene practices when using this product.
Storage: Keep away from: reducers oxidizable materials Protect from: moisture heat
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Labor atory Reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Use a fume hood to avoid exposure to dust, mist or vapor.
Personal Protective Equipment:
Eye P rotection: safety glasses with top and side shields
Skin / Hand Protection: lab coat disposable latex gloves
Inhalation Protection: laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash tho roughly after handling. Keep
away from: oxidizable materials reducers
TLV: 5 mg/m 3
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m 3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White to light yellow crystals
Physical State: Solid
Odor: None
pH: of 5% solution = 4,1
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: Decomposes at >100°C or 212°F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 2,477
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: 0,0%
Partition Coefficient (n -octanol / water): Not determined
Solubility:
Water: Soluble
Acid: Not determined
Other: Not determined
Metal Corrosivity:
Steel: 0,704 in/yr
Aluminum: 0,137 in/yr
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture Exposure to air. Heating to decomposition.
Reactivity / Incompatibility: May react violently in contact with: oxidizable material reducers
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: sulfur oxides
Hazardous Polymerization: Will not occ ur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: Oral Rat LD50 = 802 mg/kg
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Testing showed only sligh t erythema to rabbit skin.
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: --
Not applicable
IARC Listed: No
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
Not applicable
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guide lines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compli ance with the respective national regulations. Product packaging must
be disposed of in compliance with the country -specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Potassium Persulphate
--
ICAO Hazard Class: 5,1
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1492
ICAO Packing Group: III
I.M.O.:
I.M.O. Proper Shipping Name: Potassium Persulphate
--
I.M.O. Hazard Class: 5,1
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1492
I.M.O. Packing Group: III
A.D.R.:
A.D.R. Proper Shipping Name: Potassium Persulphate
--
A.D.R Hazard Class: 5,1
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: 1492
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Prop er Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: EINECS Listed: Yes
EEC Number: 2317818
EEC LABEL COPY:
EU Symbols: Xn - HARMFUL O - OXIDIZER
R PHRASES: R 8: Contact with combustible material may cause fire. R 22: Harmful if swallowed. R 36/37/38:
Irritating to eyes, respiratory system and skin. R 42/43: May cause sensitization by inhalation and skin contact.
S PHRASES: S 22: Do not breathe dust. S 24: Avoid contact with skin. S 26: In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. S 37: Wear suitable gloves.
____________________________ __________
16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992 -1993. American Conference of
Governmental Industrial Hygienists, 1992. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., I nc., 1989.
Technical Judgment. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand
Reinhold Co., 1989. List of Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification,
Packagi ng and Labeling of Dangerous Substances, Amended July 1992. In -house information. Fire Protection Guide on
Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Fire Protection Guide on Hazardous Materials, 10th
Ed. Quincy, MA: National Fire Protection Association, 1991. CCINFO RTECS. Canadian Centre for Occupational
Health and Safety. Hamilton, Ontario Canada: 30 June 1993. CCINFO MSDS/FTSS. Canadian Centre for Occupational
Health and Safety. Hamilton, Ontario Canada: 30 June 199 3. Air Contaminants, Federal Register, Vol. 54, No. 12.
Thursday, January 19, 1989. pp. 2332 -2983. 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor).
R PHRASES: R 8: Contact with combustible material may cause fire. R 22: Harmful if swall owed. R 36/37/38:
Irritating to eyes, respiratory system and skin. R 42/43: May cause sensitization by inhalation and skin contact.
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
____________ ___________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and un derstand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY ©2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00035
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: PhosVer ® 3 Phosphate Reagent
Catalog Number: 2106046
HACH LANGE GmbH Emergency Telephone Numbers:
Willstätterstrasse 11 (Poison Information Center Main)
40549 Düsseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M00035
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Phosphate determination
CAS No.: Not applicable
Hazard: Causes eye burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: + 49 (0)6131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -0266101029, Netherlands: +31
- -(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Potassium Pyrosulfate
EEC Number: 2322168
CAS No.: 7790627
--
Percent Range: 75,0 - 85,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xi - IRRITATING
Ingredient R phrase(s) (R phrase details given in Heading 16): R 41
TLV: Not established
PEL: Not established
3 mg/m 3, Inhalable dust
EU Occupational Exposure Limits:
Ascorbic Acid
EEC Number: 2000662
CAS No.: 50817
--
Percent Range: 15,0 - 25,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not appl icable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
3 mg/m 3, Inhalable dust
EU Occupational Exposure Limits:
Sodium Molybdate
EEC Number: 2315517
CAS No.: 10102 -40-6
Percent Range: 1,0 - 10,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 5 mg/m³ (as Mo)
PEL: 5 mg/m³ (as Mo)
EU Occupational Exposur e Limits: 5 mg/m 3 as Mo
Other components, each
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: 0,1 - 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
3. HAZARDS IDENTIFICATION
Emergenc y Overview:
Appearance: White to off -white powder
Odor: None
EU Symbols: Xi - IRRITATING
R PHRASES: R 41: Risk of serious damage to eyes.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe irritation
Skin Contact (EC): No effects are anticipated
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: copper deficiency anemia gout loss of appetite loss of coordination listlessness
diarrhea liver damage May effect enzyme activity.
Target Organs (Ing E): Blood Liver
Inhalation: May cause: irritation of nose and throat Effects similar to those of ingestion.
Target Organs (Inh E): Blood Liver
Medical Conditions Aggravated: Pre -existing: Eye conditions Respiratory conditions Gout
Chronic Effects: Chronic overexposure may cause copper deficiency enzyme activity effects liver damage
Molybdenum poisoning signs include loss of appetite, listlessness and reduced growt h rate. Excessive exposure to
molybdenum compounds may cause gout and anemia.
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid ): Wash skin with plenty of water.
Ingestion (First Aid): Do not induce vomiting. Give 1 -2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Give artificial r espiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: sulfur oxides. carbon mon oxide, carbon dioxide. sodium monoxide
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NO T To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pressure -demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean -up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an alkali, such as soda ash or sodium bicarbonate. Flush re acted material to the drain with a large excess of water.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantit y is spilled.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrial
hygiene practices when using this product.
Storage: Store between 10° and 25°C.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Phosphate determination
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab cot a
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling.
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m 3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White to off -white powder
Physical State: Solid
Odor: None
pH: of a 5% solution = 1,5
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 105 °C (221 °F)
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 2,22
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n -octanol / water): Not applicable
Solubility:
Water: Solu ble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: Not Applicable
Aluminum: Not Applicable
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures
Reactivity / Incompatibility: Incompatible with: oxidizers dyes alkalies iron copper
Hazardous Decomposition: Heating to decomposition releases: carbon dioxide carbon monoxide sulfur oxides
Haza rdous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
Ingredient Toxicological Data: Potassium Pyrosulfate Oral rat LD50 = 2340 mg/kg; Sodium Molybdate Oral rat LD50 =
3
4000 mg/kg, Inhalation rat LC50 > 2080mg/m /4 hr; A scorbic Acid Oral rat LD50 = 11.9 g/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These d isposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country -specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xi - IRRITATING
R PHRASES: R 41: Risk of serious damage to eyes.
S PHRASES: S 26: In case of contact with eye s, rinse immediately with plenty of water and seek medical advice. S
37/39: Wear suitable gloves and eye / face protection.
______________________________________
16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposu re Indices for 1992 -1993. American Conference of
Governmental Industrial Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19,
1989. pp. 2332 -2983. In -house information. Technical Judgment. Outside Testing. NI SH/OSHA Occupational Health
O
Guidelines for Chemical Hazards. Cincinnati: Department of Health and Human Services, 1981. Sax, N. Irving.
Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. Gosselin, R. E. et al.
Clinical Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Vendor
Information. Patty, Frank A. Industrial Hygiene and Toxicology, 3rd Revised Edition. Volume 2. New York: A Wiley -
Interscience Publicat ion, 1981.
R PHRASES: R 41: Risk of serious damage to eyes.
Use of the substance/preparation: Phosphate determination
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applica ble hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE T HEREOF.
HACH COMPANY ©2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M01616
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Phosphate Acid Reagent Vials
Catalog Number: 2742900
HACH LANGE GmbH Emergency Telephone Numbers:
Willstätterstrasse 11 (Poison Information Center Main)
40549 Düsseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M01616
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Standard solution
CAS No.: Not applicable
Hazard: Causes ey e burns. Harmful if inhaled. Carcinogen.
Date of MSDS Preparation:
Day: 13
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -0266101029, Netherlands: +31 -(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: 90,0 - 100,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Sulfuric Acid
EEC Number: 2316395
CAS No.: 7664939
--
Percent Range: 1,0 - 5,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Xi - IRRITATING
Ingredient R phrase(s) (R phrase details given in Heading 16): R 36
TLV: 1 mg/m³ (TWA) ; 3 mg/m³ (STEL)
PEL: 1 mg/m³
0,1 mg/m 3
EU Occupational Exposure Limits:
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: None
EU Symbols: Xi - IRRITATING
R PHRASES: R 36: Irritating to eyes.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes irritation
Skin Contact (EC): No effects are anticipated
Skin Absorption (EC): None Reported
Target Organs (SA E): Not applicable
Ingestion (EC): Causes: irritation of the mouth and esophagus May cause: vomiting diarrhea
Target Organs (Ing E): None Reported
Inhalation: May cause: respiratory tract irritation teeth erosion mouth soreness difficult breathing
Target Organs (Inh E): Lungs
Medical Conditions Aggravated: Pre -existing: Eye conditions Respiratory conditions
Chronic Effects: Chronic overexposure may cause erosion of the teeth chronic irritation or inflammation of the lungs
cancer
Cancer / Reproductive Toxicity Information:
An ingredient of this mixture is: IARC Group 1: Recognized Carcinogen
Sulfuric Acid - The IARC evaluation was based on exposure to the mist or vapor of concentrated sulfuric acid
generated dur ing chemical processes.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water.
Ingestion (First Aid): Do not induce vomiting. Give 1 -2 glasses of water. Call physician immediately. Never give
anything by mouth to an uncon scious person.
Inhalation: Remove to fresh air.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Material will not burn. During a fire, irritating and highly toxic gases may be generated by
thermal decomposition.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: This product will not burn or explode.
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear sel f-contained breathing apparatus pressure -demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous s ubstances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non -reactive sorbent material. Stop spilled material from being
released to the e nvironment.
Clean -up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Scoop up slurry into
a large beaker. Dilute with a large excess of water. Adjust to a pH between 6 and 9. Use sulfuric or citric acid to l ower pH.
Use soda ash or sodium bicarbonate to increase pH. Flush reacted material to the drain with a large excess of water.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as di rected by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation. If conditions warrant, increase the
size of the evacuation.
______________________________________
7. HANDLI NG AND STORAGE
Handling: Avoid contact with eyes Do not breathe mist or vapors. Use with adequate ventilation. Wash thoroughly
after handling. Maintain general industrial hygiene practices when using this product.
Storage: Store between 10° an d 25°C.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Standard solution
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearb y. Use general ventilation to minimize exposure to mist, vapor or
dust. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: mist/vapor Use with adequate ventilation.
Protect from: heat
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: None
pH: Not determined
Vapor Pressu re: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: Not determined
Melting Point: Not applicable
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): Not determined
Evaporation Rate (water = 1): Not determined
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n -octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Not determined
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures Heating to decomposition.
Reactivity / Incompatibility: Incompatible with: alkalies oxidizers reducers
Hazardous Decomposition: Heatin g to decomposition releases toxic and/or corrosive fumes of: sulfur oxides
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: Non e reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Skin irritation testing performed on 10% sulfuric acid showed SLIGHT to NO
IRRITATION effects
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sulfuric acid: oral rat LD50 = 2140 mg/kg; inhalation rat LC50 = 87 ppm/4h
An ingredient of this mixture is: IARC Group 1: Recognized Carcinogen
Sulfuric Acid - The IARC evaluation was based on exposure to the mist or vapor of concentrated sulfuric acid generated
during chemical processes.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on feder al regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country -specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Prop er Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(<10 % Sulphuric Acid Solution)
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN3264
ICAO Packing Group: III
I.M.O.:
I.M.O. Proper Shipping Name: Corrosive Liqui d, Acidic, Inorganic, N.O.S.
(<10 % Sulphuric Acid Solution)
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN3264
I.M.O. Packing Group: III
A.D.R.:
A.D.R. Proper Shipping Name: Corrosive Liquid, Acidic, Inorganic, N.O.S.
(< 10 % Sulphuric Acid Solution)
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: 3264
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part o f a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
____________________ __________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xi - IRRITATING
R PHRASE S: R 36: Irritating to eyes.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
______________________________________
16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992 -1993. American Conference of
Governmental Industrial Hygienists, 1992. In -house information. Technical Judgment. Air Contaminants, Federal
Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332 -2983. Vendor Information. IARC Monographs on the
Evaluation of the Carcinogenic Risks to Humans. World Health Organization (Volumes 1 -42) Supplement 7. France:
1987.
R PHRASES: R 36: Irritating to eyes.
Use of the substance/preparation: Standard solution
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBIL ITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY ©2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M01622
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Sodium Hydroxide Solution, 1,54N
Catalog Number: 2743042
HACH LANGE GmbH Emergency Telephone Numbers:
Willstätterstrasse 11 (Poison Information Center Main)
40549 Düsseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M01622
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Standard solution
CAS No.: Not applicable
Hazard: Causes severe burns.
Date of MSDS Preparation:
Day: 13
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -0266101029, Netherlands: +31
- -(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
_________________________________ _____
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Hydroxide
EEC Number: 2151855
CAS No.: 1310732
--
Percent Range: 5,0 - 15,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 35
TLV: 2 mg/m³
PEL: 2 mg/m³
2 mg/m 3
EU Occupational Exposure Limits:
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: > 90,0
Percent Range Units: vo / volume
lume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
____________________ __________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: None
EU Symbols: C - CORROSIVE
R PHRASES: R 35: Causes severe burns.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe burns
Skin Contact (EC): Causes severe burns
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): Causes: severe burns vomiting rapid pulse and respirations shock col lapse death
Target Organs (Ing E): None Reported
Inhalation: Causes: severe burns
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre -existing: Eye conditions Skin conditions Respiratory conditions
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contamin ated clothing. Call physician
immediately.
Ingestion (First Aid): Do not induce vomiting. Give 1 -2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air.
________ ______________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Material will not burn.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pre ssure -demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Absorb spilled liquid with non -reactive sorbent material. Stop spilled material from being
released to the environment.
Clean -up Technique: Cover spilled material with a dry acid, such as citric or boric. Scoop up slurry into a large beaker.
Dilute with a large excess of water. Adjust to a pH between 6 and 9 with an acid, such as sulfuric or citric. Flush reacted
material to the drain wit h a large excess of water. Decontaminate the area of the spill with a weak acid solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditio ns warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.
Maintain general ind ustrial hygiene practices when using this product.
Storage: Protect from: heat Keep away from: acids
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Standard solution
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have a safety shower nearby. Have an eyewash station nearby. Maintain general industrial
hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly afte r
handling. Protect from: heat Keep away from: acids/acid fumes
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: None
pH: >13
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: Not determined
Melting Point: Not applicable
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): Not determined
Evaporation Rate (water = 1): Not determined
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n -octanol / water): Not applicable
Solubility:
Water: Miscible
Acid: Reacts with acid
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not deter mined
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heat Evaporation Exposure to air.
Reactivity / Incompatibility: May react violently in contact with: strong acids Incompatible with: halogenated organic
compounds tin aluminum zinc nitro compounds
Hazardous Decomposition: No hazardous decomposition products known.
Hazardous Polymerization: Will not occur.
_______________ _______________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sodium Hydroxide: Oral rat LDLo = 500 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATI ON
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CO NSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemi cal
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country -specific regulations or must be passed to a packaging return system.
_____________________________________
_
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Sodium Hydroxide Solution
--
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1824
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Sodium Hydroxide Solution
--
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1824
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Sodium Hydroxide Solution
--
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: 1824
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purpos es. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: C - CORROSIVE
R PHRASES: R 35: Causes severe burns.
S PHRASES: S 26: In case of contact with eyes, rinse immedia tely with plenty of water and seek medical advice. S
37/39: Wear suitable gloves and eye / face protection. S 45: In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
___________________________ ___________
16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332 -2983. TLV's Threshold Limit Values and Biological Exposure Indices for
1992 -1993. American Conference of Governmental Industrial Hygienists, 1992. Technical Judgment. In -house
information. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Fire
Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: Na tional Fire Protection Association, 1991. List of
Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of
Dangerous Substances, Amended July 1992.
R PHRASES: R 35: Causes severe burns.
Use of the substance/preparation: Standard solution
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREI N IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY ©2006
|