World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00127
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Ammonia Salicylate Reagent
Catalog Number: 2653299
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00127
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Reagent for ammonia test
CAS No.: Not applicable
Hazard: May cause irritation. Harmful if swallowed
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
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(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Salicylate
EEC Number: 2001980.
CAS No.: 54217
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Percent Range: 40,0 - 50,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 22
TLV: Respirable particles: 3 mg/m3; Inhalable particles: 10 mg/m3
PEL: Total dust: 15 mg/m3; Respirable fraction: 5 mg/m3
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Nitroferricyanide
EEC Number: 2383739
CAS No.: 14402-89-2
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 5 mg/m鲁 as CN炉
PEL: 5 mg/m鲁 as CN炉
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust. Cyanides are on the Priority List for OELs.
Other components, each
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: 0,1 - 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Sodium Citrate
EEC Number: 2006753
CAS No.: 68042
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Percent Range: 40,0 - 50,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Tartrate
EEC Number: 2127733
CAS No.: 6106247
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Percent Range: 10,0 - 20,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Tan powder
Odor: None
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): Harmful if absorbed through the skin Effects similar to those of ingestion Sodium
nitroferricyanide produces a delayed cyanide poisoning reaction.
Target Organs (SA E): Central nervous system Blood
Ingestion (EC): Sodium nitroferricyanide produces a delayed cyanide poisoning reaction. May cause: headache
nausea vomiting central nervous system effects
Target Organs (Ing E): Central nervous system Blood
Inhalation: Sodium nitroferricyanide produces a delayed cyanide poisoning reaction. May cause: headache nausea
vomiting central nervous system effects
Target Organs (Inh E): Central nervous system Blood
Medical Conditions Aggravated: Allergies or sensitivity to aspirin or salicylates.
Chronic Effects: Chronic overexposure may cause confusion diarrhea fatigue weakness death Salicylates may
cause ringing in the ears (tinnitus), abnormal bleeding, gastric ulceration, mental deterioration, skin eruption, temporary
vision loss, and other optical effects.
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen. an experimental
teratogen.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Remove contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Induce vomiting using syrup of ipecac or by sticking finger down throat. Never give anything by
mouth to an unconscious person. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, this product decomposes to form toxic gases.
Hazardous Combustion Products: May emit acrid smoke and fumes.
Fire / Explosion Hazards: This product will not burn or explode.
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Dry chemical. Carbon dioxide Alcohol foam.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear. Evacuate area and fight fire from a safe distance.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances shoul respond to a spill
d
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Stop spilled material from being
released to the environment.
Clean-up Technique: Avoid contact with spilled material. Sweep up material. Dilute with a large excess of water. Flush
the spilled material to the drain with a large excess of water. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Store between 10掳 and 25掳C. Keep away from: acids / acid fumes. oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Reagent for ammonia test
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Use a fume hood to avoid exposure to dust, mist or vapor.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: lab coat disposable latex gloves
Inhalation Protection: laboratory fume hood
Precautionary Measures: eyes skin clothing Do not breathe: dust Wash thoroughly after handling. Use with adequate
ventilation. Keep away from: acids/acid fumes oxidizers
TLV: Not established.
PEL: Not established.
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Tan powder
Physical State: Solid
Odor: None
pH: 7,84 (5% solution)
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 97掳C (206,6掳F)
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined.
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,689
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: None.
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble.
Acid: Soluble.
Other: Not determined.
Metal Corrosivity:
Steel: Not applicable
Aluminum: Not applicable
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heating to decomposition. Extreme temperatures
Reactivity / Incompatibility: Incompatible with: acids iodine iron salts lead acetate organic materials oxidizers silver
nitrate sodium phosphate
Hazardous Decomposition: Contact with acids/acid fumes releases toxic cyanide gas. Heating to decomposition releases
toxic and/or corrosive fumes of: cyanide nitrogen oxides sodium oxides
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported.
LC50: None reported.
Dermal Toxicity Data: None reported.
Skin and Eye Irritation Data: None reported.
Mutation Data: None reported.
Reproductive Effects Data: None reported.
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Ingredient Toxicological Data: Sodium Salicylate: Oral rat LD50 = 1200 mg/kg; Sodium Citrate: Oral rat LD50 > 8 g/kg;
Sodium Tartrate: Oral rabbit LD50 = 5290 mg/kg; Sodium Nitroferricyanide: Oral rat LD50 = 99 mg/kg.
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
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ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
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I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
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A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed.
S PHRASES: S 24/25: Avoid contact with skin and eyes. S 37: Wear suitable gloves.
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16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of
Governmental Industrial Hygienists, 1992. Technical Judgment. Sixth Annual Report on Carcinogens, 1991. U.S.
Department of Health and Human Services. Rockville, MD: Technical Resources, Inc. 1991. Sax, N. Irving. Dangerous
Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. List of Dangerous Substances
Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of Dangerous Substances,
Amended July 1992. In-house information. IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans.
World Health Organization (Volumes 1-42) Supplement 7. France: 1987. Gosselin, R. E. et al. Clinical Toxicology of
Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Cassaret and Doull's Toxicology, 3rd Ed.
New York: Macmillan Publishing Co., Inc., 1986. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday,
January 19, 1989. pp. 2332-2983. 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor).
R PHRASES: R 22: Harmful if swallowed.
Use of the substance/preparation: Reagent for ammonia test
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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