World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00055
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: NitriVer庐 3 Nitrite Test 麓N TubeTM Reagent
Catalog Number: 1406500
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00055
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of nitrite
CAS No.: Not applicable
Hazard: Causes eye burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Chromatropic Acid, Disodium salt
EEC Number: 2049729
CAS No.: 129-96-4
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3 Inhalable dust
Sodium Sulfanilate
EEC Number: 2082085
CAS No.: 515-74-2
Percent Range: 5,0 - 15,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Potassium Pyrosulfate
EEC Number: 2322168
CAS No.: 7790627
--
Percent Range: 1,0 - 10,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xi - IRRITATING
Ingredient R phrase(s) (R phrase details given in Heading 16): R 36
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Potassium Phosphate, Monobasic
EEC Number: 2319134
CAS No.: 7778770
--
Percent Range: 75,0 - 85,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
1,2-Cyclohexanediaminetetraacetic Acid Trisodium Salt
EEC Number: None
CAS No.: 36679-96-6
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White powder
Odor: Not determined
EU Symbols: Xi - IRRITATING
R PHRASES: R 36: Irritating to eyes.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: irritation of the mouth and esophagus Very large doses may cause: gastrointestinal
disturbances cardiac depression kidney damage
Target Organs (Ing E): Heart Kidneys
Inhalation: May cause: irritation of nose and throat
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre-existing: Eye conditions Kidney conditions Central nervous system diseases
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, this product decomposes to form toxic gases.
Hazardous Combustion Products: Toxic fumes of: phosphorus oxides carbon monoxide, carbon dioxide.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an alkali, such as soda ash or sodium bicarbonate. Flush the spilled material to the drain with a large excess of
water.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Do not breathe dust. Wash thoroughly after handling. Maintain general
industrial hygiene practices when using this product.
Storage: Protect from: light heat moisture
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of nitrite
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash thoroughly after handling. Protect
from: light heat moisture
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Physical State: Solid
Odor: Not determined
pH: of 5% solution = 3,2
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 224掳C (435掳F)
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 3,12
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Not determined
Other: Not determined
Metal Corrosivity:
Steel: 0,057 in/yr
Aluminum: 0,00 in/yr
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Excess moisture Extreme temperatures
Reactivity / Incompatibility: None reported
Hazardous Decomposition: Toxic fumes of: phosphorus oxides carbon dioxide carbon monoxide
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Chromatropic Acid: Oral rat LD50: >5000 mg/kg, Potassium Phosphate Monobasic: Oral
rat LD50 = 7100 mg/kg, Potassium Pyrosulfate: Oral rat LD50 = 2340 mg/kg
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
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ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS or are placed on the
market in quantities less than 10 kg per year.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xi - IRRITATING
R PHRASES: R 36: Irritating to eyes.
S PHRASES: S 37/39: Wear suitable gloves and eye / face protection.
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16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy,
MA: National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire
Protection Association, 1991. In-house information. Technical Judgment. TLV's Threshold Limit Values and Biological
Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992.
R PHRASES: R 36: Irritating to eyes.
Use of the substance/preparation: Determination of nitrite
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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