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MSDS Material Safety Data Sheet
CAS

101-68-8
25686-28-6
4083-64-1

File Name: freemansupply_com---ARA_2027_R.asp
Huntsman Advanced Materials Americas Inc.


4917 Dawn Avenue
East Lansing, MI 48823-5691

8am to 5pm Phone: (517) 351-5900
24-Hour Emergency Phone: 1-888-354-3323


MSDS No: 33805
Effective Date: 5/27/05 Material Safety Data Sheet

Health: 2*
1. PRODUCT IDENTIFICATION 1
Flammability: 1
2 1
Reactivity: 1
Trade Name: Araldite 2027 Resin
Personal Protection:
Chemical Family: Isocyanate
HMIS RATING
NFPA RATING

Intended Use or Product Type: Fast Setting Polyurea.


2. COMPOSITION / INFORMATION ON INGREDIENTS


O CAS No. CHEMICAL IDENTITY EXPOSURE LIMITS CARCINOGEN
S STATUS
H ACGIH OSHA MFR. IARC NTP OSHA
A TWA STEL PEL STEL
* 101-68-8 Benzene, 1,1'-Methylenebis[4- 0.005 NE 0.02 NE NE NR NR NR
Isocyanato- ppm ppm
Common MDI
Name:
* 25686-28-6 Benzene, 1,1'-Methylenebis[4- NE NE NE NE NE NR NR NR
Isocyanato-, Homopolymer
Common Modified MDI
Name:
* 4083-64-1 Benzenesulfonyl Isocyanate, 4- NE NE NE NE NE NR NR NR
Methyl-
Common 4-Isocyanatosulphonyltoluene
Name:
* Held Isocyanate Prepolymer NE NE NE NE NE NR NR NR
confidential by
our supplier

NE = Not Established NR = Not Reviewed * = OSHA Hazardous Ingredient

3. HAZARDS IDENTIFICATION



Emergency Overview: Causes skin, eye, and respiratory irritations. May cause allergic skin and respiratory reactions.



Primary Route(s) of Entry: Dermal; heated product may produce inhalable vapors.


4. FIRST AID MEASURES


Printed: 7/27/2007 Page 1 of 5
Araldite 2027 Resin Huntsman Advanced Materials
Effective Date: 5/27/05 Americas Inc.



Ingestion: If conscious, give 2 - 4 glasses of water to drink. Do not induce vomiting. Call a physician.

Skin: Immediately wash with soap and water. Remove contaminated clothing and launder before reuse. Destroy contaminated
shoes.

Inhalation: Remove to fresh air. Call a physician.

Eyes: Immediately flush eyes with water for at least 15 minutes. Call a physician.

Overexposure Effects: Contact with liquid causes eye and skin irritation. If inhaled causes breathlessness, chest discomfort, and
reduced pulmonary function. May cause allergic skin and respiratory reactions in some individuals, leading to asthma type spasms
of the bronchial tubes and difficulty in breathing.

Medical Conditions Aggravated by Exposure: Persons with asthmatic-type conditions, chronic bronchitis, other chronic
respiratory diseases, eye conditions or recurrent skin eczema or sensitization should be excluded from working with isocyanates.

Additional Information: Referral to a physician is recommended if there is any question about the seriousness of any injury.


5. FIRE FIGHTING MEASURES

> 200掳C (> 392 掳F)
Flash Point:
Estimated
Flash Point Method Used:
Not established
Flammable Limits in Air (Lower - % by volume):
Not established
Flammable Limits in Air (Upper - % by volume):


Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical, foam, water.

Fire Fighting Equipment: Use self-contained breathing apparatus.

Fire and Explosion Hazards: Decomposition and combustion products may be toxic.


6. ACCIDENTAL RELEASE MEASURES

Accidental Release Measures: Remove spillage by absorbing in absorbent material.


7. HANDLING AND STORAGE

Signal Word: Warning!

Precautions: Causes irritation if inhaled and can cause skin irritation, eye irritation, allergic respiratory reaction, and allergic skin
reaction. Avoid breathing vapor or mist. Avoid contact with eyes, skin, and clothing. Keep container closed when not in use. Use
with adequate ventilation. Wash thoroughly after handling.

Other Handling Information: Nuisance dust may be generated when sanding or sawing cured material.


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Skin Protection: Wear impermeable gloves.

Printed: 7/27/2007 Page 2 of 5
Araldite 2027 Resin Huntsman Advanced Materials
Effective Date: 5/27/05 Americas Inc.



Respiratory Protection: Use NIOSH approved organic vapor cartridge respirator when vapor/mist exposure is likely.

Eye Protection: Wear splash-proof chemical goggles.

Engineering Controls: General mechanical and local exhaust in accordance with ACGIH recommendations.


9. PHYSICAL AND CHEMICAL PROPERTIES

Beige
Color:
Isocyanate
Odor:
Paste
Physical State:
Reacts with water
Solubility in Water:
Not Determined
Vapor Pressure:
1.5 (water = 1)
Specific Gravity:
Not Determined
Boiling Point:
Not Determined
Evaporation Rate:
Not Determined
Vapor Density:
Not Determined
pH:

Percent Volatile: Negligible.


10. STABILITY AND REACTIVITY

Conditions to Avoid: Excessive heat for prolonged periods of time.

Stability: Stable.

Incompatibility: Strong oxidizers, acids and bases.

Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon monoxide.

Hazardous Polymerization: Will not occur.


11. TOXICOLOGICAL INFORMATION

Acute Inhalation Exposure Effects: Respiratory irritant.

Sensitization: Causes allergic skin and respiratory sensitivity in some people.

Skin Irritation: Irritant.

Eye Irritation: Irritant.


12. ECOLOGICAL INFORMATION


13. DISPOSAL CONSIDERATIONS



Printed: 7/27/2007 Page 3 of 5
Araldite 2027 Resin Huntsman Advanced Materials
Effective Date: 5/27/05 Americas Inc.



Waste Disposal Method: Consult qualified local or corporate personnel for method that will comply with local, state and federal
health and environmental regulations.


14. TRANSPORT INFORMATION

DOT: Non-Bulk
Resin compounds, N.O.I.
Proper Shipping Name:


Department of Transportation: Not regulated as a hazardous material by the U.S. Dept. of Transportation (DOT) 49 CFR
172.101 hazardous materials table.


15. REGULATORY INFORMATION

US Federal Regulations:
Occupational Safety and Health Act (OSHA): This Material Safety Data Sheet (MSDS) has been prepared in compliance with
the federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous chemical
under that standard.

Resource Conservation and Recovery Act (RCRA): Not specifically listed as hazardous waste under RCRA (40 CFR 261).
However, it is strongly recommended that compound be treated as a hazardous waste and disposed of accordingly.

SARA Title III: Section 313 Toxic Chemical List (TCL): This product contains a toxic chemical(s) for routine annual toxic
chemical release reporting under section 313 (40 CFR 372). This information must be included in all MSDS's copied or distributed
for this material.

Chemical Name: Benzene, 1,1'-Methylenebis[4-Isocyanato-
Common Name: MDI
Percent in Composition: 46.225 % by wt
Comment:

TSCA Section 8(b) - Inventory Status: Chemical components listed on TSCA Inventory.

TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b)
export notification.

State Regulations:
Pennsylvania Right-to-Know: The following is required composition information:

Chemical Name: Benzene, 1,1'-Methylenebis[4-Isocyanato-
Common Name: MDI
CAS Number: 101-68-8
Comment: Environmental Hazardous Substance

Chemical Name: Limestone
Common Name: Calcium carbonate
CAS Number: 1317-65-3
Comment: Hazardous Substance


Printed: 7/27/2007 Page 4 of 5
Araldite 2027 Resin Huntsman Advanced Materials
Effective Date: 5/27/05 Americas Inc.



Chemical Name: Isocyanate Prepolymer
CAS Number: Held confidential by our supplier
Comment: Not on Pennsylvania Hazardous Substance List

Chemical Name: Siloxanes and silicones, di-me, reaction products with silica
Common Name: Amorphous hydrophobic fumed silica
CAS Number: 67762-90-7
Comment: Not on Pennsylvania Hazardous Substance List


16. OTHER INFORMATION

33805
MSDS No:
Dianne Blessing
Approved By:
EHS Specialist
Title:


Disclaimer: The information and recommendations contained herein are based upon tests in controlled laboratory conditions, are
believed to be correct, and are provided for the sole purpose of hazard communication as part of Huntsman s product safety
program. This product has not been tested for, and therefore is not recommended or suitable for, uses for which prolonged contact
with mucous membranes, abraded skin, or blood is intended or likely, or for uses for which implantation within the human body is
intended, and Huntsman assumes no liability for any such uses.

The information and recommendations contained herein are not intended to constitute performance information concerning the
product, which is available in separate technical data sheets available from Huntsman upon request. Users are urged, and are urged
to urge others who may come in contact with the product, to obtain and consult data sheets prior to purchase, use, transportation or
storage of the product.

HUNTSMAN MAKES NO REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY, QUALITY, OR FITNESS FOR A PARTICULAR PURPOSE. HUNTSMAN S LIABILITY IS
STRICTLY LIMITED TO REIMBURSEMENT OF BUYER S PURCHASE PRICE, OR IN HUNTSMAN S DISCRETION
REPLACEMENT, OF THE PRODUCT IN RESPECT OF WHICH SUCH CLAIM IS MADE. HUNTSMAN S LIABILITY IS
STRICTLY LIMITED BY LEGAL NOTICES IN TECHNICAL DATA SHEETS, PRODUCT LITERATURE AND/OR SALE
DOCUMENTS. The foregoing DISCLAIMERS and LIMITATION OF LIABILITY supercede inconsistent or contradictory
provisions in Buyer s documents.

USER SHOULD CONSULT A LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENTAL AGENCY TO DETERMINE
THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT. HUNTSMAN
DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.




Printed: 7/27/2007 Page 5 of 5

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