World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00110
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: DPD Total Chlorine Reagent
Catalog Number: 2503025
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00110
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Indicator for total chlorine
CAS No.: Not applicable
Hazard: May cause sensitizaton. May cause irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Potassium Iodide
EEC Number: 2316594
CAS No.: 7681110
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Percent Range: 20,0 - 30,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Salt of N,N-Diethyl-p-Phenylenediamine
EEC Number: Confidential
CAS No.: Confidential
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 22 R 36 R 52/53
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Phosphate, Dibasic
EEC Number: 2314487
CAS No.: 7558794
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Percent Range: 20,0 - 30,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Other component
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: 0,1 - 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Carboxylate Salt
EEC Number: Confidential
CAS No.: Confidential
Percent Range: 40,0 - 50,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White or light pink powder
Odor: None
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation May cause allergic reaction
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): Causes: lethargy loss of strength loss of coordination difficult breathing diarrhea May cause
iodism, which symptoms include skin rash, conjunctivitis, runny nose, sneezing, bronchitis, headache, fever and irritation
of mucous membranes. DPD LD50 studies revealed decreased locomotor activity, depressed respiration, muscle spasms,
loss of righting reflex and death. Autopsies revealed ulcerated stomach, enteritis, gas and congested lungs.
Target Organs (Ing E): Liver
Inhalation: May cause: respiratory tract irritation Effects similar to those of ingestion.
Target Organs (Inh E): Liver
Medical Conditions Aggravated: Allergy or sensitivity to salts of N,N-Diethyl-p-phenylenediamine Pre-existing: Eye
conditions Skin conditions Respiratory conditions Persons with pre-existing respiratory conditions may be more
susceptible to the effects of Potassium Iodide exposure.
Chronic Effects: Chronic overexposure may cause allergic skin reactions hypothyroidism liver damage DPD may
cause allergic skin reactions in some people causing severe skin rashes and itching. Iodines overdose, 'iodism', may
cause skin rash, runny nose, headaches, fever and bronchitis.
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Maternal ingestion of potassium iodide during pregnancy
may cause congenital goiter and hyperthyroidism in the newborn infant.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Call physician immediately. Give 1-2 glasses of water under medical supervision. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air.
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5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, this product decomposes to form toxic gases.
Hazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide. iodine compounds phosphorus
oxides potassium oxides sodium monoxide nitrogen oxides.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Flush reacted material to the
drain with a large excess of water. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of the
evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Store between 10掳 and 25掳C. Protect from: light heat moisture
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Indicator for total chlorine
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Use general ventilation to minimize exposure to mist, vapor or
dust.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Protect from: light heat moisture
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White or light pink powder
Physical State: Solid
Odor: None
pH: of 1% soln = 6,35 @ 20掳C
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 145掳 C
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,79
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not determined
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,038 in/yr
Aluminum: 0,006 in/yr
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Exposure to light. Excess moisture Extreme temperatures
Reactivity / Incompatibility: Incompatible with: oxidizers
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: carbon dioxide carbon
monoxide iodine compounds phosphorus oxides potassium oxide nitrogen oxides
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: Oral rat (female) LD50 = 4700 mg/kg; Oral rat (male) LD50 = 7000 mg/kg.
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: DPD Oral rat LD50 = 970 mg/kg; Potassium Iodide Oral mouse LDLo = 1862 mg/kg;
Sodium Phosphate, Dibasic Oral rat LD50 = 17 g/kg
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
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ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
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I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS or are placed on the
market in quantities less than 10 kg per year.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
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16. OTHER INFORMATION
References: CCINFO MSDS/FTSS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada:
30 June 1993. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. Outside Testing. Technical
Judgment. In-house information. TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993.
American Conference of Governmental Industrial Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12.
Thursday, January 19, 1989. pp. 2332-2983.
R PHRASES: Not applicable
Use of the substance/preparation: Indicator for total chlorine
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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