HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, Sample cuvette; 1/5
Print date : 20.04.2007 Product code : LCK365-1 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCK365 Organische Säuren/Organic Acids/Acides organiques, Sample cuvette; 1/5
Use of the substance/preparation
Water analysis
Company/undertaking identification
Company name : HACH LANGE GmbH
Street : Willstätterstr. 11
Place : D-40549 Düsseldorf
Telephone : +49(0)2115288-0
e-mail : Telefax : +49(0)2115288-143
info@hach-lange.de
Internet : www.hach-lange.com
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: info@hach-lange.ie
2. Composition/information on ingredients
Chemical characterization ( substance )
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
203-473-3 107-21-1 ethanediol, ethylene glycol 100 % Xn R22
Full text of each relevant R phrase can be found in heading 16.
Index No. 603-027-00-1
3. Hazards identification
Classification
Indications of danger : Harmful
R-phrases :
Harmful if swallowed.
4. First aid measures
General information
Take off all contaminated clothing immediately.
Consult a physician. Show this safety data sheet to the doctor in attendance.
After inhalation
Move to fresh air.
After contact with skin
Wash off immediately with plenty of water for at least 15 minutes.
Revision no. : 1,01 GB - EN Revision date : 28.10.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, Sample cuvette; 1/5
Print date : 20.04.2007 Product code : LCK365-1 Page 2 of 5
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Clean mouth with water and drink afterwards plenty of water.
Consult a physician. Show this safety data sheet to the doctor in attendance.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. The product itself does not burn.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. In order to avoid contact with skin, keep a
safety distance and wear suitable protective clothing.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
7. Handling and storage
Handling
Advice on safe handling
Use only in well-ventilated areas.
Storage
Requirements for storage rooms and vessels
Keep tightly closed in a dry, cool and well-ventilated place.
Further information on storage conditions
Keep locked up or in an area accessible only to qualified or authorised persons.
8. Exposure controls/personal protection
Exposure limit values
Exposure limits (EH40)
CAS No. Substance ml/m³ mg/m³ F/ml Category Origin
107-21-1 Ethane-1,2-diol, vapour 20 52 TWA (8 h) WEL
40 104 STEL (15 min) WEL
Revision no. : 1,01 GB - EN Revision date : 28.10.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, Sample cuvette; 1/5
Print date : 20.04.2007 Product code : LCK365-1 Page 3 of 5
Exposure controls
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Breathing apparatus only if aerosol or dust is formed.
Hand protection
Use barrier skin cream.
Wash hands before breaks and after work.
Chemical resistant protective gloves
The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and
the resultant standard EN374.
Eye protection
Safety glasses with side-shields
Skin protection
Remove and wash contaminated clothing before re-use.
9. Physical and chemical properties
General information
Physical state : liquid
Colour : colourless
Odour : sweet
Important health, safety and environmental information
Test method
Changes in the physical state
- 13 °C
Melting point :
197,6 °C
Boiling point :
Flash point : 111 °C
Lower explosion limits : 1,8
Upper explosion limits : 12,8
Vapour pressure : 0,053 hPa
1,11 g/cm³
completely soluble
Other information
Ignition temperature : 410 °C
10. Stability and reactivity
Conditions to avoid
No dangerous reaction known under conditions of normal use.
Materials to avoid
bases
oxidizing agents
Hazardous decomposition products
No decomposition if stored and applied as directed.
11. Toxicological information
Acute toxicity
LD50/oral/rat = 4700 mg/kg
Revision no. : 1,01 GB - EN Revision date : 28.10.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, Sample cuvette; 1/5
Print date : 20.04.2007 Product code : LCK365-1 Page 4 of 5
12. Ecological information
Ecotoxicity
No data is available on the product itself.
Do not flush into surface water or sanitary sewer system.
13. Disposal considerations
Advice on disposal
Our local agencies will accept used cuvettes to ensure their proper disposal.
In accordance with local and national regulations.
Waste disposal number of waste from residues/unused products
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
160506
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
160506
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
ADR/RID class : 9
Warning plate
UN number : 3316
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Remarks (inland waterways transport)
Not tested
Marine transport
IMDG code : 9
UN number : 3316
Marine pollutant : --
EmS : F-A,S-P
IMDG packing group : II
Description of the goods
Chemical kit
Air transport
ICAO/IATA-DGR : 9
UN/ID number : 3316
ICAO packing group : II
Description of the goods
Chemical kit
Further Information
These transport data apply to the entire pack
Revision no. : 1,01 GB - EN Revision date : 28.10.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, Sample cuvette; 1/5
Print date : 20.04.2007 Product code : LCK365-1 Page 5 of 5
15. Regulatory information
Labelling
Danger symbols : Xn - Harmful
Xn - Harmful
Labelling according to EC-guidelines : Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
ethanediol, ethylene glycol
R phrases
22 Harmful if swallowed.
National regulations
Water contaminating class : 1 - slightly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
22 Harmful if swallowed.
Revision no. : 1,01 GB - EN Revision date : 28.10.2005
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 A; 2/5
Print date : 20.04.2007 Product code : LCK365-2 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 A; 2/5
Use of the substance/preparation
Water analysis
Company/undertaking identification
Company name : HACH LANGE GmbH
Street : Willstätterstr. 11
Place : D-40549 Düsseldorf
Telephone : +49(0)2115288-0
e-mail : Telefax : +49(0)2115288-143
info@hach-lange.de
Internet : www.hach-lange.com
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: info@hach-lange.ie
2. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
213-791-2 7732-18-5 Water < 90%
231-639-5 7664-93-9 sulphuric acid ... % > 10% C R35
Full text of each relevant R phrase can be found in heading 16.
3. Hazards identification
Classification
Indications of danger : Irritant
R-phrases :
Irritating to eyes and skin.
4. First aid measures
General information
Take off all contaminated clothing immediately.
Show this safety data sheet to the doctor in attendance.
After inhalation
Move to fresh air. Consult a physician after significant exposure.
After contact with skin
Wash off immediately with plenty of water for at least 15 minutes.
If skin irritation persists, call a physician.
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 A; 2/5
Print date : 20.04.2007 Product code : LCK365-2 Page 2 of 5
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Do NOT induce vomiting. Drink 1 or 2 glasses of water.
Never give anything by mouth to an unconscious person.
Consult a physician.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
The product itself does not burn.
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus.
In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Dilute with plenty of water.
Methods for cleaning up/taking up
Neutralise with the following product(s): Cover with dry sodium carbonate. pH 6-9
Flush into sewer with plenty of water.
7. Handling and storage
Handling
Advice on safe handling
Avoid contact with skin and eyes. Do not breathe vapours or spray mist. Use only in well-ventilated
areas.
Storage
Requirements for storage rooms and vessels
Keep at temperatures between 10 and 25°C.
Keep in a dry place.
Further information on storage conditions
Keep locked up or in an area accessible only to qualified or authorised persons.
8. Exposure controls/personal protection
Exposure limit values
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 A; 2/5
Print date : 20.04.2007 Product code : LCK365-2 Page 3 of 5
Exposure controls
Occupational exposure controls
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Protective and hygiene measures
Wash hands before breaks and at the end of workday.
Respiratory protection
Ensure adequate ventilation, especially in confined areas.
Hand protection
Use barrier skin cream. The selected protective gloves have to satisfy the specifications of EU
Directive 89/689/EEC and the standard EN 374 derived from it.
Eye protection
Safety glasses with side-shields
Skin protection
Avoid contact with skin, eyes and clothing.
9. Physical and chemical properties
General information
Physical state : liquid
Colour : colourless
Odour : odourless
Important health, safety and environmental information
Test method
<1
Changes in the physical state
112 °C
Boiling point :
Flash point : not applicable
Flammability
not applicable
Solid :
Gas : not applicable
Explosive properties
not applicable
1,047 g/cm³
Water solubility : soluble
10. Stability and reactivity
Conditions to avoid
Extremes of temperature and direct sunlight.
Materials to avoid
Reacts violently with water.
Hazardous decomposition products
Sulphur trioxide
Additional information
Stable under recommended storage conditions.
11. Toxicological information
Acute toxicity
No data is available on the product itself.
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 A; 2/5
Print date : 20.04.2007 Product code : LCK365-2 Page 4 of 5
Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.
12. Ecological information
Ecotoxicity
No data is available on the product itself.
13. Disposal considerations
Advice on disposal
In accordance with local and national regulations.
Our local agencies will accept used cuvettes to ensure their proper disposal.
Waste disposal number of waste from residues/unused products
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
160506
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
160506
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
ADR/RID class : 9
Warning plate
UN number : 3316
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Remarks (inland waterways transport)
Not tested
Marine transport
IMDG code : 9
UN number : 3316
Marine pollutant : --
EmS : F-A,S-P
IMDG packing group : II
Description of the goods
Chemical kit
Air transport
ICAO/IATA-DGR : 9
UN/ID number : 3316
ICAO packing group : II
Description of the goods
Chemical kit
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 A; 2/5
Print date : 20.04.2007 Product code : LCK365-2 Page 5 of 5
Further Information
These transport data apply to the entire pack
15. Regulatory information
Labelling
Danger symbols : Xi - Irritant
Xi - Irritant
Labelling according to EC-guidelines : Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
sulphuric acid ... %
R phrases
36/38 Irritating to eyes and skin.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37/39 Wear suitable gloves and eye/face protection.
National regulations
Water contaminating class : 1 - slightly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
35 Causes severe burns.
36/38 Irritating to eyes and skin.
Other data
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 B; 3/5
Print date : 20.04.2007 Product code : LCK365-3 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 B; 3/5
Use of the substance/preparation
Water analysis
Company/undertaking identification
Company name : HACH LANGE GmbH
Street : Willstätterstr. 11
Place : D-40549 Düsseldorf
Telephone : +49(0)2115288-0
e-mail : Telefax : +49(0)2115288-143
info@hach-lange.de
Internet : www.hach-lange.com
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: info@hach-lange.ie
2. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
213-791-2 7732-18-5 Water < 90%
5470-11-1 hydroxylamine hydrochloride,
226-798-2 < 5 % Xn, Xi, N R22-48/22-36/38-43-50
hydroxylammonium chloride
Full text of each relevant R phrase can be found in heading 16.
3. Hazards identification
Classification
Indications of danger : Irritant
R-phrases :
May cause sensitization by skin contact.
4. First aid measures
General information
Take off all contaminated clothing immediately.
Show this safety data sheet to the doctor in attendance.
After inhalation
Move to fresh air.
After contact with skin
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 B; 3/5
Print date : 20.04.2007 Product code : LCK365-3 Page 2 of 5
Wash off immediately with plenty of water for at least 15 minutes.
If skin irritation persists, call a physician.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Do NOT induce vomiting. Drink 1 or 2 glasses of water.
Never give anything by mouth to an unconscious person.
Consult a physician.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
The product itself does not burn.
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus.
In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Dilute with plenty of water.
Methods for cleaning up/taking up
Neutralise with the following product(s): Cover with dry sodium carbonate. pH 6-9
Flush into sewer with plenty of water.
7. Handling and storage
Handling
Advice on safe handling
Avoid contact with skin and eyes.
Use only in well-ventilated areas.
Storage
Requirements for storage rooms and vessels
Keep at temperatures between 10 and 25°C.
Keep in a dry place.
Further information on storage conditions
Keep locked up or in an area accessible only to qualified or authorised persons.
8. Exposure controls/personal protection
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 B; 3/5
Print date : 20.04.2007 Product code : LCK365-3 Page 3 of 5
Exposure limit values
Exposure controls
Occupational exposure controls
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Protective and hygiene measures
Wash hands before breaks and at the end of workday.
Respiratory protection
Ensure adequate ventilation, especially in confined areas.
Hand protection
Use barrier skin cream.
Chemical resistant protective gloves
The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the
standard EN 374 derived from it.
Eye protection
Safety glasses with side-shields
Skin protection
Avoid contact with skin, eyes and clothing.
9. Physical and chemical properties
General information
Physical state : liquid
Colour : colourless
Odour : odourless
Important health, safety and environmental information
Test method
2,5 - 3,5
Changes in the physical state
Boiling point : -
Flash point : not applicable
Flammability
not applicable
Solid :
Gas : not applicable
Explosive properties
not applicable
Lower explosion limits : not applicable
Upper explosion limits : not applicable
1,0 g/cm³
Water solubility : completely soluble
10. Stability and reactivity
Conditions to avoid
Extremes of temperature and direct sunlight.
Materials to avoid
No dangerous reaction known under conditions of normal use.
Hazardous decomposition products
No decomposition if used as directed.
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 B; 3/5
Print date : 20.04.2007 Product code : LCK365-3 Page 4 of 5
Additional information
Stable under recommended storage conditions.
11. Toxicological information
Acute toxicity
No data is available on the product itself.
Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.
12. Ecological information
Ecotoxicity
No data is available on the product itself.
13. Disposal considerations
Advice on disposal
In accordance with local and national regulations.
Our local agencies will accept used cuvettes to ensure their proper disposal.
Waste disposal number of waste from residues/unused products
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
160506
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
160506
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
ADR/RID class : 9
Warning plate
UN number : 3316
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Remarks (inland waterways transport)
Not tested
Marine transport
IMDG code : 9
UN number : 3316
Marine pollutant : --
EmS : F-A,S-P
IMDG packing group : II
Description of the goods
Chemical kit
Air transport
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 B; 3/5
Print date : 20.04.2007 Product code : LCK365-3 Page 5 of 5
ICAO/IATA-DGR : 9
UN/ID number : 3316
ICAO packing group : II
Description of the goods
Chemical kit
Further Information
These transport data apply to the entire pack
15. Regulatory information
Labelling
Danger symbols : Xi - Irritant
Xi - Irritant
Labelling according to EC-guidelines : Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
hydroxylamine hydrochloride, hydroxylammonium chloride
R phrases
43 May cause sensitization by skin contact.
S phrases
37 Wear suitable gloves.
24/25 Avoid contact with skin and eyes.
National regulations
Water contaminating class : 3 - highly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
22 Harmful if swallowed.
43 May cause sensitization by skin contact.
50 Very toxic to aquatic organisms.
36/38 Irritating to eyes and skin.
48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
Other data
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 C; 4/5
Print date : 20.04.2007 Product code : LCK365-4 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 C; 4/5
Use of the substance/preparation
Water analysis
Company/undertaking identification
Company name : HACH LANGE GmbH
Street : Willstätterstr. 11
Place : D-40549 Düsseldorf
Telephone : +49(0)2115288-0
e-mail : Telefax : +49(0)2115288-143
info@hach-lange.de
Internet : www.hach-lange.com
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: info@hach-lange.ie
2. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
213-791-2 7732-18-5 Water < 80%
215-185-5 1310-73-2 caustic soda, sodium hydroxide 15 % C R35
Full text of each relevant R phrase can be found in heading 16.
3. Hazards identification
Classification
Indications of danger : Corrosive
R-phrases :
Causes severe burns.
4. First aid measures
General information
Take off all contaminated clothing immediately.
In the case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
Show this safety data sheet to the doctor in attendance.
After inhalation
Move to fresh air. Consult a physician.
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 C; 4/5
Print date : 20.04.2007 Product code : LCK365-4 Page 2 of 5
After contact with skin
Wash off immediately with plenty of water for at least 15 minutes.
If skin irritation persists, call a physician.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Do NOT induce vomiting. Drink 1 or 2 glasses of water.
Never give anything by mouth to an unconscious person.
Consult a physician.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
The product itself does not burn.
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus.
In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Shovel into suitable container for disposal.
7. Handling and storage
Handling
Advice on safe handling
Avoid contact with skin and eyes.
Use only in well-ventilated areas.
Storage
Requirements for storage rooms and vessels
Keep in a dry place.
Further information on storage conditions
Keep locked up or in an area accessible only to qualified or authorised persons.
8. Exposure controls/personal protection
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 C; 4/5
Print date : 20.04.2007 Product code : LCK365-4 Page 3 of 5
Exposure limit values
Exposure limits (EH40)
CAS No. Substance ml/m³ mg/m³ F/ml Category Origin
1310-73-2 Sodium hydroxide - - TWA (8 h) WEL
- 2 STEL (15 min) WEL
Exposure controls
Occupational exposure controls
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Protective and hygiene measures
Wash hands before breaks and at the end of workday.
Respiratory protection
Ensure adequate ventilation, especially in confined areas.
Hand protection
Use barrier skin cream.
Chemical resistant protective gloves
The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the
standard EN 374 derived from it.
Eye protection
Safety glasses with side-shields
Skin protection
Avoid contact with skin, eyes and clothing.
9. Physical and chemical properties
General information
Physical state : liquid
Colour : colourless
Odour : odourless
Important health, safety and environmental information
Test method
> 13
Changes in the physical state
Boiling point : -
Flash point : not applicable
Flammability
not applicable
Solid :
Gas : not applicable
Explosive properties
not applicable
Lower explosion limits : not applicable
Upper explosion limits : not applicable
1,0 g/cm³
Water solubility : completely soluble
10. Stability and reactivity
Conditions to avoid
Extremes of temperature and direct sunlight.
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 C; 4/5
Print date : 20.04.2007 Product code : LCK365-4 Page 4 of 5
Materials to avoid
Gives off hydrogen by reaction with metals.
Incompatible with acids.
Hazardous decomposition products
No decomposition if used as directed.
Additional information
Stable under recommended storage conditions.
11. Toxicological information
Acute toxicity
No data is available on the product itself.
Corrosive and irritant effects
The product causes burns of eyes, skin and mucous membranes.
12. Ecological information
Ecotoxicity
No data is available on the product itself.
13. Disposal considerations
Advice on disposal
In accordance with local and national regulations.
Our local agencies will accept used cuvettes to ensure their proper disposal.
Waste disposal number of waste from residues/unused products
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
160506
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
160506
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
ADR/RID class : 9
Warning plate
UN number : 3316
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Remarks (inland waterways transport)
Not tested
Marine transport
IMDG code : 9
UN number : 3316
Marine pollutant : --
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 C; 4/5
Print date : 20.04.2007 Product code : LCK365-4 Page 5 of 5
EmS : F-A,S-P
IMDG packing group : II
Description of the goods
Chemical kit
Air transport
ICAO/IATA-DGR : 9
UN/ID number : 3316
ICAO packing group : II
Description of the goods
Chemical kit
Further Information
These transport data apply to the entire pack
15. Regulatory information
Labelling
Danger symbols : C - Corrosive
C - Corrosive
Labelling according to EC-guidelines : Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Hazardous component(s) to be indicated on label
caustic soda, sodium hydroxide
R phrases
35 Causes severe burns.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
37/39 Wear suitable gloves and eye/face protection.
National regulations
Employment restrictions : Observe employment restrictions for young people.
Water contaminating class : 1 - slightly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
35 Causes severe burns.
Other data
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 D; 5/5
Print date : 20.04.2007 Product code : LCK365-5 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 D; 5/5
Use of the substance/preparation
Water analysis
Company/undertaking identification
Company name : HACH LANGE GmbH
Street : Willstätterstr. 11
Place : D-40549 Düsseldorf
Telephone : +49(0)2115288-0
e-mail : Telefax : +49(0)2115288-143
info@hach-lange.de
Internet : www.hach-lange.com
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: info@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: info@hach-lange.ie
2. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
213-791-2 7732-18-5 Water < 90%
231-639-5 7664-93-9 sulphuric acid ... % < 5 % C R35
231-729-4 10025-77-1 Iron(III) chloride hexahydrate < 5 % Xn, Xi R22-38-41
Full text of each relevant R phrase can be found in heading 16.
3. Hazards identification
Classification
The product does not need to be labelled in accordance with EC directives or respective national laws.
4. First aid measures
General information
Take off all contaminated clothing immediately.
Show this safety data sheet to the doctor in attendance.
After inhalation
Move to fresh air. Consult a physician after significant exposure.
After contact with skin
Wash off immediately with plenty of water for at least 15 minutes.
If skin irritation persists, call a physician.
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 D; 5/5
Print date : 20.04.2007 Product code : LCK365-5 Page 2 of 5
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Do NOT induce vomiting. Drink 1 or 2 glasses of water.
Never give anything by mouth to an unconscious person.
Consult a physician.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
The product itself does not burn.
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus.
In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Dilute with plenty of water.
Methods for cleaning up/taking up
Neutralise with the following product(s): Cover with dry sodium carbonate. pH 6-9
Flush into sewer with plenty of water.
7. Handling and storage
Handling
Advice on safe handling
Avoid contact with skin and eyes.
Use only in well-ventilated areas.
Storage
Requirements for storage rooms and vessels
Keep in a dry place.
Further information on storage conditions
Keep locked up or in an area accessible only to qualified or authorised persons.
8. Exposure controls/personal protection
Exposure limit values
Exposure controls
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 D; 5/5
Print date : 20.04.2007 Product code : LCK365-5 Page 3 of 5
Occupational exposure controls
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Protective and hygiene measures
Wash hands before breaks and at the end of workday.
Respiratory protection
Ensure adequate ventilation, especially in confined areas.
Hand protection
Use barrier skin cream. The selected protective gloves have to satisfy the specifications of EU
Directive 89/689/EEC and the standard EN 374 derived from it.
Eye protection
Safety glasses with side-shields
Skin protection
Avoid contact with skin, eyes and clothing.
9. Physical and chemical properties
General information
Physical state : liquid
Colour : colourless
Odour : odourless
Important health, safety and environmental information
Test method
<2
Changes in the physical state
Boiling point : -
Flash point : not applicable
Flammability
not applicable
Solid :
Gas : not applicable
Explosive properties
not applicable
Lower explosion limits : not applicable
Upper explosion limits : not applicable
1,00 g/cm³
Water solubility : soluble
10. Stability and reactivity
Conditions to avoid
Extremes of temperature and direct sunlight.
Materials to avoid
Reacts violently with water.
Hazardous decomposition products
Sulphur trioxide
Additional information
Stable under recommended storage conditions.
11. Toxicological information
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 D; 5/5
Print date : 20.04.2007 Product code : LCK365-5 Page 4 of 5
Acute toxicity
No data is available on the product itself.
Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.
12. Ecological information
Ecotoxicity
No data is available on the product itself.
13. Disposal considerations
Advice on disposal
In accordance with local and national regulations.
Our local agencies will accept used cuvettes to ensure their proper disposal.
Waste disposal number of waste from residues/unused products
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
160506
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
160506
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures
of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
ADR/RID class : 9
Warning plate
UN number : 3316
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Remarks (inland waterways transport)
Not tested
Marine transport
IMDG code : 9
UN number : 3316
Marine pollutant : --
IMDG packing group : II
Description of the goods
Chemical kit
Air transport
ICAO/IATA-DGR : 9
UN/ID number : 3316
ICAO packing group : II
Description of the goods
Chemical kit
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
HACH LANGE GmbH
Safety Data Sheet
according to 2001/58/EC
LCK365 Organische Säuren/Organic Acids/Acides organiques, LCK 365 D; 5/5
Print date : 20.04.2007 Product code : LCK365-5 Page 5 of 5
Further Information
These transport data apply to the entire pack
15. Regulatory information
Labelling
Labelling according to EC-guidelines : Classification according to European directive on classification of
hazardous preparations 1999/45/EC.
Additional information on EC regulations
The product does not need to be labelled in accordance with EC directives or respective national laws.
National regulations
Water contaminating class : 1 - slightly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
22 Harmful if swallowed.
35 Causes severe burns.
38 Irritating to skin.
41 Risk of serious damage to eyes.
Other data
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
Revision no. : 1,00 GB - EN Revision date : 04.01.2006
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