Material Safety Data Sheet
Freeman 705-15 Hardener
Date of Preparation: January 3, 2007 Revision:
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: Freeman 705-15 Hardener HMIS
Chemical Family: Amine 2
H
CAS Number: N/A 1
F
Other Designations: N/A 0
R
General Use: N/A PPE鈥?
Manufacturer: Freeman Manufacturing and Supply Company, 1101 Moore Road, Avon, OH 44011, 鈥燬ec. 8
Phone (440)934-1902, FAX (440)934-7200, Hours of Operation 8-5, Emergency Phone Number 800-424-9300.
Emergency Overview
Irritant,
Section 2 - Composition / Information on Ingredients
Ingredient Name CAS Number
Polyamine Adduct Proprietary
Polyamine Adduct Proprietary
Imidazole 931-36-2
Ingredient OSHA PEL ACGIH TLV
TWA STEL TWA STEL
none estab. none estab. none estab. none estab.
Polyamine Adduct
none estab. none estab. none estab. none estab.
Polyamine Adduct
none estab. none estab. none estab. none estab.
Imidazole
Section 3 - Physical and Chemical Properties
Physical State: Liquid pH: N/A
Appearance and Odor: Amber, Amine odor Water Solubility: Moderate
Odor Threshold: N/A Other Solubilities: N/A
Viscosity: 100-1000 cps Boiling Point: N/A
Vapor Pressure: N/A Freezing/Melting Point: N/A
Vapor Density (Air=1): >1 % Volatile: N/A
Evaporation Rate: <0.01
Specific Gravity (H2O=1, at 4 掳C): 1.06
Section 4 - Fire-Fighting Measures
NFPA
Flash Point: 200 掳F (93掳C)
Flash Point Method: PMCC
1
Burning Rate: N/A
0
2
Autoignition Temperature: N/A
鈥?
LEL: N/E
UEL: N/E
Flammability Classification: N/A
Extinguishing Media: Water, fog, foam, dry chemical, CO2.
Unusual Fire or Explosion Hazards: Container areas exposed to intense heat or flame should be cooled with water to prevent
pressure build-up and/or weakening of container structure.
Hazardous Combustion Products: N/A
Fire-Fighting Instructions: Do not enter confined fire space without full protective hear including a positive pressure, self-
contained, NIOSH approved breathing apparatus. Cool fire exposed container with water. Do not release runoff from fire
control methods to sewers or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing
apparatus (SCBA) with a full face piece operated in pressure-demand or positive-pressure mode.
Freeman 705-15 Hardener Revision:
Section 5 - Stability and Reactivity
Stability: Freeman 705-15 Hardener is stable at room temperature in closed containers under normal storage and handling
conditions.
Polymerization: Hazardous polymerization cannot occur. Avoid mixing resin and hardener in uncontrollable quantities.
Chemical Incompatibilities: Incompatible with strong oxidizing agents, strong acids and bases, secondary aliphatic amines and
mercaptans.
Conditions to Avoid: Avoid high temperatures, open flames and unscheduled contact with curing agents.
Hazardous Decomposition Products: Thermal oxidative decomposition of Freeman 705-15 Hardener can produce carbon
dioxide, carbon monoxide, by products may include oxides of nitrogen when burned.
Section 6 - Health Hazard Information
Potential Health Effects
Primary Entry Routes: Inhalation, skin
Target Organs: N/A
Acute Effects N/A
Signs and Symptoms:
Inhalation: Vapor is irritating to the upper respiratory system and mucous membranes.
Eye: Product can cause severe eye irritation, swelling and/or chemical burn. Contact lenses should not be worn when working
with this material.
Skin: Skin contact may result in irritation or chemical burn.
Ingestion: Liquid causes damage to mucous membrane if swallowed.
Carcinogenicity: IARC, NTP, and OSHA do not list any component as carcinogenic.
Medical Conditions Aggravated by Long-Term Exposure: N/A
Chronic Effects: N/A
Emergency and First Aid Procedures
Inhalation: Remove victim to fresh air.
Eye Contact: Flush eyes with generous amounts of water for at least 15 minutes. Get medical attention immediately.
Skin Contact: Immediately wash skin with soap and water. Wash contaminated clothing before reuse.
Ingestion: If swallowed do not induce vomiting. Give large amounts of water or milk if available. Call a physician. Treatment
based on judgment of the physician in response to reactions of the patient.
After first aid, get appropriate in-plant, paramedic, or community medical support.
Note to Physicians: N/A
Special Precautions/Procedures: N/A
Section 7 - Spill, Leak, and Disposal Procedures
Precautions: Store at ambient temperatures in well ventilated area. Avoid sparks, open flames and extreme heat. Store
separately from epoxy resins. Protect container from physical damage. Container, even those that have been emptied, can
contain product residues. Handle in accordance with good industrial practices. Avoid prolonged or repeated contact with skin.
Wash with soap before eating, drinking, smoking, applying cosmetics, or using toilet facilities. Launder contaminate clothing
before use.
Spill /Leak Procedures: Use cautious judgment when cleaning spills.
Small Spills: May be collected with adsorbent material, such as clay or sand.
Large Spills: Should be diked and contained with absorbent materials. Flush area with water spray to remove residue. Dispose
of flush legally.
Containment: For large spills, dike far ahead of liquid spill for later disposal. Do not release into sewers or waterways.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Disposal: Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state, and
local regulations.
Disposal Regulatory Requirements: N/A
Container Cleaning and Disposal: N/A
Ecological Information: N/A
EPA Regulations:
RCRA Hazardous Waste Number: Not listed (40 CFR 261.33)
RCRA Hazardous Waste Classification (40 CFR 261): Not classified
CERCLA Hazardous Substance (40 CFR 302.4) listed/unlisted specific per RCRA, Sec. 3001; CWA, Sec. 311 (b)(4); CWA,
Sec. 307(a), CAA, Sec. 112
CERCLA Reportable Quantity (RQ), lb (kg)
Page 2 of 3
Revision: Freeman 705-15 Hardener
SARA 311/312 Codes:
SARA Toxic Chemical (40 CFR 372.65): Not listed
SARA EHS (Extremely Hazardous Substance) (40 CFR 355): Not listed, Threshold Planning Quantity (TPQ)
OSHA Regulations:
Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed
OSHA Specifically Regulated Substance (29CFR 1910
State Regulations:
May contain trace amounts of Triethylene Tetramine (CAS # 112-24-3) which is on the New Jersey and Pennsylvania Right to
Know Lists.
May contain trace amounts of Aminoethylpiperazine (CAS # 140-31-8) which is on the New Jersey, Pennsylvania and
Massachusetts Right to Know Lists.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: N/A
Ventilation: Use only with adequate ventilation. Local exhaust is recommended. General Mechanical can be used as a backup
system. Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec. 2).
Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its
source.
Administrative Controls: N/A
Respiratory Protection: Wear NIOSH approved respiratory protection where exposure limits are exceeded or in the absence of
proper environmental control. Seek professional advice prior to respirator selection and use. Follow OSHA respirator
regulations (29 CFR 1910.134) and, if necessary, wear a MSHA/NIOSH-approved respirator. Select respirator based on its
suitability to provide adequate worker protection for given working conditions, level of airborne contamination, and presence of
sufficient oxygen. For emergency or nonroutine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA.
Protective Clothing/Equipment: Wear chemically protective gloves, boots, aprons, and gauntlets to prevent prolonged or
repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations
(29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in
conjunction with contact lenses.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area.
Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this
material from your shoes and clean personal protective equipment.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before
eating, drinking, smoking, using the toilet, or applying cosmetics.
Section 9 - Special Precautions and Comments
Handling Precautions:
Storage Requirements:
DOT Transportation Data (49 CFR 172.101):
Shipping Name: Liquid Plastic, N.O. I Packaging Quantity Limitations
Shipping Symbols: Authorizations a) Passenger, Aircraft, or Railcar:
Hazard Class: Not Regulated a) Exceptions: b) Cargo Aircraft Only:
ID No.: b) Non-bulk Packaging:
Packing Group: c) Bulk Packaging: Vessel Stowage Requirements
Label: a) Vessel Stowage:
Special Provisions (172.102): b) Other:
Prepared By:
Revision Notes:
Disclaimer: The following supersedes Buyer鈥檚 documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,
EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under no
circumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breach of warranty,
strict of liability arising in connection with the product(s). Buyer鈥檚 sole remedy and Seller鈥檚 sole liability for any claims shall be
Buyer鈥檚 purchase price. Data and results are based on controlled lab work and must be confirmed by Buyer by testing for its
intended conditions of use. The product(s) has not been tested for, and is therefore not recommended for, uses for which
prolonged contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation within the
human body is intended.
Page 3 of 3
|