World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00127
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Ammonia Salicylate Reagent
Catalog Number: 2395266
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00127
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Reagent for ammonia test
CAS No.: Not applicable
Hazard: May cause irritation. Harmful if swallowed
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Salicylate
EEC Number: 2001980.
CAS No.: 54217
--
Percent Range: 40,0 - 50,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Xn - HARMFUL
Ingredient R phrase(s) (R phrase details given in Heading 16): R 22
TLV: Respirable particles: 3 mg/m3; Inhalable particles: 10 mg/m3
PEL: Total dust: 15 mg/m3; Respirable fraction: 5 mg/m3
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Nitroferricyanide
EEC Number: 2383739
CAS No.: 14402-89-2
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 5 mg/m鲁 as CN炉
PEL: 5 mg/m鲁 as CN炉
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust. Cyanides are on the Priority List for OELs.
Other components, each
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: 0,1 - 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Sodium Citrate
EEC Number: 2006753
CAS No.: 68042
--
Percent Range: 40,0 - 50,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Tartrate
EEC Number: 2127733
CAS No.: 6106247
--
Percent Range: 10,0 - 20,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Tan powder
Odor: None
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): Harmful if absorbed through the skin Effects similar to those of ingestion Sodium
nitroferricyanide produces a delayed cyanide poisoning reaction.
Target Organs (SA E): Central nervous system Blood
Ingestion (EC): Sodium nitroferricyanide produces a delayed cyanide poisoning reaction. May cause: headache
nausea vomiting central nervous system effects
Target Organs (Ing E): Central nervous system Blood
Inhalation: Sodium nitroferricyanide produces a delayed cyanide poisoning reaction. May cause: headache nausea
vomiting central nervous system effects
Target Organs (Inh E): Central nervous system Blood
Medical Conditions Aggravated: Allergies or sensitivity to aspirin or salicylates.
Chronic Effects: Chronic overexposure may cause confusion diarrhea fatigue weakness death Salicylates may
cause ringing in the ears (tinnitus), abnormal bleeding, gastric ulceration, mental deterioration, skin eruption, temporary
vision loss, and other optical effects.
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen. an experimental
teratogen.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Remove contaminated clothing. Call physician
immediately.
Ingestion (First Aid): Induce vomiting using syrup of ipecac or by sticking finger down throat. Never give anything by
mouth to an unconscious person. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, this product decomposes to form toxic gases.
Hazardous Combustion Products: May emit acrid smoke and fumes.
Fire / Explosion Hazards: This product will not burn or explode.
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Dry chemical. Carbon dioxide Alcohol foam.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear. Evacuate area and fight fire from a safe distance.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Stop spilled material from being
released to the environment.
Clean-up Technique: Avoid contact with spilled material. Sweep up material. Dilute with a large excess of water. Flush
the spilled material to the drain with a large excess of water. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Store between 10掳 and 25掳C. Keep away from: acids / acid fumes. oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Reagent for ammonia test
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Use a fume hood to avoid exposure to dust, mist or vapor.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: lab coat disposablelatex gloves
Inhalation Protection: laboratory fume hood
Precautionary Measures: eyes skin clothing Do not breathe: dust Wash thoroughly after handling. Use with adequate
ventilation. Keep away from: acids/acid fumes oxidizers
TLV: Not established.
PEL: Not established.
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Tan powder
Physical State: Solid
Odor: None
pH: 7,84 (5% solution)
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 97掳C (206,6掳F)
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined.
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,689
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: None.
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble.
Acid: Soluble.
Other: Not determined.
Metal Corrosivity:
Steel: Not applicable
Aluminum: Not applicable
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heating to decomposition. Extreme temperatures
Reactivity / Incompatibility: Incompatible with: acids iodine iron salts lead acetate organic materials oxidizers silver
nitrate sodium phosphate
Hazardous Decomposition: Contact with acids/acid fumes releases toxic cyanide gas. Heating to decomposition releases
toxic and/or corrosive fumes of: cyanide nitrogen oxides sodium oxides
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported.
LC50: None reported.
Dermal Toxicity Data: None reported.
Skin and Eye Irritation Data: None reported.
Mutation Data: None reported.
Reproductive Effects Data: None reported.
--
Ingredient Toxicological Data: Sodium Salicylate: Oral rat LD50 = 1200 mg/kg; Sodium Citrate: Oral rat LD50 > 8 g/kg;
Sodium Tartrate: Oral rabbit LD50 = 5290 mg/kg; Sodium Nitroferricyanide: Oral rat LD50 = 99 mg/kg.
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xn - HARMFUL
R PHRASES: R 22: Harmful if swallowed.
S PHRASES: S 24/25: Avoid contact with skin and eyes. S 37: Wear suitable gloves.
______________________________________
16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of
Governmental Industrial Hygienists, 1992. Technical Judgment. Sixth Annual Report on Carcinogens, 1991. U.S.
Department of Health and Human Services. Rockville, MD: Technical Resources, Inc. 1991. Sax, N. Irving. Dangerous
Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. List of Dangerous Substances
Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of Dangerous Substances,
Amended July 1992. In-house information. IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans.
World Health Organization (Volumes 1-42) Supplement 7. France: 1987. Gosselin, R. E. et al. Clinical Toxicology of
Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Cassaret and Doull's Toxicology, 3rd Ed.
New York: Macmillan Publishing Co., Inc., 1986. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday,
January 19, 1989. pp. 2332-2983. 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor).
R PHRASES: R 22: Harmful if swallowed.
Use of the substance/preparation: Reagent for ammonia test
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00128
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Ammonia Cyanurate Reagent
Catalog Number: 2395466
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00128
Chemical Name: Not Applicable
Chemical Formula: Not Applicable
Chemical Family: Not applicable
Use of the substance/preparation: Reagent for ammonia test
CAS No.: Not Applicable
Hazard: Causes burns.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Dichloroisocyanurate
EEC Number: 2207677
CAS No.: 2893789
--
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Lithium Hydroxide, Anhydrous
EEC Number: 2151834
CAS No.: 1310652
--
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: C - CORROSIVE
Ingredient R phrase(s) (R phrase details given in Heading 16): R 34
TLV: STEL 2 mg/m3 (ceiling)
PEL: 2 mg/m3
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Citrate
EEC Number: 2006753
CAS No.: 68042
--
Percent Range: 80,0 - 90,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Tartrate
EEC Number: 2127733
CAS No.: 6106247
--
Percent Range: 5,0 - 15,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White powder
Odor: Chlorine
EU Symbols: C - CORROSIVE
R PHRASES: R 34: Causes burns.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes burns
Skin Contact (EC): Causes burns
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): Causes: burns May cause: dizziness nausea kidney damage liver damage
Target Organs (Ing E): Liver Kidneys Central nervous system Bone marrow
Inhalation: Causes: burns May cause: shortness of breath c ughing
o
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions
Chronic Effects: Lithium compounds have been implicated in development of aplastic anemia. Signs of lithium
poisoning include dehydration, extreme weight loss, fine tremor of hands, nausea, vomiting and diarrhea, Chronic
overexposure may cause central nervous system effects kidney damage liver damage
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water for 15 minutes. Remove contaminated clothing. Call
physician immediately.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, irritating and highly toxic gases may be generated by thermal decomposition.
Hazardous Combustion Products: May emit toxic and corrosive fumes.
Fire / Explosion Hazards: Not combustible.
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Dry chemical. Carbon dioxide Water.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Cover spilled solid material with sand or other inert material. Stop spilled material from being
released to the environment.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an acid, such as sulfuric or citric. Flush reacted material to the drain with a large excess of water. Decontaminate
the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled. If conditions warrant, increase the size of the evacuation.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Protect from: heat moisture Store away from: acids / acid fumes.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Reagent for ammonia test
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Use a fume hood to avoid
exposure to dust, mist or vapor. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Keep away from: acids/acid fumes metals
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Physical State: Solid
Odor: Chlorine
pH: of a 5% solution = 12,33
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: >240 掳C; >464 掳F
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,783
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: None reported
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: 0,00 in/yr
Aluminum: 0,803 in/yr
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heating to decomposition. Extreme temperatures Excess moisture
Reactivity / Incompatibility: Incompatible with: acids
Hazardous Decomposition: Contact with acids releases toxic and/or corrosive fumes of: chlorides nitrogen oxides
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None Reported
LC50: None Reported
Dermal Toxicity Data: None Reported
Skin and Eye Irritation Data: None Reported
Mutation Data: None Reported
Reproductive Effects Data: None Reported
--
Ingredient Toxicological Data: Sodium Citrate Oral rat LD50 > 8 g/k; Sodium Tartrate Oral rabbit LD50 = 5290 mg/kg;
Lithium Hydroxide Oral rat LD50 = 225 mg/kg; Sodium Dichloroisocyanurate Oral rat LD50 = 1400 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Lithium Hydroxide Mixture
--
ICAO Hazard Class: 8
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN2680
ICAO Packing Group: II
I.M.O.:
I.M.O. Proper Shipping Name: Lithium Hydroxide Mixture
--
I.M.O. Hazard Class: 8
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN2680
I.M.O. Packing Group: II
A.D.R.:
A.D.R. Proper Shipping Name: Lithium Hydroxide Mixture
--
A.D.R Hazard Class: 8
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 2680
A.D.R. Packing Group: II
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: C - CORROSIVE
R PHRASES: R 34: Causes burns.
S PHRASES: S 24/25: Avoid contact with skin and eyes. S 37: Wear suitable gloves.
______________________________________
16. OTHER INFORMATION
References: NIOSH Registry of Toxic Effects of Chemical Substances, 1985-86. Cincinnati: U.S. Department of Health
and Human Services, April, 1987. Patty, Frank A. Industrial Hygiene and Toxicology, 3rd Revised Edition. Volume 2.
New York: A Wiley-Interscience Publication, 1981. Gosselin, R. E. et al. Clinical Toxicology of Commercial Products,
5th Ed. Baltimore: The Williams and Wilkins Co., 1984. Technical Judgment. In-house information. Air Contaminants,
Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and
Biological Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992.
R PHRASES: R 34: Causes burns.
Use of the substance/preparation: Reagent for ammonia test
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M01132
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
______________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: AmVer TM Diluent Reagent LR for Nitrogen, Ammonia
Catalog Number: 2602200
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M01132
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Laboratory Reagent
CAS No.: Not applicable
Hazard: May cause irritation. May be embryotoxic. Experimental mutagen.
Date of MSDS Preparation:
Day: 13
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
______________________________________
2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Hydroxide
EEC Number: 2151855
CAS No.: 1310732
--
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: 2 mg/m鲁
PEL: 2 mg/m鲁
EU Occupational Exposure Limits: 2 mg/m3
Sodium Salicylate
EEC Number: 2001980.
CAS No.: 54217
--
Percent Range: 1,0 - 5,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Respirable particles: 3 mg/m3; Inhalable particles: 10 mg/m3
PEL: Total dust: 15 mg/m3; Respirable fraction: 5 mg/m3
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: > 99,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: Not determined
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): Will be absorbed through the skin. Effects similar to those of ingestion
Target Organs (SA E): Central nervous system
Ingestion (EC): May cause: irritation of the mouth and esophagus Very large doses may cause: headache dizziness
ringing in the ears (tinnitus) blurred vision confusion drowsiness thirst nausea vomiting diarrhea convulsions coma
Target Organs (Ing E): Central nervous system
Inhalation: No effects anticipated
Target Organs (Inh E): Not applicable
Medical Conditions Aggravated: Allergies or sensitivity to aspirin or salicylates.
Chronic Effects: Salicylates may cause ringing in the ears (tinnitus), abnormal bleeding, gastric ulceration, mental
deterioration, skin eruption, temporary vision loss, and other optical effects.
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: In laboratory tests, sodium salicylate, when given orally to
pregnant rats or mice, has caused various effects on the embryo, fetus, and newborn. The effects of sodium salicylate
on the embryo, fetus, or newborn included: muscular, skeletal, and other developmental abnormalities; death (of
embryo or fetus); and stillbirth.
Toxicologically Synergistic Products: None reported
______________________________________
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Do not induce vomiting. Call physician immediately.
Inhalation: None required.
______________________________________
5. FIRE FIGHTING MEASURES
Flammable Properties: Material will not burn.
Hazardous Combustion Products: May emit acrid smoke and fumes.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear. Evacuate area and fight fire from a safe distance.
______________________________________
6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Cover spilled material with a dry acid, such as citric or boric. Scoop up slurry into a large beaker.
Adjust to a pH between 6 and 9. Use sulfuric or citric acid to lower pH. Use soda ash or sodium bicarbonate to increase pH.
Flush reacted material to the drain with a large excess of water. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate as needed to perform spill clean-up.
______________________________________
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin Wash thoroughly after handling. Maintain general industrial hygiene practices
when using this product.
Storage: Keep container tightly closed when not in use.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
______________________________________
8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Use general ventilation to minimize exposure to mist, vapor or
dust. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Wash thoroughly after handling. Use
with adequate ventilation.
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: Not determined
pH: 11,4
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: 99掳C
Melting Point: Not applicable
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 1,010
Evaporation Rate (water = 1): Not determined
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Miscible
Acid: Not determined
Other: Not determined
Metal Corrosivity:
Steel: 0,00 in/yr
Aluminum: 0,036 in/yr
______________________________________
10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures Exposure to light. Excess moisture
Reactivity / Incompatibility: Incompatible with: acids iodine iron salts lead acetate oxidizers silver nitrate sodium
phosphate
Hazardous Decomposition: Toxic fumes of: carbon dioxide carbon monoxide
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: Sodium salicylate: DNA damage rat liver 240 mg/l; DNA damage rat embryo 30 mg/l
Reproductive Effects Data: Sodium salicylate: Oral rat TDLo = 375 mg/kg (female 8-10 day post) - Reproductive
effects; Oral mouse TDLo = 665 mg/kg (female 17 day post) - Teratogenic effects
--
Ingredient Toxicological Data: Sodium salicylate: Oral rat LD50 = 1200 mg/kg; Oral human LDLo = 700 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
______________________________________
15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
______________________________________
16. OTHER INFORMATION
References: Vendor Information. TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993.
American Conference of Governmental Industrial Hygienists, 1992. Technical Judgment. Sixth Annual Report on
Carcinogens, 1991. U.S. Department of Health and Human Services. Rockville, MD: Technical Resources, Inc. 1991.
Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. List
of Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of
Dangerous Substances, Amended July 1992. IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans.
World Health Organization (Volumes 1-42) Supplement 7. France: 1987. CCINFO RTECS. Canadian Centre for
Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor).
R PHRASES: Not applicable
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
_______________________________________
Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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