HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 304 Ammonium, Sample cuvette; 1/2
Print date : 22.02.2006 Product code : LCK304-1 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation
LCK 304 Ammonium, Sample cuvette; 1/2
Use of the substance/preparation
Water analysis
1.2 Company/undertaking identification
Company name HACH LANGE GmbH
Street Willst盲tterstr. 11
D-40549 D眉sseldorf
Place
Telephone +49(0)2115288 0
Telefax +49(0)2115288143
e-mail info@hach-lange.de
Inquiry office
HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - England
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk
2. Composition/information on ingredients
( preparation )
Chemical characterization
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
213-791-2 7732-18-5 Water >80 %
200-198-0 54-21-7 Sodium salicylate <10 % Xn R22
215-185-5 1310-73-2 caustic soda, sodium hydroxide <1,5 % C R35
Full text of each relevant R phrase can be found in heading 16.
3. Hazards identification
Classification
Symbols : Irritant
R-phrases :
Irritating to eyes and skin.
4. First aid measures
General information
Take off all contaminated clothing immediately.
After inhalation
Move to fresh air.
After contact with skin
Wash off immediately with plenty of water.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Clean mouth with water and drink afterwards plenty of water. Consult a physician.
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 304 Ammonium, Sample cuvette; 1/2
Print date : 22.02.2006 Product code : LCK304-1 Page 2 of 5
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. The product itself does not burn.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material and dispose of as hazardous waste.
7. Handling and storage
7.1 Handling
Advice on safe handling
Use only in well-ventilated areas.
7.2 Storage
Requirements for storage rooms and vessels
Keep in a dry, cool place.
8. Exposure controls/personal protection
8.1 Exposure limit values
Exposure limits (EH40)
CAS No. Substance ml/m鲁 mg/m鲁 F/ml Category Origin
1310-73-2 Sodium hydroxide - - TWA (8 h) WEL
- 2 STEL (15 min) WEL
8.2 Exposure controls
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Hand protection
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 304 Ammonium, Sample cuvette; 1/2
Print date : 22.02.2006 Product code : LCK304-1 Page 3 of 5
Use barrier skin cream.
Wash hands before breaks and after work.
Chemical resistant protective gloves
The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and
the resultant standard EN374.
Eye protection
safety glasses with side-shields
Skin protection
Remove and wash contaminated clothing before re-use.
9. Physical and chemical properties
9.1 General information
Physical state liquid
Colour colourless
Odour odourless
9.2 Important health, safety and environmental information
Test method
12,5
pH-Value (at 20 掳C) :
Changes in the physical state
Melting point 0 掳C
Boiling point 100 掳C
Flash point not applicable
Lower explosion limits not applicable
Upper explosion limits not applicable
Density (at 20 掳C) : 1,02 g/cm鲁
completely soluble
Water solubility :
10. Stability and reactivity
Conditions to avoid
No dangerous reaction known under conditions of normal use.
Materials to avoid
No dangerous reaction known under conditions of normal use.
Hazardous decomposition products
No decomposition if stored and applied as directed.
11. Toxicological information
Acute toxicity
No data is available on the product itself.
Specific effects in experiment on an animal
No data is available on the product itself.
12. Ecological information
Ecotoxicity
No data is available on the product itself.
Do not flush into surface water or sanitary sewer system.
13. Disposal considerations
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 304 Ammonium, Sample cuvette; 1/2
Print date : 22.02.2006 Product code : LCK304-1 Page 4 of 5
Advice on disposal
Our local agencies will accept used cuvettes to ensure their proper disposal.
In accordance with local and national regulations.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
Remarks (land transport)
Not subject to transport regulations.
Inland waterways transport
Remarks (inland waterways transport)
not tested
Marine transport
Remarks (marine transport)
Not subject to transport regulations.
Air transport
Remarks (air transport)
Not subject to transport regulations.
15. Regulatory information
15.1 Labelling
Indication of danger Xi - Irritant
Xi - Irritant
Labelling according to EC-guidelines Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
caustic soda, sodium hydroxide
R phrases
36/38 Irritating to eyes and skin.
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 304 Ammonium, Sample cuvette; 1/2
Print date : 22.02.2006 Product code : LCK304-1 Page 5 of 5
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
15.2 National regulations
Water contaminating class 1 - slightly water contaminating
16. Other information
List of relevant R phrases
22 Harmful if swallowed.
35 Causes severe burns.
36/38 Irritating to eyes and skin.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1,00 GB - EN Revision date : 07.04.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 304 Ammonium, DosiCapZip; 2/2
Print date : 22.02.2006 Product code : LCK304-2 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation
LCK 304 Ammonium, DosiCapZip; 2/2
Use of the substance/preparation
Water analysis
1.2 Company/undertaking identification
Company name HACH LANGE GmbH
Street Willst盲tterstr. 11
D-40549 D眉sseldorf
Place
Telephone +49(0)2115288 0
Telefax +49(0)2115288143
e-mail info@hach-lange.de
Inquiry office
HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - England
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk
2. Composition/information on ingredients
( preparation )
Chemical characterization
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
200-711-8 69-65-8 D(-)-Mannitol 76 %
220-767-7 51580-86-0 troclosene sodium, dihydrate 12 % Xn, Xi, N R22-31-36/37-50-53
238-373-9 13755-38-9 Sodium nitroprusside dihydrate 12 % T R25
Full text of each relevant R phrase can be found in heading 16.
3. Hazards identification
Classification
Symbols : Harmful, Dangerous for the environment
R-phrases :
Harmful if swallowed.
Contact with acids liberates toxic gas.
Irritating to eyes and respiratory system.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. First aid measures
General information
Take off all contaminated clothing immediately.
After inhalation
Move to fresh air.
After contact with skin
Wash off immediately with plenty of water.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Revision no. : 1,01 GB - EN Revision date : 26.10.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 304 Ammonium, DosiCapZip; 2/2
Print date : 22.02.2006 Product code : LCK304-2 Page 2 of 5
After ingestion
Clean mouth with water and drink afterwards plenty of water. Consult a physician.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. The product itself does not burn.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Use mechanical handling equipment.
7. Handling and storage
7.1 Handling
Advice on safe handling
Use only in well-ventilated areas.
7.2 Storage
Requirements for storage rooms and vessels
Keep in a dry, cool place.
8. Exposure controls/personal protection
8.1 Exposure limit values
8.2 Exposure controls
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Hand protection
Use barrier skin cream.
Wash hands before breaks and after work.
Chemical resistant protective gloves
The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and
the resultant standard EN374.
Revision no. : 1,01 GB - EN Revision date : 26.10.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 304 Ammonium, DosiCapZip; 2/2
Print date : 22.02.2006 Product code : LCK304-2 Page 3 of 5
Eye protection
safety glasses with side-shields
9. Physical and chemical properties
9.1 General information
Physical state solid
Colour white
Odour characteristic
9.2 Important health, safety and environmental information
Test method
7 ( 5 % solution)
pH-Value (at 20 掳C) :
Changes in the physical state
Flash point not applicable
Lower explosion limits not applicable
Upper explosion limits not applicable
160 g/L
Water solubility :
at (20 掳C)
10. Stability and reactivity
Conditions to avoid
No dangerous reaction known under conditions of normal use.
Materials to avoid
May develop chlorine if mixed with acidic solutions.
Hazardous decomposition products
Carbon monoxide
May develop chlorine if mixed with acidic solutions.
11. Toxicological information
Acute toxicity
No data is available on the product itself.
Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.
12. Ecological information
Ecotoxicity
No data is available on the product itself.
Do not flush into surface water or sanitary sewer system.
13. Disposal considerations
Advice on disposal
Our local agencies will accept used cuvettes to ensure their proper disposal.
In accordance with local and national regulations.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Revision no. : 1,01 GB - EN Revision date : 26.10.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 304 Ammonium, DosiCapZip; 2/2
Print date : 22.02.2006 Product code : LCK304-2 Page 4 of 5
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
Remarks (land transport)
Not subject to transport regulations.
Inland waterways transport
Remarks (inland waterways transport)
not tested
Marine transport
Remarks (marine transport)
Not subject to transport regulations.
Air transport
Remarks (air transport)
Not subject to transport regulations.
15. Regulatory information
15.1 Labelling
Indication of danger Xn - Harmful; N - Dangerous for the environment
Xn - Harmful N - Dangerous for the
environment
Labelling according to EC-guidelines Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
troclosene sodium, dihydrate
Sodium nitroprusside dihydrate
R phrases
22 Harmful if swallowed.
31 Contact with acids liberates toxic gas.
36/37 Irritating to eyes and respiratory system.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
35 This material and its container must be disposed of in a safe way.
37/39 Wear suitable gloves and eye/face protection.
Revision no. : 1,01 GB - EN Revision date : 26.10.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK 304 Ammonium, DosiCapZip; 2/2
Print date : 22.02.2006 Product code : LCK304-2 Page 5 of 5
15.2 National regulations
Water contaminating class 3 - highly water contaminating
16. Other information
List of relevant R phrases
22 Harmful if swallowed.
25 Toxic if swallowed.
31 Contact with acids liberates toxic gas.
50 Very toxic to aquatic organisms.
53 May cause long-term adverse effects in the aquatic environment.
36/37 Irritating to eyes and respiratory system.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1,01 GB - EN Revision date : 26.10.2005
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