MATERIAL SAFETY DATA SHEET
Page 1 of 4
1. PRO DUCT AND CO MPANY IDENTIFICATIO N
NAME: PREMIUM BREAK
USE: ALKALI LAUNDRY BOOSTER
NE
MSDS # 105709P
U S CHEMICAL, 316HARTSTREET, W ATERTOW N,W I53094 USA
MEDI CALEMERGENCY #: 1-800-851-7145 EXT. 075 USA
SPILLEMERGENCY #: 1-800-424-9300 USA
PRODUCTI NFORMATI #:1-
ON 800-558-9566 ( 8A.M. TO 5 P.M. CSTMONDAY TO FRI
DAY)
I
NTERNETADDRESS:W W W .USCHEMI CAL.COM
REVI ED 3- 06 REVI
EW 20- SED 3- 06 SECTI REVI
20- ON SED: 1
2. HAZARDS IDENTIFICATIO N
EMERGENCY OVERVIEW :
DANGER. CORROSI LI D. CAUSES EYE AND SKI BURNS.
VE QUI N
HARMFUL OR FATAL I SW ALLOW ED.
F
PRINCIPLE ROUTES OF EXPOSURE: EYES,SKI I
N, NGESTI
ON,I
NHALATI
ON.
POTENTIAL ACUTE HEALTH EFFECTS
EYES: CORROSIVE. CAUSES EYE BURNS. MAY CAUSE PERMANENT DAMAGE I
NCLUDI BLI
NG NDNESS
WITHOUT I
MMEDIATE FIRST AI TREATMENT.
D
SKIN: CORROSIVE. CAUSES SKI BURNS. MAY CAUSE PERMANENT DAMAGE.
N
HARMFUL CONTACT MAY NOT CAUSE I
MMEDIATE PAIN.
INHALATION: CORROSIVE. I
NHALATI OF MI
ON STS MAY CAUSE CORROSI EFFECTS TO NOSE,THROAT,
VE
AND RESPI
RATORY SYSTEM.
INGESTION: CORROSI VE. MAY CAUSE BURNS TO MOUTH,THROAT AND STOMACH.
HARMFUL OR FATAL I SW ALLOW ED.
F
MEDICAL CONDITIONS AGGRAVATED: NONE KNOW N.
3. CO MPO SITIO N /INFO RMATIO N O N ING REDIENTS
% BY W T LC50/
LD50
HAZARDOUS INGREDIENT CAS #
SEE 11.0
SODI HYDROXI
UM DE 1310- 2
73- 30.0 鈥? 60.0
STATE RI
GHT TO KNOW : THI PRODUCT CONTAI
S NS: W ATER/7732- 5,
18-
SODI HYDROXI 1310- 2,SODI AMI
UM DE/ 73- 2235- 0
43-
UM NOTRI
METHYLENE PHOSPHONATE/
PREMIUM BREAK MSDS # 105709P
4. FIRST AID MEASURES Page 2 of 4
EYES: FLOOD WITH LUKEWARM (NOT HOT) WATER POURED FROM A LARGE GLASS 2 OR 3
INCHES FROM EYES. REMOVE CONTACTS. HAVE PATIENT BLINK AS MUCH AS POSSIBLE
WHILE FLOODING THE EYES. CONTINUE FOR AT LEAST 15 MINUTES.
SKIN: REMOVE CONTAMINATED CLOTHES, FLOOD WITH WATER FOR 15 MINUTES.
INHALATION: MOVE VICTIM TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF PATIENT IS
NOT BREATHING.
INGESTION: DO NOT INDUCE VOMITING. IF PATIENT IS CONSCIOUS AND CAN SWALLOW,
ADMINISTER MILK OR WATER.
ADMINISTER FIRST AID TREATMENT AS STATED ABOVE,THEN CALL 1- 800-851- 7145 EXT.
075 OR CONTACT PHYSICIAN FOR FURTHER MEDICAL INSTRUCTIONS.
NOTE TO PHYSICIAN: CALL 1-800-851-7145 EXT. 075 FOR ASSISTANCE WITH THE MANAGEMENT OF EXPOSURES.
5. FIRE-FIGHTING MEASURES
FLAMMABILITY: NO HAZARD.
FLASH POINT: N.AP.
PRODUCTS OF COMBUSTION: SEE SECTION 10.
SUITABLE EXTINGUISHING MEDIA: FOR FIRES IN AREA, USE APPROPRIATE MEDIA.
FOR EXAMPLE: WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE, OR ALCOHOL FOAM.
SPECIFIC HAZARDS: CORROSIVE PRODUCT MAY REACT WITH CERTAIN METALS. SEE 8. AND 10.
SPECIFIC METHODS: NORMAL FIRE FIGHTING PROCEDURES MAY BE USED.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS: CORROSIVE. PUT ON PERSONAL PROTECTIVE EQUIPMENT. SEE 8.
SPILL RESPONSE: EVACUATE UNPROTECTED PERSONNEL FROM AREA. WEAR PROPER
PROTECTIVE EQUIPMENT INCLUDING RUBBER BOOTS. VENTILATE AREA IF NEEDED.
STOP LEAK IF YOU CAN DO SO WITHOUT RISK. DIKE OR DAM LARGE SPILLS.
AVOID DIRECT DISCHARGE TO SEWER AND SURFACE WATERS. PUMP OR SCOOP TO CONTAINER
OR SOAK UP WITH NON-COMBUSTIBLE INERT ABSORBENT MATERIALS. AFTER SPILL COLLECTION,
RINSE AREA WITH WATER AND FOLLOW WITH NORMAL CLEAN-UP PROCEDURES.
BE CAREFUL AS SPILLS ARE SLIPPERY.
7. HANDLING AND STORAGE
HANDLING: FOLLOW ALL LABEL DIRECTIONS. INSTRUCT PERSONNEL ABOUT
PROPER USE, HAZARDS, PRECAUTIONS, AND FIRST AID MEASURES.
AVOID INHALATION, INGESTION, AND CONTACT WITH SKIN, EYES AND CLOTHING.
DO NOT TASTE OR SWALLOW. REMOVE AND WASH CONTAMINATED CLOTHING AND
FOOTWEAR BEFORE RE-USE. PRODUCT RESIDUE MAY REMAIN IN EMPTY CONTAINERS.
HANDLE CAREFULLY TO AVOID DAMAGING CONTAINER.
STORAGE: ROTATE STOCK REGULARLY. KEEP CONTAINER CLOSED WHEN NOT IN USE.
AVOID TEMPERATURES BELOW 35 F OR ABOVE 120 F. PROTECT FROM FREEZING.
STORAGE AT AMBIENT TEMPERATURES IN A DRY AREA OUT OF DIRECT SUNLIGHT IS
RECOMMENDED. KEEP AWAY FROM FOOD AND DRINK. KEEP OUT OF CHILDREN鈥? REACH.
S
PREMIUM BREAK MSDS # 105709P
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Page 3 of 4
EXPOSURE LIMITS:
SODIUM HYDROXIDE = 2 MG/M3 CEILING LIMIT (ACGIH), 2 MG/M3 TWA (OSHA)
ENGINEERING CONTROLS: NONE REQUIRED. GENERAL ROOM VENTILATION IS TYPICALLY ADEQUATE.
PERSONAL PROTECTION
EYES: SPLASH PROOF SAFEY GLASSES, SAFETY GOGGLES AND AN EYE WASH STATION.
HANDS: CHEMICAL RESISTANT GLOVES: RUBBER OR NEOPRENE. LONG TYPE IF NEEDED.
RESPIRATORY: IF MISTS/VAPORS ARE NOT CONTROLLED BY VENTILATION, WEAR SUITABLE
RESPIRATOR.
FEET: TYPICALLY NOT NEEDED. WEAR BOOTS DURING SPILL & WHEN EXPOSURE IS POSSIBLE.
BODY: IF MAJ EXPOSURE IS POSSIBLE, WEAR FULL-COVER PROTECTIVE CLOTHING.
OR
9. PHYSICAL AND CHEMICAL PROPERTIES
COLOR: COLORLESS FLASH POINT: N.AP.
ODOR : NONE UEL: N.AP.
pH CONCENTRATE: GREATER THAN 13.0 (BASIC) LEL: N.AP.
pH @ 2500 PPM SOLUTION: N.AP. EVAPORATION RATE: N.AP.
pH @ USE DILUTION: N.AP. ODOR THRESHOLD: N.AP
PHYSICAL STATE: LIQUID VAPOR PRESSURE: N.AP
SPECIFIC GRAVITY: 1.443 VAPOR DENSITY: N. AP.
VISCOSITY: NON-VISCOUS COEFF. OIL/WATER: N.AP.
BOILING POINT: N.AP. WATER SOLUBILITY: COMPLETE
MELTING POINT: N.AP. OTHER: N.AP.
10. STABILITY AND REACTIVITY
STABLE: YES
CONDITIONS TO AVOID: AVOID TEMPERATURES BELOW 35 F OR ABOVE 120 F.
MATERIALS TO AVOID: AVOID MIXING DIRECTLY WITH ANY OTHER CLEANING PRODUCT.
AVOID ACIDS AND VARIOUS METALS (ALUMINUM, ZINC, TIN, BRASS OR BRONZE) WHICH CAN
GENERATE FLAMMABLE HYDROGEN GAS. MIX ONLY WITH WATER.
DECOMPOSITION PRODUCTS: FIRE OR MIXING WITH INCOMPATIBLE MATERIALS MAY
PRODUCE OXIDES OF CARBON AND OTHER TOXIC OR IRRITATING FUMES.
POSSIBILITY OF HAZARDOUS REACTIONS: AVOID MIXING DIRECTLY WITH ACIDS.
11. TOXICOLOGICAL INFORMATION
ACUTE EFFECTS: CORROSIVE. SEE SECTION 2.
CHRONIC EFFECTS: NONE KNOWN. NO REPORTABLE CARCINOGENS, MUTAGENS,
SENSITIZERS, SYNERGISTIC MATERIALS, TERATOGENS, OR REPRODUCTIVE TOXINS.
LC50/LD50: SODIUM HYDROXIDE 50% : 350 MG/KG ORAL-RAT LD50
TARGET ORGANS: EYES, SKIN, RESPIRATORY SYSTEM.
OTHER TOXIC EFFECTS: NONE KNOWN.
PREMIUM BREAK MSDS # 105709P
12. ECOLOGICAL INFORMATION Page 4 of 4
NOT AVAILABLE.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: UNDILUTED PRODUCT IS REGULATED UNDER ENVIRONMENTAL
AND TRANSPORTATION LAWS AS A CORROSIVE WASTE (RCRA CLASS D002).
DISPOSE OF ACCORDING TO ALL FEDERAL, STATE, PROVINCIAL AND LOCAL LAWS AND
REGULATIONS. CONSULT STATE AND LOCAL AUTHORITIES FOR RESTRICTIONS ON
DISPOSAL OF CHEMICAL WASTE. MANAGE CHEMICAL WASTES THROUGH AN APPROVED
WASTE TREATMENT FACILITY. DO NOT REUSE EMPTY CONTAINER.
RINSE EMPTY CONTAINER THOROUGHLY WITH WATER BEFORE DISCARDING
CONTAINER IN ACCORDANCE WITH CURRENT LOCAL COMMUNITY CODES. PLEASE
RECYCLE EMPTY CONTAINER WHENEVER POSSIBLE.
14. TRANSPORT INFORMATION
DOT/TDG: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (CONTAINS SODIUM HYDROXIDE), 8, UN3266, II
DOT RQ: N.AP.
DOT ERG #: 154
15. REGULATORY INFORMATION
EPA CERCLA RQ: SODIUM HYDROXIDE = 1000 LBS
EPA REGISTERED: NO
EPA %VOC: 0.00
EPA VOC RULE: THIS PRODUCT DOES NOT CONTAIN VOLATILE ORGANIC COMPOUNDS.
KOSHER ( CRC) YES
:
OSHA HAZARDOUS: YES
PHOSPHORUS CONTENT: SEE LABEL
PROPOSITION 65: N.AP.
SARA 311/312 HAZARDS: ACUTE
SARA 313 CHEMICALS: NO
STATE RIGHT TO KNOW: SEE SECTION 3 FOR CHEMICAL NAMES.
TSCA INVENTORY STATUS: ALL COMPONENTS ARE LISTED ON THE INVENTORY.
WHMIS CLASS: E
16. OTHER INFORMATION
NFPA RATING: HEALTH-3/FLAMMABILITY-0/REACTIVITY-1/SPECIAL HAZARD-N.AP.
HMIS RATING: HEALTH-3/FLAMMABILITY-0/REACTIVITY-1/PERSONAL PROTECTION-SEE 8.0
N.AV. = NOT AVAILABLE N.AP. = NOT APPLICABLE PREPARED BY: HEALTH AND SAFETY
NOTICE TO READER
THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED TECHNICALLY
RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESS OR IMPLIED, AS TO THE ACCURACY
OF THE INFORMATION CONTAINED WITHIN. ACTUAL CONDITIONS OF USE AND HANDLING ARE
BEYOND SELLER鈥橲 CONTROL. USER IS RESPONSIBLE FOR EVALUATING ALL AVAILABLE
INFORMATION WHEN USING PRODUCT FOR ANY PARTICULAR USE AND TO COMPLY WITH ALL
FEDERAL, STATE, PROVINCIAL AND LOCAL LAWS AND REGULATIONS.
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