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MSDS Material Safety Data Sheet
CAS

7732-18-5
64-17-5
1310-58-3

File Name: camlab_co_uk---hh_lck308.asp
                                                                                                                  HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, Analysenküvette; 1/3
Print date : 22.02.2006 Product code : LCK308-1 Page 1 of 5

1. Identification of the substance/preparation and of the company/undertaking

1.1 Identification of the substance or preparation
LCK 308 Cadmium, Analysenküvette; 1/3
Use of the substance/preparation
Water analysis
1.2 Company/undertaking identification
Company name HACH LANGE GmbH
Street Willstätterstr. 11
D-40549 Düsseldorf
Place
Telephone +49(0)2115288 0
Telefax +49(0)2115288143
e-mail info@hach-lange.de
Inquiry office
HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - England
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk

2. Composition/information on ingredients

( preparation )
Chemical characterization


Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification

213-791-2 7732-18-5 Water >70 %
200-578-6 64-17-5 ethanol, ethyl alcohol 25 % F R11
215-181-3 1310-58-3 caustic potash, potassium hydroxide <2 % Xn, C R22-35

Full text of each relevant R phrase can be found in heading 16.

3. Hazards identification

Classification
Symbols : Irritant
R-phrases :
Flammable.
Irritating to eyes and skin.

4. First aid measures

General information
Take off contaminated clothing and shoes immediately.
Show this safety data sheet to the doctor in attendance.
After inhalation
Move to fresh air.
If symptoms persist, call a physician.
After contact with skin
Wash off immediately with plenty of water for at least 15 minutes.
If skin irritation persists, call a physician.
After contact with eyes


Revision no. : 1,01 GB - EN Revision date : 05.07.2005
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, Analysenküvette; 1/3
Print date : 22.02.2006 Product code : LCK308-1 Page 2 of 5
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After ingestion
Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an
unconscious person. Obtain medical attention.
Advice to doctor
Treat symptomatically.

5. Fire-fighting measures

Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.
In the event of fire, wear self-contained breathing apparatus.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.

6. Accidental release measures

Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

7. Handling and storage

7.1 Handling
Advice on safe handling
Use only in well-ventilated areas. Avoid contact with skin and eyes.
7.2 Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a dry and well-ventilated place.
Keep away from heat and sources of ignition.
Further information on storage conditions
Keep locked up or in an area accessible only to qualified or authorised persons.

8. Exposure controls/personal protection

8.1 Exposure limit values




Revision no. : 1,01 GB - EN Revision date : 05.07.2005
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, Analysenküvette; 1/3
Print date : 22.02.2006 Product code : LCK308-1 Page 3 of 5

Exposure limits (EH40)
CAS No. Substance ml/m³ mg/m³ F/ml Category Origin

64-17-5 Ethanol 1000 1920 TWA (8 h) WEL
- - STEL (15 min) WEL
1310-58-3 Potassium hydroxide - - TWA (8 h) WEL
- 2 STEL (15 min) WEL

8.2 Exposure controls
Occupational exposure controls
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Protective and hygiene measures
Wash hands before breaks and at the end of workday.
Respiratory protection
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of
local exhaust ventilation and good general extraction.
Hand protection
Use barrier skin cream.
The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the
standard EN 374 derived from it.
Eye protection
safety glasses with side-shields
Skin protection
Avoid contact with skin, eyes and clothing.
9. Physical and chemical properties

9.1 General information
Physical state liquid
Colour violet
Odour sweet
9.2 Important health, safety and environmental information
Test method
>10
pH-Value (at 20 °C) :
Changes in the physical state
Flash point 28 °C
Lower explosion limits not applicable
Upper explosion limits not applicable
Density (at 20 °C) : 0,96 g/cm³
soluble
Water solubility :
at (20 °C)

10. Stability and reactivity

Conditions to avoid
Heat, flames and sparks.
Additional information
Stable under recommended storage conditions.

11. Toxicological information

Revision no. : 1,01 GB - EN Revision date : 05.07.2005
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, Analysenküvette; 1/3
Print date : 22.02.2006 Product code : LCK308-1 Page 4 of 5

Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.

12. Ecological information

Ecotoxicity
No information on ecology is available.

13. Disposal considerations

Advice on disposal
In accordance with local and national regulations.
Our local agencies will accept used cuvettes to ensure their proper disposal.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.

14. Transport information

Land transport (ADR/RID)
ADR/RID class 9
Warning plate
UN number 3316
ADR/RID packing group II
Description of the goods
Chemical kit
Inland waterways transport
Remarks (inland waterways transport)
not tested
Marine transport
IMDG code 9
UN number 3316
EmS F-A,S-A
IMDG packing group II
Description of the goods
Chemical kit
Air transport
ICAO/IATA-DGR 9
UN/ID number 3316

Revision no. : 1,01 GB - EN Revision date : 05.07.2005
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, Analysenküvette; 1/3
Print date : 22.02.2006 Product code : LCK308-1 Page 5 of 5
ICAO packing group II
Description of the goods
Chemical kit
Futher Information
This product forms part of a kit. Information in this section relates to the kit as a whole.

15. Regulatory information

15.1 Labelling
Indication of danger Xi - Irritant




Xi - Irritant
Labelling according to EC-guidelines Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
caustic potash, potassium hydroxide
R phrases
10 Flammable.
36/38 Irritating to eyes and skin.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37/39 Wear suitable gloves and eye/face protection.
15.2 National regulations
Employment restrictions Observe employment restrictions for young people.; Observe employment
restrictions for child bearing mothers and nursing.
Water contaminating class 1 - slightly water contaminating

16. Other information

List of relevant R phrases
10 Flammable.
11 Highly flammable.
22 Harmful if swallowed.
35 Causes severe burns.
36/38 Irritating to eyes and skin.
Other data
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)




Revision no. : 1,01 GB - EN Revision date : 05.07.2005
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 A; 2/3
Print date : 22.02.2006 Product code : LCK308-2 Page 1 of 6

1. Identification of the substance/preparation and of the company/undertaking

1.1 Identification of the substance or preparation
LCK 308 Cadmium, LCK 308 A; 2/3
Use of the substance/preparation
Water analysis
1.2 Company/undertaking identification
Company name HACH LANGE GmbH
Street Willstätterstr. 11
D-40549 Düsseldorf
Place
Telephone +49(0)2115288 0
Telefax +49(0)2115288143
e-mail info@hach-lange.de
Inquiry office
HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - England
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk

2. Composition/information on ingredients

( preparation )
Chemical characterization


Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification

213-791-2 7732-18-5 Water >95 %
205-792-3 151-50-8 Potassium cyanide 3 % T+, N R32-26/27/28-50-53
215-181-3 1310-58-3 caustic potash, potassium hydroxide <2 % Xn, C R22-35

Full text of each relevant R phrase can be found in heading 16.

3. Hazards identification

Classification
Symbols : Toxic, Corrosive, Harmful, Irritant, Dangerous for the environment
R-phrases :
Contact with acids liberates very toxic gas.
Toxic by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

4. First aid measures

General information
Take off contaminated clothing and shoes immediately.
Show this safety data sheet to the doctor in attendance.
After inhalation
Move to fresh air.
If symptoms persist, call a physician.
After contact with skin
Wash off immediately with plenty of water for at least 15 minutes.
If skin irritation persists, call a physician.

Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 A; 2/3
Print date : 22.02.2006 Product code : LCK308-2 Page 2 of 6

After contact with eyes
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After ingestion
Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an
unconscious person. Obtain medical attention.
Advice to doctor
Treat symptomatically.

5. Fire-fighting measures

Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.
In the event of fire, wear self-contained breathing apparatus.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.

6. Accidental release measures

Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

7. Handling and storage

7.1 Handling
Advice on safe handling
Use only in well-ventilated areas. Avoid contact with skin and eyes.
7.2 Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a dry and well-ventilated place.
Further information on storage conditions
Keep locked up or in an area accessible only to qualified or authorised persons.

8. Exposure controls/personal protection

8.1 Exposure limit values




Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 A; 2/3
Print date : 22.02.2006 Product code : LCK308-2 Page 3 of 6

Exposure limits (EH40)
CAS No. Substance ml/m³ mg/m³ F/ml Category Origin

1310-58-3 Potassium hydroxide - - TWA (8 h) WEL
- 2 STEL (15 min) WEL

8.2 Exposure controls
Occupational exposure controls
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Protective and hygiene measures
Wash hands before breaks and at the end of workday.
Respiratory protection
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of
local exhaust ventilation and good general extraction.
Hand protection
Use barrier skin cream.
The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the
standard EN 374 derived from it.
Eye protection
safety glasses with side-shields
Skin protection
Avoid contact with skin, eyes and clothing.
9. Physical and chemical properties

9.1 General information
Physical state liquid
Colour colourless
Odour odourless
9.2 Important health, safety and environmental information
Test method
13
pH-Value (at 20 °C) :
Changes in the physical state
Flash point not applicable
Explosive properties
not applicable
Density (at 20 °C) : 1,04 g/cm³
soluble
Water solubility :
at (20 °C)

10. Stability and reactivity

Materials to avoid
acids
Hazardous decomposition products
hydrogen cyanide (hydrocyanic acid)
Additional information
Stable under recommended storage conditions.

11. Toxicological information

Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 A; 2/3
Print date : 22.02.2006 Product code : LCK308-2 Page 4 of 6

Acute toxicity
Contact with acids liberates toxic gas.
Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.

12. Ecological information

Ecotoxicity
No information on ecology is available.

13. Disposal considerations

Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Contaminated packaging
In accordance with local and national regulations. Our local agencies will accept used cuvettes to
ensure their proper disposal.

14. Transport information

Land transport (ADR/RID)
ADR/RID class 9
Warning plate
UN number 3316
ADR/RID packing group II
Description of the goods
Chemical kit
Inland waterways transport
Remarks (inland waterways transport)
not tested
Marine transport
IMDG code 9
UN number 3316
Marine pollutant --
EmS F-A,S-A
IMDG packing group II
Description of the goods
Chemical kit


Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 A; 2/3
Print date : 22.02.2006 Product code : LCK308-2 Page 5 of 6

Air transport
ICAO/IATA-DGR 9
UN/ID number 3316
ICAO packing group II
Description of the goods
Chemical kit
Futher Information
This product forms part of a kit. Information in this section relates to the kit as a whole.

15. Regulatory information

15.1 Labelling
Indication of danger T - Toxic; N - Dangerous for the environment




T - Toxic N - Dangerous for the
environment
Labelling according to EC-guidelines Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
caustic potash, potassium hydroxide
Potassium cyanide
R phrases
32 Contact with acids liberates very toxic gas.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
36/38 Irritating to eyes and skin.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
35 This material and its container must be disposed of in a safe way.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
37/39 Wear suitable gloves and eye/face protection.
15.2 National regulations
Employment restrictions Observe employment restrictions for young people.; Observe employment
restrictions for child bearing mothers and nursing.
Water contaminating class 3 - highly water contaminating

16. Other information

List of relevant R phrases
22 Harmful if swallowed.
32 Contact with acids liberates very toxic gas.
35 Causes severe burns.
50 Very toxic to aquatic organisms.
53 May cause long-term adverse effects in the aquatic environment.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.
36/38 Irritating to eyes and skin.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 A; 2/3
Print date : 22.02.2006 Product code : LCK308-2 Page 6 of 6
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Other data
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)




Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 B; 3/3
Print date : 22.02.2006 Product code : LCK308-3 Page 1 of 6

1. Identification of the substance/preparation and of the company/undertaking

1.1 Identification of the substance or preparation
LCK 308 Cadmium, LCK 308 B; 3/3
Use of the substance/preparation
Water analysis
1.2 Company/undertaking identification
Company name HACH LANGE GmbH
Street Willstätterstr. 11
D-40549 Düsseldorf
Place
Telephone +49(0)2115288 0
Telefax +49(0)2115288143
e-mail info@hach-lange.de
Inquiry office
HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - England
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk

2. Composition/information on ingredients

( preparation )
Chemical characterization


Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification

213-791-2 7732-18-5 Water >70 %
200-001-8 50-00-0 formaldehyde ...% <13 % Carc. Cat. 3, T, C
R40-23/24/25-34-43
200-659-6 67-56-1 methanol <4 % F, T R11-23/24/25-39/23/24/25
231-793-3 7446-20-0 Zinc sulfate heptahydrate 0,2 % Xn, N R22-41-50/53

Full text of each relevant R phrase can be found in heading 16.

3. Hazards identification

Classification
Symbols : Harmful, Irritant
R-phrases :
Limited evidence of a carcinogenic effect.
May cause sensitization by skin contact.
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.

4. First aid measures

General information
Take off contaminated clothing and shoes immediately.
Show this safety data sheet to the doctor in attendance.
After inhalation
Move to fresh air.
If symptoms persist, call a physician.


Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 B; 3/3
Print date : 22.02.2006 Product code : LCK308-3 Page 2 of 6

After contact with skin
Wash off immediately with plenty of water for at least 15 minutes.
If skin irritation persists, call a physician.
After contact with eyes
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After ingestion
Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an
unconscious person. Obtain medical attention.
Advice to doctor
Treat symptomatically.

5. Fire-fighting measures

Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.
In the event of fire, wear self-contained breathing apparatus.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.

6. Accidental release measures

Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

7. Handling and storage

7.1 Handling
Advice on safe handling
Use only in well-ventilated areas. Avoid contact with skin and eyes.
7.2 Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a dry and well-ventilated place.
Keep away from heat and sources of ignition.
Advice on storage compatibility
Do not store near combustible materials.
Further information on storage conditions
Keep locked up or in an area accessible only to qualified or authorised persons.



Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 B; 3/3
Print date : 22.02.2006 Product code : LCK308-3 Page 3 of 6

8. Exposure controls/personal protection

8.1 Exposure limit values
Exposure limits (EH40)
CAS No. Substance ml/m³ mg/m³ F/ml Category Origin

50-00-0 Formaldehyde 2 2.5 TWA (8 h) WEL
2 2.5 STEL (15 min) WEL
67-56-1 Methanol 200 266 TWA (8 h) WEL
250 333 STEL (15 min) WEL

BAT values (TRGS 903)
CAS No. Substance Value Parameter Test material Sampling time

67-56-1 Methanol 30 mg/l Methanol U c,b

8.2 Exposure controls
Occupational exposure controls
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Protective and hygiene measures
Wash hands before breaks and at the end of workday.
Respiratory protection
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of
local exhaust ventilation and good general extraction.
Hand protection
Use barrier skin cream.
The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the
standard EN 374 derived from it.
Eye protection
safety glasses with side-shields
Skin protection
Avoid contact with skin, eyes and clothing.
9. Physical and chemical properties

9.1 General information
Physical state liquid
Colour colourless
Odour not significant
9.2 Important health, safety and environmental information
Test method
Changes in the physical state
Flash point 78 °C
Density (at 20 °C) : 1,09 g/cm³
soluble
Water solubility :
at (20 °C)

10. Stability and reactivity

Conditions to avoid
Heat, flames and sparks.
Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 B; 3/3
Print date : 22.02.2006 Product code : LCK308-3 Page 4 of 6

Additional information
Stable under recommended storage conditions.

11. Toxicological information

Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.
Sensitising effects
May cause sensitisation by skin contact.

12. Ecological information

Ecotoxicity
No information on ecology is available.

13. Disposal considerations

Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Contaminated packaging
In accordance with local and national regulations. Our local agencies will accept used cuvettes to
ensure their proper disposal.

14. Transport information

Land transport (ADR/RID)
ADR/RID class 9
Warning plate
UN number 3316
ADR/RID packing group II
Inland waterways transport
Remarks (inland waterways transport)
not tested
Marine transport
IMDG code 9
UN number 3316
Marine pollutant --
EmS F-A,S-A
IMDG packing group II


Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 B; 3/3
Print date : 22.02.2006 Product code : LCK308-3 Page 5 of 6

Description of the goods
Chemical kit
Air transport
ICAO/IATA-DGR 9
UN/ID number 3316
ICAO packing group II
Description of the goods
Chemical kit
Futher Information
This product forms part of a kit. Information in this section relates to the kit as a whole.

15. Regulatory information

15.1 Labelling
Indication of danger Xn - Harmful




Xn - Harmful
Labelling according to EC-guidelines Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
formaldehyde ...%
methanol
R phrases
40 Limited evidence of a carcinogenic effect.
43 May cause sensitization by skin contact.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37/39 Wear suitable gloves and eye/face protection.
15.2 National regulations
Employment restrictions Observe employment restrictions for young people.; Observe employment
restrictions for child bearing mothers and nursing.
Water contaminating class 2 - water contaminating

16. Other information

List of relevant R phrases
11 Highly flammable.
22 Harmful if swallowed.
34 Causes burns.
40 Limited evidence of a carcinogenic effect.
41 Risk of serious damage to eyes.
43 May cause sensitization by skin contact.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if

Revision no. : 1,00 GB - EN Revision date : 02.01.2006
HACH LANGE GmbH
Safety Data Sheet

according to 2001/58/EC

LCK 308 Cadmium, LCK 308 B; 3/3
Print date : 22.02.2006 Product code : LCK308-3 Page 6 of 6
swallowed.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Other data
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)




Revision no. : 1,00 GB - EN Revision date : 02.01.2006

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