World Headquarters Page 1
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00035
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: PhosVer 庐 3 Phosphate Reagent
Catalog Number: 2508025
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00035
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Phosphate determination
CAS No.: Not applicable
Hazard: Causes eye burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33-
(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-(0)1-2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Potassium Pyrosulfate
EEC Number: 2322168
CAS No.: 7790-62-7
Percent Range: 75,0 - 85,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xi - IRRITATING
Ingredient R phrase(s) (R phrase details given in Heading 16): R 41
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Ascorbic Acid
EEC Number: 2000662
CAS No.: 50-81-7
Percent Range: 15,0 - 25,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Molybdate
EEC Number: 2315517
CAS No.: 10102-40-6
Percent Range: 1,0 - 10,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
World Headquarters Page 2
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00035
Loveland, CO USA 80539
(970) 669-3050
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 5 mg/m鲁 (as Mo)
PEL: 5 mg/m鲁 (as Mo)
EU Occupational Exposure Limits: 5 mg/m3 as Mo
Other components, each
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: 0,1 - 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White to off-white powder
Odor: None
EU Symbols: Xi - IRRITATING
R PHRASES: R 41: Risk of serious damage to eyes.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes severe irritation
Skin Contact (EC): No effects are anticipated
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: copper deficiency anemia gout loss of appetite loss of coordination listlessness
diarrhea liver damage May effect enzyme activity.
Target Organs (Ing E): Blood Liver
Inhalation: May cause: irritation of nose and throat Effects similar to those of ingestion.
Target Organs (Inh E): Blood Liver
Medical Conditions Aggravated: Pre-existing: Eye conditions Respiratory conditions Gout
Chronic Effects: Chronic overexposure may cause copper deficiency enzyme activity effects liver damage
Molybdenum poisoning signs include loss of appetite, listlessness and reduced growth rate. Excessive exposure to
molybdenum compounds may cause gout and anemia.
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: sulfur oxides. carbon monoxide, carbon dioxide. sodium monoxide
World Headquarters Page 3
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00035
Loveland, CO USA 80539
(970) 669-3050
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain with a large excess of water.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrial
hygiene practices when using this product.
Storage: Store between 10掳 and 25掳C.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Phosphate determination
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling.
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White to off-white powder
Physical State: Solid
Odor: None
pH: of a 5% solution = 1,5
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 105 掳C (221 掳F)
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 2,22
World Headquarters Page 4
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00035
Loveland, CO USA 80539
(970) 669-3050
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: Not Applicable
Aluminum: Not Applicable
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures
Reactivity / Incompatibility: Incompatible with: oxidizers dyes alkalies iron copper
Hazardous Decomposition: Heating to decomposition releases: carbon dioxide carbon monoxide sulfur oxides
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
Ingredient Toxicological Data: Potassium Pyrosulfate Oral rat LD50 = 2340 mg/kg; Sodium Molybdate Oral rat LD50 =
4000 mg/kg, Inhalation rat LC50 > 2080mg/m3/4 hr; Ascorbic Acid Oral rat LD50 = 11.9 g/kg
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
World Headquarters Page 5
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00035
Loveland, CO USA 80539
(970) 669-3050
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xi - IRRITATING
R PHRASES: R 41: Risk of serious damage to eyes.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S
37/39: Wear suitable gloves and eye / face protection.
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16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of
Governmental Industrial Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19,
1989. pp. 2332-2983. In-house information. Technical Judgment. Outside Testing. NIOSH/OSHA Occupational Health
Guidelines for Chemical Hazards. Cincinnati: Department of Health and Human Services, 1981. Sax, N. Irving.
Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. Gosselin, R. E. et al.
Clinical Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Vendor
Information. Patty, Frank A. Industrial Hygiene and Toxicology, 3rd Revised Edition. Volume 2. New York: A Wiley-
Interscience Publication, 1981.
R PHRASES: R 41: Risk of serious damage to eyes.
Use of the substance/preparation: Phosphate determination
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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