Black ink for Ink Jet Printer (No.404) May 9, 2005
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MATERIAL SAFETY DATA SHEET
1.Product and Company Identification
: Black ink for Ink Jet Printer (No. 404)
Product Name
Company Name : GENERAL TECHNOLOGY COMPANY LTD.
18 Satsukigaoka, Minakuchi-cho
Koka-City Shiga, 528-0062 Japan
Research and Development Department
Kozo Isobe
Tel Number :0748(65)2260
Emergency Tel Number :0748(65)2260 (Research and Development Department)
:03(3833)2136 Sales Department
Fax Number :0748(63)7555
Date Prepared :March 8, 2005
Date Revised :May 9, 2005
2.Composition/Information on Ingredients
Substance or Preparation
Preparation
Chemical Nature
Ingredients Contents (wt%) CAS No. EU classification
[Ink]
Carbon Black 1-5 1333-86-4 not classified
1,3-Dimethyl-2-imidazolidinone 45-55 80-73-9 Xn;R21/22 Xi;R36/R38
Organic Compound A <5 F;R11
Organic Compound B2 0.5-2.5 not classified
Water >40 7732-18-5 not classified
The substances that are contained over 0.1% in this ink are not carcinogens.
EU classification of ink as a whole is not classified.
3 Hazards Identification (Most Important Hazard)
Adverse Human Health Effects
[Ink]
Inhalation - Vapors and / or mists which may be formed at elevated temperatures may be irritating to eyes.
Skin - No irritation.
Ingestion - May be harmful if swallowed.
Eyes - Contact with eye result in mild irritation.
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Black ink for Ink Jet Printer (No.404) May 9, 2005
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[Ingredients]
Carbon Black
Inhalation - No adverse affects expected.
Skin 鈥? No adverse affects expected.
Ingestion 鈥? No adverse affects expected.
Eyes 鈥? Not identified as an irritant in rat studies.
1,3-Dimethyl-2-imidazolidinone
Contact with eye and skin may result in irritation.
May be harmful if absorbed through the skin.
Organic compound A
Consider not hazard compound for industrial use.
But contact repeatedly with eye and skin may result in irritation.
Inhalation may result cough, headache, fatigue and drowsiness.
Organic compound B
Contact with eye may result in mild irritation.
4. First-Aid Measures
Inhalation
Remove subject to ventilated fresh air. Consult physician if necessary.
Skin Contact
Wash thoroughly with soap and water.
Eye Contact
Try to remove with eye drops or flush with water. If unsuccessful, get medical attention.
Ingestion
Wash mouth with water and get medical advice.
5. Fire-Fighting Measures
Flash point for the ink and method
Method: Cleveland (Open)
Upper and lower flammable (explosive) limits in air
Not yet determined.
Hazardous combustion products
Carbon oxides, nitrogen oxides in fire
Extinguishing Media
Water, CO2, Dry Chemical and others
Specific Method
No special fire protecting method is required.
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Black ink for Ink Jet Printer (No.404) May 9, 2005
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6. Accidental Release Measures
Personal Precautions
Waterless hand cleaners followed by washing with soap and water readily remove product from skin.
Clean-Up Methods
Use non-sparkling tools and equipment. Absorb or cover with dry earth, send or other non-combustible
material and transfer to sealable containers.
Large spills: Dike far ahead of liquid spill for later disposal.
Environment Precautions
Especially nothing
7. Handling and Storage
All employees who handle this ink should be trained to handle safely.
Handling (technical measures, precautions, safe handling material)
Prohibition of dropping and throwing
Storage (technical measures storage conditions, packaging material)
Keep out of reach of children and do not drink ink. Do not store ink in high or freezing temperature.
Keep ink out of direct sunlight. Do not store ink with acids,oxidizing agents or explosives.
Store with container tightly closed. Store containers in a cool, dry location, away from direct sunlight or
freezing temperature.
8. Exposure Controls / Personal Protection
Respiratory Protections
Use with adequate ventilation to avoid breathing vapors or mists minimal exposure vapors or mists
generated by this ink.
None required under normal conditions of use.
If respiratory protection is needed during emergency response situations, use only protection authorized in
29 CFR 1910,134, or applicable States regulations.
Hand Protection
Wear light-weight plastic or rubber gloves for routine industrial use.
Eye Protection
Wear appropriate protective eyeglasses or safety goggles.
Skin and Body Protection
Remove contaminated clothing immediately.
None required under normal conditions of use. If protection is needed, chemical protective clothing made
from natural rubber is generally acceptable.
9. Physical and Chemical Properties.
Physical State
Form: Solvent type ink
Color: Black
Odor: No strong odor is allowed.
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Information
o
: 25 oC
pH : 8.5-10.0 Measuring Temperature. C
Boiling Point (oC) : 99.6 oC (JIS-K2233)
Flash Point (oC) : Flash Point is not detected.(JIS-K2265 ) This ink will not burn.
o o
Auto Ignition Temperature ( C) : 410 C (ASTM-659)
Melting Point (oC) : 0.6 oC (JIS-K2249)
Explosion Properties : This product is considered non explosive material under normal use condition.
Measuring Temperature. (oC)
Vapor Pressure (pa) : Not yet determined.
Vapor Density (AIR=1) : Not yet determined.
15/4(oC)
Density (g / cm 3) : 1.06 (JIS-K2249) Measuring Temperature.
Solubility
Water Solubility Measuring Temp(oC): -
Water Solubility g / L : soluble
Other Solvent name : -
Other Solvent Solubility (g / L) : -
Measuring Temperature (oC) : -
Other Solvent Solubility
Octanol /Water Partition Coefficient : Not yet determined.
10. Stability and Reactivity
Stability
Stable
Conditions to Avoid
Extreme high or low temperatures
Materials to Avoid
Acid and strong oxidizer can cause a reaction.
Hazardous Decomposition Products
Carbon oxides, nitrogen oxides in fire.
1,3-Dimethyl-2-imidazolidinone
Combustible liquid. Material may burn, producing irritating and poisonous gases.
Organic compound A
Flammable, Vapor /air mixtures are explosive.
Hazardous polymerization conditions and released products
Will not occur.
11. Toxicological Information
Acute Toxicity
Acute Oral Toxicity
: rat LD50 >2000mg/Kg
Acute Dermal Toxicity
: rat LD50 >2000mg/Kg
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Black ink for Ink Jet Printer (No.404) May 9, 2005
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Acute Inhalation Toxicity
: No data
Sensitization
Acute Skin Irritation : Non-irritating
Acute Eye Irritation : Slight irritating
Acute Allergenic Effects : Non sensitization
Mean daily scores for skin sensitization
Carcinogenicity
Ames test : Negative
The carbon black contained in this product corresponds to IARC(2B).
12. Ecological Information
Acute Toxicity for fish
LC50 > 1000mg/L (96Hour) Orange killilfish
13. Disposal Consideration
Dispose of waste material in accordance with local, state and federal pollution regulations.
14. Transport Information
This ink is subject to the following transportation regulations as indicated:
IATA: Not regulated
DOT: Not regulated
ADR: Not regulated
Singapore land transport: Not regulated
15. Regulation Information
1,3-Dimethyl-2-imidazolidinone is subject to SNUR under 40C.F.R. section 721.9892 and to 12(b) export
notification reporting requirements.
SNUN S04-03 for 1,3-Dimethyl-2-imidazolidinone had completed on October 14, 2004.
EU Notification: All ingredients are listed on EINECS.
EU classification of ink as a whole is not classified.
The chemicals that are listed in California Proposition 65 are not contained in this ink.
Metal present in ink at concentration > 0.1ppm
Na+ =165ppm
16. Other Information
None
The information herein given in good faith and to the best knowledge but no warranty, express or implied, is made.
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