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3M Canada Company
1840 Oxford Street East, Post Office Box 5757
London, Ontario N6A 4T1
Medical Emergency Telephone: (519) 451-2500, Ext. 2222
Transportation Emergency Telephone (CANUTEC): (613) 996-6666
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Material Safety Data Sheet
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Document id : 06-1683-9 Issue date : 03/11/2005
Version : 36.00 Supersedes date : 21/10/2005
Copyright, 1997, 3M Canada Company. All rights reserved. Copying
and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information
is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold
or otherwise distributed with the intention of earning a profit
thereon.
Prepared by: Environmental Health and Safety Services Department, 3M
Canada Company
Telephone: (519) 452-2161, Fax: (519) 452-6015, Web Site: www.3M.ca
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1 Product Identification
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Tradename:
3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (PRODUCT NO. 4,
TWIST 'N FILL(TM) SYSTEM)
Product ID:
70-0711-6337-5 70-0711-9216-8 FN-5100-1191-2 FN-5100-1192-0
XN-1015-1339-0 XN-1015-4513-7 XN-1016-5549-3 70-0705-2685-3
70-0705-2686-1 70-0705-4315-5 70-0705-4316-3 70-0705-4904-6
70-0705-8964-6 70-0707-1409-5 70-0708-3905-8 70-0708-3992-6
70-0709-9000-0 70-0710-0961-0
Intended Use of Product:
To Be Used With Twist 'N Fill Dispenser
Makes 102 liters Ready-To-Use product.
Division:
COMMERCIAL CARE DIVISION
Limitations on Use of Product:
Not intended for use outside of dispenser
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2 Composition/Information on Ingredients
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Ingredient Name CAS Number Percentage
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1-OCTYL-2-PYRROLIDINONE 2687-94-7 15 - 40
HYDROXYACETIC ACID 79-14-1 10 - 30
WATER 7732-18-5 10 - 30
MALIC ACID 6915-15-7 10 - 30
FRAGRANCE Mixture 1-3
TRANS-3,7-DIMETHYL-2,6-OCTADIENOL 106-24-1 1-2
ETHYL ALCOHOL 64-17-5 0.5 - 1.5
METHOXYACETIC ACID 625-45-6 0.1 - 1.0
BENZYL-C12-16-ALKYLDIMETHYL 68424-85-1 1-2
AMMONIUM CHLORIDES
OCTYL DECYL DIMETHYL AMMONIUM 32426-11-2 0.5 - 1.5
CHLORIDE
DIDECYL DIMETHYL AMMONIUM CHLORIDE 7173-51-5 0.1 - 0.9
DIOCTYL DIMETHYL AMMONIUM CHLORIDE 5538-94-3 0.1 - 0.6
NOTE:
Each percentage is expressed as the ratio of the weight of the
ingredient to the weight of the controlled product.
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3 Hazards Identification
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Critical Hazards:
Corrosive (Eye Burns): Signs/symptoms can include cloudy appearance
of the cornea, chemical burns, severe pain, tearing, ulcerations,
significantly impaired vision or complete loss of vision.
Corrosive (Skin Burns): Signs/symptoms can include localized
redness, swelling, itching, intense pain, blistering, ulceration,
and tissue destruction.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may
include redness, swelling, blistering, and itching.
May be absorbed following inhalation and cause target organ effects.
May be absorbed following ingestion and cause target organ effects.
See Sections 7 and 11 for further information.
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4 First Aid Measures
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Instructions for Eye Contact:
Immediately flush eyes with large amounts of water for at least 15
minutes. Get immediate medical attention.
Instructions for Skin Contact:
Remove contaminated clothing and shoes. Immediately flush skin with
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large amounts of water for at least 15 minutes. Get immediate
medical attention. Wash contaminated clothing and clean shoes
before reuse.
Instructions for Inhalation:
Remove person to fresh air. If signs/symptoms develop, get medical
attention.
Instructions for Ingestion:
Do not induce vomiting. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get immediate
medical attention.
Special Instructions:
Measures against circulatory shock, respiratory depression, and
convulsion may be needed. Probable mucosal damage may
contraindicate the use of gastric lavage.
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5 Fire Fighting Measures
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Flash point: Not applicable
Lower Explosive Limit (%): Not applicable
Upper Explosive Limit (%): Not applicable
Autoignition temperature: Not applicable
Suitable Extinguishing Media:
Non-flammable
Exposure Hazards during Fire:
Material will not burn.
Combustion Products from Fire:
Under recommended usage conditions, hazardous decomposition
products are not expected. Hazardous decomposition products may
occur as a result of oxidation, heating, or reaction with another
material.
Fire Fighting Procedures:
No data available.
NFPA: Health 3
NFPA: Fire 0
NFPA: Reactivity 0
NFPA: Unusual Reaction Hazard none
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6 Accidental Release Measures
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Personal Precautions:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation,
and personal protective equipment. Call 3M-HELPS line
(1-800-364-3577) for more information on handling and managing the
spill.
Spill Response:
Evacuate unprotected and untrained personnel from hazard area. The
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spill should be cleaned up by qualified personnel. Ventilate the
area with fresh air. Contain spill. Working from around the edges
of the spill inward, cover with bentonite, vermiculite, or
commercially available inorganic absorbent material. Mix in
sufficient absorbent until it appears dry. Remember, adding an
absorbent material does not remove a toxic, corrosivity or
flammability hazard. Collect as much of the spilled material as
possible. Clean up residue with a dilute solution (approximately 1
to 5%) of soda ash (sodium carbonate) or baking soda (sodium
bicarbonate) in water. Collect the resulting residue containing
solution. Place in a metal container approved for use in
transportation by appropriate authorities. The container must be
lined with polyethylene plastic or contain a plastic drum liner
made of polyethylene. Cover, but do not seal for 48 hours. Dispose
of collected material as soon as possible.
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7 Handling and Storage
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Storage Requirements:
Do not store containers on their sides. Store away from areas where
product may come into contact with food or pharmaceuticals. Store
away from strong bases.
Incompatible Materials:
Strong bases;
Ventilation:
Keep container in well-ventilated area.
Use Instructions:
This product is not intended to be used without prior dilution as
specified on the product label. Do not use on marble or marble
products.
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8 Exposure Controls/Personal Protection
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Personal Protection
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Eye Protection:
Avoid eye contact with vapours, mists, or spray. NOTE: When used as
directed and diluted and dispensed with a TWIST 'n FILL(TM)
Chemical Dispenser, eye contact with the concentrate is not
expected to occur.
If the product is not used with the Twist 'n Fill system or if
there is an accidental release, the following eye protection is
recommended: Indirect vented goggles; full face shield;
Hand Protection:
NOTE: When used as directed and diluted and dispensed with a TWIST
'n FILL(TM) Chemical Dispenser, skin contact with the concentrate
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is not expected to occur. If the product is not used with the Twist
'n Fill system or if there is an accidental release, Select and use
gloves and/or protective clothing to prevent skin contact based on
the results of an exposure assessment. Consult with your glove
and/or protective clothing manufacturer for selection of
appropriate compatible materials. Wear appropriate gloves when
handling this material. The following glove material(s) are
recommended: butyl rubber; nitrile rubber;
Skin Protection:
Avoid skin contact.
NOTE: When used as directed and diluted and dispensed with a TWIST
'n FILL(TM) Chemical Dispenser, skin contact with the concentrate
is not expected to occur.
If the product is not used with the Twist 'n Fill system or if
there is an accidental release,
Select and use gloves and/or protective clothing to prevent skin
contact based on the results of an exposure assessment. Consult
with your glove and/or protective clothing manufacturer for
selection of appropriate compatible materials.
Respiratory Protection:
Avoid breathing of vapours, mists or spray.
NOTE: When used as directed and diluted and dispensed with a TWIST
'n FILL(TM) Chemical Dispenser, respiratory protection is not
required.
If the product is not used with the Twist 'n Fill system or if
there is an accidental release,
Select one of the following approved respirators based on airborne
concentration of contaminants and in accordance with regulations:
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Fullface air-purifying respirator with organic vapour/acid gas
cartridges; Consult the current 3M Respirator Selection Guide for
additional information or call 1-800-243-4630 for 3M technical
assistance.
Ingestion (Prevention):
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Keep out of the reach of
children.
Recommended Ventilation:
NOTE: When used as directed and diluted and dispensed with a TWIST
'n FILL(TM) Chemical Dispenser, special ventilation is not
required. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below Occupational
Exposure Limits and/or control mist, vapor, or spray. If
ventilation is not adequate, use respiratory protection equipment.
Ingredient Exposure Data
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1-OCTYL-2-PYRROLIDINONE (2687-94-7)
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Specific Ingredient Data
No data available.
LD50 (rat, oral) 2050 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
HYDROXYACETIC ACID (79-14-1)
Specific Ingredient Data
No data available.
LD50 (rat, oral) 1950 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
CMRG: TWA 10 mg/m3
WATER (7732-18-5)
LD50 (rat, oral) >90 ml/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
MALIC ACID (6915-15-7)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
FRAGRANCE (Mixture)
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Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
TRANS-3,7-DIMETHYL-2,6-OCTADIENOL (106-24-1)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
ETHYL ALCOHOL (64-17-5)
LD50 (rat, oral) 7060 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: TWA 1000 ppm (Table A4)
ACGIH: TWA 1880 mg/m3 (Table A4)
METHOXYACETIC ACID (625-45-6)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM CHLORIDES (68424-85-1)
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LD50 (rat, oral) 426 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
OCTYL DECYL DIMETHYL AMMONIUM CHLORIDE (32426-11-2)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
DIDECYL DIMETHYL AMMONIUM CHLORIDE (7173-51-5)
LD50 (rat, oral) 84 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
DIOCTYL DIMETHYL AMMONIUM CHLORIDE (5538-94-3)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
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9 Physical and Chemical Properties
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Physical form,Color,Odour: Liquid; Green; with floral
fragrance;
Odour Threshold: No data available.
pH: Approx 0.9 -1.5
Boiling point/boiling range: >35 C
Melting point/melting range: Not applicable
Vapour pressure: 15 -40 psia at 55 C
Water Solubility: Complete
Specific gravity: Approximately1.12
Vapour density: Not available
Volatile organic compounds: 1 -5 % CARB
Evaporation rate: Not available
Viscosity: Approximately100 centipoise
Percent Volatile: Not applicable
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10 Stability and Reactivity
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Conditions to Avoid:
None known.
Materials to Avoid:
Strong bases;
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Hazardous Decomposition:
Under recommended usage conditions, hazardous decomposition
products are not expected. Hazardous decomposition products may
occur as a result of oxidation, heating, or reaction with another
material.
Stability and Reactivity:
Stable. Hazardous polymerization will not occur.
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11 Toxicological Information
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Effects from Eye Contact:
Corrosive (Eye Burns): Signs/symptoms can include cloudy appearance
of the cornea, chemical burns, severe pain, tearing, ulcerations,
significantly impaired vision or complete loss of vision.
Effects from Skin Contact:
Corrosive (Skin Burns): Signs/symptoms can include localized
redness, swelling, itching, intense pain, blistering, ulceration,
and tissue destruction.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may
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include redness, swelling, blistering, and itching.
Effects from Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
May be absorbed following inhalation and cause target organ
effects.
Effects from Ingestion:
Gastrointestinal Corrosion: Signs/symptoms may include severe
mouth, throat and abdominal pain, nausea, vomiting, and diarrhea;
blood in the feces and/or vomitus may also be seen.
May cause chemical gastrointestinal burns.
May be absorbed following ingestion and cause target organ effects.
Sensitization Information:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may
include redness, swelling, blistering, and itching.
Carcinogenicity:
No data available.
Mutagenicity:
No data available.
Reproductive Effects:
No data available.
Component Based Information:
No data available.
Product Based Information:
No data available.
Other Effects & Information:
Central Nervous System (CNS) Depression: Signs/symptoms may include
headache, dizziness, drowsiness, incoordination, nausea, slowed
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reaction time, slurred speech, giddiness, and unconsciousness.
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12 Ecological Information
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Environmental Data:
Ecotoxicity Data:
A 3M Product Environmental Data Sheet (PED) is available. Not
determined. A conservative assessment indicates this product
presents a low environmental risk because use and disposal are
unlikely to result in the significant release of components to the
environment.
Ecofate Data:
A 3M Product Environmental Data Sheet (PED) is available. Not
determined.
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13 Disposal Considerations
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Product as Sold:
Incinerate in a permitted hazardous waste incinerator in the
presence of a combustible material. As a disposal alternative,
dispose of waste product in a permitted hazardous waste facility.
Product Packaging:
No data available.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
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14 Transportation Information
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Transportation of Dangerous Goods
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TDG Classification: Consumer Commodity
International Dangerous Goods Classification
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15 Regulatory Information
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WHMIS Classification: D2B, E
NOTE:
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
Product Certifications:
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The product on this MSDS, or all its components, is included on the
following countries' chemical inventories, as noted:
AICS - Australian Inventory of Chemical Substances
DSL - Domestic Substances List (Canada)
CICS - Chinese Inventory of Chemical Substances
KECI - Korean Existing Chemicals Inventory
TSCA - Toxic Substances Control Act (USA)
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16 Other Information
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Reason for Reissue:
The following Sections and topics have been updated or revised:
Section 1 - Intended Use of Product;
Section 2 - Composition/Information on Ingredients;
Section 3 - Hazards Identification - Critical Hazards;
Section 4 - First Aid Measures;
Section 5 - Fire Fighting Measures
Section 6 - Accidental Release Measures;
Section 7 - Handling and Storage;
Section 8 - Exposure Controls/Personal Protection;
Section 9 - Physical and Chemical Properties;
Section 10 - Stability and Reactivity;
Section 11 - Toxicological Information;
Section 12 - Ecological Information
Section 13 - Disposal Considerations;
Section 14 - Transportation Information
Section 15 - Regulatory Information
WHMIS Classification change
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. 3M MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT
LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is
fit for a particular purpose and suitable for user's method of use or
application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within
the user's knowledge and control, it is essential that the user
evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or
application.
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