World Headquarters
Hach Company
P.O.Box 389 MSDS No: M01433
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: HgEx TM Reagent C
Catalog Number: 2659059
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M01433
Chemical Name: Sodium Hypochlorite Solution
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Laboratory reagent
CAS No.: Not applicable
Hazard: May caus e irritation. Experimental mutagen.
Date of MSDS Preparation:
Day: 13
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -0266101029, Nether lands: +31(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
- -
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
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Percent Range: > 90,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Sodium Hypochlorite
EEC Number: 2316683
CAS No.: 7681529
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Percent Range: < 10,0
Percent Range Units: volume / volume
Ingredient EEC Symbol: Xi - IRRITATING
Ingredient R phrase(s) (R phrase details given in Heading 16): R 31 R 36/38
TLV: Not established (0,5 ppm as chlorine)
PEL: Not established
EU Occupational Exposure Limits: Not established (Chlorine as a decomposition product)
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless to ligh t yellow liquid
Odor: Chlorine
EU Symbols: Xi - IRRITATING
R PHRASES: R 31: Contact with acids liberates toxic gas. R 36/38: Irritating to eyes and skin.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes modera te irritation
Skin Contact (EC): Causes irritation
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): Causes: nausea vomiting circulatory collapse confusion coma death
Target Organs (Ing E): None Reported
Inhalation: May cause: respiratory tract irritation
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: None reported
Chronic Effects: Chronic overexposure may cause pulmonary edema nausea vomiting confu sion coma
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Call physician if irritation develops.
Ingestion (First Aid): Do not induce vomiting. Give 1 -2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Material will not burn. During a fire, corrosive and toxic gases may be generated by thermal
decomposition.
Hazardous Combustion P roducts: This material will not burn.
Fire / Explosion Hazards: This product will not burn or explode.
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: Evacuate area and fight fire from a safe distance. As in any fire, wear self -contained breathing
apparatus pressur e-demand and full protective gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
inv olving chemicals.
Containment Technique: Stop spilled material from being released to the environment.
Clean -up Technique: Flush the spilled material to the drain with a large excess of water.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.
Maintain general industrial hygiene practices when using this product.
Storage: Keep container tightly closed when not in use.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laborat ory reagent
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Use general ventilation to
minimize exposure to mist, vapor or dust. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: mist/vapor Wash thoroughly after handling.
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
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_
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless to light yellow liquid
Physical State: Liquid
Odor: Chlorine
pH: 11,5
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: 100掳C
Melting Point: Not applicable
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specifi c Gravity (water = 1): 1,06
Evaporation Rate (water = 1): Not determined
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n -octanol / water): Not applicable
Solubility:
Water: Miscible
Acid: Miscible
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme te mperatures Heating to decomposition.
Reactivity / Incompatibility: Incompatible with: amines oxidizable material cellulose acids ammonia ammonia salts
methanol phenyl acetonitrile ethyleneimine
Hazardous Decomposition: Heating to decompos ition releases: Chlorine oxygen
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None re ported
Skin and Eye Irritation Data: Sodium Hypochlorite: Eye irritation rabbit (Standard Draize) @ 10 mg = MODERATE
Mutation Data: Sodium Hypochlorite: Cytogenetic analysis in human lyphocytes @ 100 ppm/24hr; Sister chromatid
exchange in human embryo @ 149 mg/L; Cytogenetic analysis in hamster lung cells @ 100 mg/L
Reproductive Effects Data: None reported
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Ingredient Toxicological Data: Sodium Hypochlorite: Oral mouse LD50 = 5800 mg/kg
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stri ngent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country -specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
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ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xi - IRRITATING
R PHRASES: R 31: Contact with acids liberates toxic gas. R 36/38: Irritating to eyes and skin.
S PHRASES: S 28a: After contact with skin, wash immediately with plenty of water.
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16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992 -1993. American Conference of
Governmental Industrial Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19,
1989. pp. 2332 -2983. Vendor Information. Technical Judgment. NIOSH Registry of Toxic Effects of Chemical
Substances, 1985 -86. Cincinnati: U.S. Department of Health and Human Services, April, 1987. Sax, N. Irving.
Dangerous Properties of Indust rial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989.
R PHRASES: R 31: Contact with acids liberates toxic gas. R 36/38: Irritating to eyes and skin.
Use of the substance/preparation: Laboratory reagent
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understa nd this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EX PRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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