Huntsman Advanced Materials Americas Inc.
Distributed by Freeman Mfg & Supply Co.
800.321.8511 www.freemansupply.com
24-Hour Emergency Phone: (800) 328-8501
MSDS No: 32589
Effective Date: 11/9/05 Material Safety Data Sheet
Health: 3
1. PRODUCT IDENTIFICATION 1
Flammability: 1
3 0
Reactivity: 0
Trade Name: RenPIM 6453-1 Polyol
Personal Protection:
Chemical Family: Polyol
HMIS RATING
NFPA RATING
Synonyms:
RP 6453-1 Hardener
Intended Use or Product Type:
Flame retardant rapid prototyping polyurethane
2. COMPOSITION / INFORMATION ON INGREDIENTS
O CAS No. CHEMICAL IDENTITY EXPOSURE LIMITS CARCINOGEN
S STATUS
H ACGIH OSHA MFR. IARC NTP OSHA
A TWA STEL PEL STEL
* 102-60-3 2-Propanol, 1,1',1'',1'''-(1,2- NE NE NE NE NE NR NR NR
ethanediyldinitrilo)tetrakis-
Common Amine based tetrol
Name:
* 68333-79-9 Polyphosphoric Acids, Ammonium NE NE NE NE NE NR NR NR
Salts
Common Ammonium polyphosphate
Name:
* 9046-10-0 Poly[Oxy(Methyl-1,2-Ethanediyl)], NE NE NE NE NE NR NR NR
.alpha.-(2-Aminomethylethyl)-
.omega.-(2-Aminomethylethoxy)-
Common Polyoxypropylenediamine
Name:
* 36483-57-5 1- PROPANOL, 2,2-DIMETHYL-, NE NE NE NE NE NR NR NR
TRIBROMO DERIV.
Common Monobromoneopentyl glycol
Name:
* = OSHA Hazardous Ingredient
3. HAZARDS IDENTIFICATION
Emergency Overview: Corrosive - causes skin burns. Can cause eye irritation and allergic skin reaction. Can be harmful if
absorbed through skin.
Printed: 4/19/2006 Page 1 of 6
RenPIM 6453-1 Polyol Huntsman Advanced Materials
Effective Date: 11/9/05 Americas Inc. (EL)
Primary Route(s) of Entry: Dermal; heated product may produce inhalable vapors.
4. FIRST AID MEASURES
Ingestion: If conscious, give 2 - 4 glasses of water to drink. Do not induce vomiting. Call a physician.
Skin: Immediately wash with soap and water. Remove contaminated clothing and launder before reuse. Destroy contaminated
shoes.
Inhalation: Remove to fresh air. Call a physician.
Eyes: Immediately flush eyes with water for at least 15 minutes. Call a physician.
Overexposure Effects: Corrosive - causes skin burns. Can cause eye irritation and allergic skin reaction. Can be harmful if
absorbed through skin.
Medical Conditions Aggravated by Exposure: Skin and eye conditions.
Additional Information: Referral to a physician is recommended if there is any question about the seriousness of any injury.
5. FIRE FIGHTING MEASURES
> 200掳F (> 93 掳C)
Flash Point:
Estimated
Flash Point Method Used:
Not established
Flammable Limits in Air (Lower - % by volume):
Not established
Flammable Limits in Air (Upper - % by volume):
Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical, foam, water.
Fire Fighting Equipment: Use self-contained breathing apparatus.
Fire and Explosion Hazards: Decomposition and combustion products may be toxic.
6. ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Remove spillage by absorbing in absorbent material.
7. HANDLING AND STORAGE
Signal Word: Danger!
Precautions: Corrosive - causes skin burns. Can cause eye irritation and allergic skin reaction. Can be harmful if absorbed
through skin. Do not get on skin or on clothing. Avoid contact with eyes. Wash thoroughly after handling.
Other Handling Information: Nuisance dust may be generated when sanding or sawing cured material.
Printed: 4/19/2006 Page 2 of 6
RenPIM 6453-1 Polyol Huntsman Advanced Materials
Effective Date: 11/9/05 Americas Inc. (EL)
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Skin Protection: Wear impermeable gloves.
Respiratory Protection: Use NIOSH approved organic vapor cartridge respirator when vapor/mist exposure is likely.
Eye Protection: Wear splash-proof chemical goggles.
Engineering Controls: General mechanical and local exhaust in accordance with ACGIH recommendations.
9. PHYSICAL AND CHEMICAL PROPERTIES
Cloudy, Off White
Color:
Liquid
Physical State:
Slight
Solubility in Water:
1.18 (water = 1)
Specific Gravity:
Not Determined
Boiling Point:
Not Determined
Evaporation Rate:
Not Determined
Vapor Density:
Not Determined
pH:
Percent Volatile: Negligible.
10. STABILITY AND REACTIVITY
Conditions to Avoid: Excessive heat for prolonged periods of time.
Stability: Stable.
Incompatibility: Strong oxidizers, acids and bases.
Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon monoxide.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Acute Dermal Toxicity (LD50): Component(s) are toxic, 200 - 1000 mg/kg (rabbit).
Sensitization: Possible in susceptible individuals.
Skin Irritation: Corrosive. Causes burns.
Eye Irritation: Irritant.
12. ECOLOGICAL INFORMATION
Printed: 4/19/2006 Page 3 of 6
RenPIM 6453-1 Polyol Huntsman Advanced Materials
Effective Date: 11/9/05 Americas Inc. (EL)
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method: Consult qualified local or corporate personnel for method that will comply with local, state and federal
health and environmental regulations.
14. TRANSPORT INFORMATION
DOT: Non-Bulk
Polyamines, liquid, corrosive, N.O.S.
Proper Shipping Name:
Polyoxypropylenediamine
Technical Shipping Name (If n.o.s.):
8
Hazard Class:
UN 2735
ID Number:
PG II
Packing Group:
Corrosive
Label:
15. REGULATORY INFORMATION
US Federal Regulations:
Occupational Safety and Health Act (OSHA): This product is considered to be a hazardous chemical under the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
Resource Conservation and Recovery Act (RCRA): Not a hazardous waste under RCRA (40 CFR 261).
SARA Title III: Section 313 Toxic Chemical List (TCL): This product does not contain any chemicals for routine annual toxic
chemical release reporting under Section 313 (40 CFR 372).
TSCA Section 8(b) - Inventory Status: All chemical components of this product are in compliance with TSCA inventory
requirements.
TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b)
export notification.
State Regulations:
California Proposition 65: The following is required composition information. This product contains the following chemical(s)
which are currently listed on the California list of Known Carcinogens and Reproductive Toxins:
Chemical Name: 1,3- PROPANEDIOL, 2,2-BIS(BROMOMETHYL)-
CAS Number: 3296-90-0
Percent in Composition: 0.0383 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer.
Chemical Name: 1,4-Dioxane
Common Name: Diethylene ether
CAS Number: 123-91-1
Percent in Composition: 0.0001 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer.
Chemical Name: Oxirane
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RenPIM 6453-1 Polyol Huntsman Advanced Materials
Effective Date: 11/9/05 Americas Inc. (EL)
Common Name: Ethylene oxide
CAS Number: 75-21-8
Percent in Composition: 0.0001 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer and birth defects or other reproductive
harm.
Chemical Name: Acetaldehyde
Common Name: Acetaldehyde
CAS Number: 75-07-0
Percent in Composition: 0.0001 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer.
Chemical Name: Formaldehyde
Common Name: Formaldehyde
CAS Number: 50-00-0
Percent in Composition: 0 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer.
Pennsylvania Right-to-Know: The following is required composition information:
Chemical Name: 2-Propanol, 1,1',1'',1'''-(1,2-ethanediyldinitrilo)tetrakis-
Common Name: Amine based tetrol
CAS Number: 102-60-3
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Oxirane, Methyl-, Polymer with Oxirane, Ether with 2-Ethyl-2-(Hydroxymethyl)-1,3-Propanediol (3:1)
Common Name: Polyether polyol
CAS Number: 52624-57-4
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: 1- PROPANOL, 2,2-DIMETHYL-, TRIBROMO DERIV.
Common Name: Monobromoneopentyl glycol
CAS Number: 36483-57-5
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Poly[Oxy(Methyl-1,2-Ethanediyl)], .alpha.-(2-Aminomethylethyl)-.omega.-(2-Aminomethylethoxy)-
Common Name: Polyoxypropylenediamine
CAS Number: 9046-10-0
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Poly(oxy-1,2-ethanediyl), .alpha.-hydro-.omega.-hydroxy-
Common Name: Polyether polyol
CAS Number: 25322-68-3
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Polyphosphoric Acids, Ammonium Salts
Common Name: Ammonium polyphosphate
CAS Number: 68333-79-9
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Castor Oil
Common Name: Castor oil
CAS Number: 8001-79-4
Comment: Not on Pennsylvania Hazardous Substance List
Printed: 4/19/2006 Page 5 of 6
RenPIM 6453-1 Polyol Huntsman Advanced Materials
Effective Date: 11/9/05 Americas Inc. (EL)
Chemical Name: Silica
Common Name: Fumed Silica
CAS Number: 7631-86-9
Comment: Hazardous Substance
16. OTHER INFORMATION
32589
MSDS No:
Dianne Blessing
Approved By:
EH&S Specialist
Title:
Disclaimer: The information and recommendations contained herein are based upon tests in controlled laboratory conditions, are
believed to be correct, and are provided for the sole purpose of hazard communication as part of Huntsman's product safety
program. This product has not been tested for, and therefore is not recommended or suitable for, uses for which prolonged contact
with mucous membranes, abraded skin, or blood is intended or likely, or for uses for which implantation within the human body is
intended, and Huntsman assumes no liability for any such uses.
The information and recommendations contained herein are not intended to constitute performance information concerning the
product, which is available in separate technical data sheets available from Huntsman upon request. Users are urged, and are urged
to urge others who may come in contact with the product, to obtain and consult data sheets prior to purchase, use, transportation or
storage of the product.
HUNTSMAN MAKES NO REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY, QUALITY, OR FITNESS FOR A PARTICULAR PURPOSE. HUNTSMAN'S LIABILITY IS
STRICTLY LIMITED TO REIMBURSEMENT OF BUYER'S PURCHASE PRICE, OR IN HUNTSMAN'S DISCRETION
REPLACEMENT, OF THE PRODUCT IN RESPECT OF WHICH SUCH CLAIM IS MADE. HUNTSMAN'S LIABILITY IS
STRICTLY LIMITED BY LEGAL NOTICES IN TECHNICAL DATA SHEETS, PRODUCT LITERATURE, AND/OR SALE
DOCUMENTS. The foregoing DISCLAIMERS and LIMITATION OF LIABILITY supercede inconsistent or contradictory
provisions in Buyer's documents.
USER SHOULD CONSULT A LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENTAL AGENCY TO DETERMINE
THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT. HUNTSMAN
DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO
PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM
UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO
PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS,
WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE
MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY AT
THE ABOVE ADDRESS.
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