MATERIAL SAFETY DATA SHEET
ARISTA
RAPID E-6 COLOR FIRST DEVELOPER
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 COLOR FIRST DEVELOPER
Product Number: 101262, 101272, 101292 Date Prepared: 04/23/2007
Customer Information Phone Number: 1-800-521-4042
CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS OHSA PEL ACGIH TLV Weight %
POTASSIUM METABISULFITE 16731-55-8 N.E. N.E. 5-10
2, 5-DIHYDROXYBENZENESULFONIC
ACID MONOSODIUM SALT 21799-87-1 15 mg/m³ 10 mg/m³ 5-10
POTASSIUM CARBONATE 584-08-7 15 mg/m³ 10mg/m³ 1-5
POTASSIUM HYDROXIDE 1310-58-3 N.E. 2mg/m³ CEILING 1-5
SODIUM BICARBONATE 144-55-8 N.E. N.E. 1-5
PENTASODIUM DTPA MIXTURE N.E. N.E. <2
3. HAZARDOUS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Eye Contact: Causes severe irritation and burns.
Inhalation: Expected to be a low hazard for recommended handling. In contact with strong acids or
if heated, sulfites may liberate sulfur dioxide gas which is irritating to respiratory tract.
Ingestion: May be harmful if swallowed, especially to sulfite-sensitive individuals.
Skin Contact: Causes irritation; may cause allergic reaction.
Signs And Symptoms Of Exposure: Eye irritation, respiratory irritation, dermatitis, difficulty
breathing, abdominal pain, skin irritation, mucus membrane irritation, coughing, nausea,
diarrhea.
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate
medical attention.
Inhalation: If symptomatic, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash
contaminated clothes before reuse. Get medical attention if irritation develops.
Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic
ailments, should consult a physician before using this product. Some asthmatics or sulfite-
sensitive persons may experience wheezing, chest tightness, stomach upset, hives, faintness,
weakness, and diarrhea.
Supplemental Health Information: None of the components in this product is listed by IARC, NTP,
or OSHA as carcinogen.
Date: 6/19/07 Rapid E-6 First Developer 1/4
MATERIAL SAFETY DATA SHEET
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
Flash Point: Nonflammable Flash Point Method: Not applicable Auto ignition: Not applicable
LEL: Not applicable UEL: Not applicable
Extinguishing Media: Use agent appropriate for surrounding fire.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
Unusual Fire And Explosion Hazards: Fire or excessive heat may cause production of hazardous
decomposition products.
Combustion Products: Carbon dioxide, carbon monoxide, and oxides of sulfur.
6. ACCIDENTAL RELEASE MEASURES
Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards
and safety precautions before proceeding with cleanup. Use appropriate personal protective
equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from
entering sewers, waterways or low areas. Absorb spillage in inert material. Soak up with sawdust,
sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for
disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting
authority and may require pre-treatment.
7. HANDLING AND STORAGE
Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well-ventilated area. Keep
containers closed. Do not store with incompatible materials. Do not store or consume food, drink,
or tobacco where they may become contaminated with this material.
Other Precautions: All labeled precautions must be observed when handling, storing and
transporting empty containers due to product residues. Triple rinse before disposal.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use of respiratory protection is generally not required. However, if use
conditions generate vapors or fumes, use a NIOSH approved acid gas respirator.
Ventilation: Provide exhaust ventilation sufficient to keep the airborne concentration of this product
below its exposure limits.
Protective Gloves: Rubber or neoprene waterproof gloves are recommended.
Eye Protection: Safety glasses with side shields (or goggles).
Other Protective Clothing or Equipment: Rubber or plastic apron.
Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands
after use, before smoking, or using the toilet.
Engineering Controls: Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
Exposure Guidelines: See Section 2.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance And Odor: Clear, yellow solution, slight odor. Solubility In Water: Complete
Boiling Point: >100°C Vapor Pressure:18 mm Hg @ 20°C Ph: 9.76
Specific Gravity: 1.23 g /ml Melting Point: Not applicable Freezing Point: N.E.
Date: 6/19/07 Rapid E-6 First Developer 2/4
MATERIAL SAFETY DATA SHEET
Evaporation Rate: N.E. Vapor Density: 0.6 Percent Volatile: 69.46
Molecular Weight: Not applicable Pounds Per Gallon: 10.22 VO.C. = 0
10. STABILITY AND REACTIVITY
Stability: Stable
Conditions To Avoid: None
Incompatibility: Strong acids, strong oxidizing agents.
Hazardous Decomposition Or By Products: May produce oxides of sulfur.
Hazardous Polymerization: Will Not Occur
11. TOXICOLOGICAL INFORMATION
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators.
Any disposal practice must be in compliance with federal, state, and local regulations. Do not
dump into sewers, ground, or any body of water.
14. TRANSPORT INFORMATION
DOT Class: NOT REGULATED
Hazard Class: NONE
UN No.: NOT APPLICABLE
Packing Group:
Guide No:
Ship Name:
15. REGULATORY INFORMATION
TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY.
SARA TITLE III: None
CALIF. PROP. 65: Product contains a mixture which includes trace amounts of Trisodium NTA.
The State of California’s Safe Drinking Water and Toxic Enforcement Act of 1986, or Proposition
65 requires the following information. This regulation does not address di minimus levels;
therefore, even trace amounts of the chemicals included on Proposition 65’s list of chemicals
known to the State of California to cause cancer or reproductive toxicity must be noted with the
“Safe Harbor� wording. WARNING: This product contains Trisodium NTA � known to the State of
California to cause cancer, birth defects or other reproductive harm.
CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS ABOVE THE
MINIMUM AMOUNT LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
SCAQMD Rule 443.1
Photochemically Reactive: No
Maximum Grams of VOC per Liter: 0 gm/L
Vapor Pressure: N.E. mmHg@ 20 °C
Date: 6/19/07 Rapid E-6 First Developer 3/4
MATERIAL SAFETY DATA SHEET
16. OTHER INFORMATION (HMIS)
Health: 2
Flammability: 0
Reactivity: 0
Protective: B
OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data
available to us and is believed to be accurate. However, no warranty is expressed or implied
regarding the accuracy of this data or the results to be obtained from the use thereof. We assume
no responsibility for the injuries from the use of the product described herein.
Date: 6/19/07 Rapid E-6 First Developer 4/4
MATERIAL SAFETY DATA SHEET
ARISTA
RAPID E-6 COLOR DEVELOPER PART A
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 COLOR DEVELOPER PART A
Product Number: 101262, 101272, 101292 Date Prepared: 04/23/2007
Customer Information Phone Number: 1-800-521-4042
CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS OHSA PEL ACGIH TLV Weight %
POTASSIUM HYDROXIDE 1310-58-3 N.E. 2mg/m³ CEILING 5-10
MONOSODIUM PHOSPHATE 7558-80-7 5 mg/m³* N.E. 5-10
PENTASODIUM
SALT MIXTURE 2235-43-0 N.E. N.E. 1-3
* Particulates not otherwise regulated respirable fraction.
3. HAZARDOUS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Eye Contact: Causes severe irritation and burns.
Inhalation: Mist may cause irritation to respiratory tract. In contact with strong acids or if heated
may liberate sulfur dioxide gas which is irritating. Some asthmatics or hypersensitive individuals
may experience difficult breathing.
Ingestion: Harmful if swallowed. May cause burns to the gastrointestinal tract. Some asthmatics
and sulfite-sensitive individuals may experience wheezing, chest tightness, stomach upset,
hives, diarrhea.
Skin Contact: Causes burns.
Signs And Symptoms Of Exposure: Eye and skin burns, abdominal pain, vomiting and diarrhea
upon ingestion., difficulty breathing.
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate
medical attention.
Inhalation: If symptomatic, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash
contaminated clothes before reuse. Get medical attention if irritation develops.
Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic
ailments, should consult a physician before using this product.
Supplemental Health Information: None of the components in this product is listed by IARC, NTP,
or OSHA as carcinogen.
Date: 6/19/07 Rapid E-6 Developer Part A 1/4
MATERIAL SAFETY DATA SHEET
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
Flash Point: Noncombustible Flash Point Method: Not applicable Auto ignition: Not applicable
LEL: Not applicable UEL: Not applicable
Extinguishing Media: Use agent appropriate for the surrounding area.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Fire or excessive heat may produce hazardous
decomposition products.
Unusual Fire And Explosion Hazards: None
Combustion Products: Carbon dioxide and carbon monoxide.
6. ACCIDENTAL RELEASE MEASURES
Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards
and safety precautions before proceeding with cleanup. Use appropriate personal protective
equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from
entering sewers, waterways or low areas. May require neutralization for pH > 12.5. Absorb spillage
in inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable
solid material and/or contaminated soil for disposal in an approved and permitted landfill.
Discharge to sewer requires approval of permitting authority. Working solution is able to be flushed
to sewer with large amounts of water upon approval.
7. HANDLING AND STORAGE
Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well-ventilated area. Keep
containers closed. Do not store with incompatible materials. Do not store or consume food, drink,
or tobacco where they may become contaminated with this material.
Other Precautions: All labeled precautions must be observed when handling, storing and
transporting empty containers due to product residues. Triple rinse before disposal.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: If use conditions do not maintain vapors or fumes below exposure limits,
use a NIOSH approved respirator with acid gas cartridges.
Ventilation: Provide exhaust ventilation sufficient to keep the airborne concentration of this product
below its exposure limits, typically 10 air changes per hour.
Protective Gloves: Rubber, or neoprene waterproof gloves are recommended.
Eye Protection: Safety glasses with side shields (or goggles) and a face shield.
Other Protective Clothing or Equipment: Rubber or plastic apron or other protective clothing
suitable for the exposure risk.
Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands
after use before smoking, or using the toilet.
Engineering Controls: Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
Exposure Guidelines: See Section 2.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance And Odor: Clear slight yellow, odorless liquid. Solubility In Water: Complete
Boiling Point: >100°C Vapor Pressure: 18 mm Hg @ 20°C Ph: 13.48 (1+1) = 13.14
Date: 6/19/07 Rapid E-6 Developer Part A 2/4
MATERIAL SAFETY DATA SHEET
Specific Gravity: 1.13 g /ml Melting Point: Not applicable
Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: 0.6 (air=1)
Percent Volatile: 81.93 Molecular Weight: Not applicable Pounds Per Gallon: 9.43
V.O.C. = 0
10. STABILITY AND REACTIVITY
Stability: Stable
Conditions To Avoid: High temperatures
Incompatibility: Strong Acids.
Hazardous Decomposition Or By Products: May produce oxides of sulfur and phosphorus
Hazardous Polymerization: Will Not Occur
11. TOXICOLOGICAL INFORMATION
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators.
Any disposal practice must be in compliance with federal, state, and local regulations. Do not
dump into sewers, ground, or any body of water.
14. TRANSPORT INFORMATION
Ship Name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (Contains Potassium Hydroxide)
Hazard Class: 8
UN No.: 3266
Packing Group: II
Guide No: 154
Limited Quantity Exception may apply to this product, for “inner packagings not over 1.0L (0.3 gal)
for liquids and 1.0 kg (2.2 lb) for solids�. 173.154 (b) (1). Each package must conform to the
packaging requirements of Subpart B of Part 173 and may not exceed 30 kg (66 lb) gross weight.
For further information consult the 49 CFR.
DOT Class: CONSUMER COMMODITY, ORM-D
Hazard Class: NOT APPLICABLE
UN No.: NOT APPLICABLE
Packing Group: NOT APPLICABLE
Guide No: NOT APPLICABLE
Ship Name: NOT APPLICABLE
15. REGULATORY INFORMATION
TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY.
SARA TITLE III: NONE
CALIF. PROP. 65: NONE
CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC,
NTP, OR OSHA AS A CARCINOGEN.
Date: 6/19/07 Rapid E-6 Developer Part A 3/4
MATERIAL SAFETY DATA SHEET
SCAQMD Rule 443.1
Photochemically Reactive: No
Maximum Grams of VOC per Liter: 0 gm/L
Vapor Pressure: N.E. mmHg@ 20 °C
16. OTHER INFORMATION (HMIS)
Health: 3
Flammability: 0
Reactivity: 0
Protective: C
OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data
available to us and is believed to be accurate. However, no warranty is expressed or implied
regarding the accuracy of this data or the results to be obtained from the use thereof. We assume
no responsibility for the injuries from the use of the product described herein.
Date: 6/19/07 Rapid E-6 Developer Part A 4/4
MATERIAL SAFETY DATA SHEET
ARISTA
RAPID E-6 COLOR DEVELOPER PART B
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 COLOR DEVELOPER PART B
Product Number: 101262, 101272, 101292 Date Prepared: 04/23/2007
Customer Information Phone Number: 1-800-521-4042
CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS OHSA PEL ACGIH TLV Weight %
4-(N-ETHYL-N-2-METHANESULFONYLAMINOETHYL)-2-METHYLPHENYLENEDIAMINE
SESQUISULFATE MOMOHYDRATE
25646-71-3 N.E. 1.0 mg/m³* 15-20
SODIUM METABISULFITE 7681-57-4 N.E 5 mg/m³ 1-3
*Manufacturer’s industrial hygiene guideline.
3. HAZARDOUS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Eye Contact: May cause irritation.
Inhalation: Harmful if inhaled. Mist may cause irritation to respiratory tract. In contact with strong
acids or if heated may liberate sulfur dioxide gas which is irritating. Some asthmatics or
hypersensitive individuals may experience difficult breathing.
Ingestion: Harmful if swallowed. Toxic. May cause burns to the gastrointestinal tract. Some
asthmatics and sulfite-sensitive individuals may experience wheezing, chest tightness, stomach
upset, hives, diarrhea.
Skin Contact: Prolonged contact will cause burns.
Signs And Symptoms Of Exposure: Eye and skin burns, abdominal pain, vomiting and diarrhea
upon ingestion and difficulty breathing.
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate
medical attention.
Inhalation: If symptomatic, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash
contaminated clothes before reuse. Get medical attention if irritation develops.
Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic
ailments, should consult a physician before using this product.
Supplemental Health Information: None of the components in this product is listed by IARC, NTP,
or OSHA as carcinogen.
Date: 6/19/07 Rapid E-6 Developer Part B 1/4
MATERIAL SAFETY DATA SHEET
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
Flash Point: Nonflammable Flash Point Method: Not applicable Auto ignition: Not applicable
LEL: Not applicable UEL: Not applicable
Extinguishing Media: Water spray, carbon dioxide, dry chemical, alcohol foam.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Fire or excessive heat may produce hazardous
decomposition products.
Unusual Fire And Explosion Hazards: None
Combustion Products: Carbon dioxide, carbon monoxide, oxides of sulfur, oxides of nitrogen.
6. ACCIDENTAL RELEASE MEASURES
Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards
and safety precautions before proceeding with cleanup. Use appropriate personal protective
equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from
entering sewers, waterways or low areas. May require neutralization if pH < 2.0. Absorb spillage in
inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable solid
material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to
sewer requires approval of permitting authority. Working solution is able to be flushed to sewer
with large amounts of water upon approval.
7. HANDLING AND STORAGE
Precautions To Be Taken In Handling And Storage: Avoid breathing mist or vapor. Store in a cool,
dry, well-ventilated area. Keep containers closed. Do not store with incompatible materials. Do not
store or consume food, drink, or tobacco where they may become contaminated with this material.
Other Precautions: All labeled precautions must be observed when handling, storing and
transporting empty containers due to product residues. Triple rinse before disposal.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: If use conditions do not maintain vapors or fumes below exposure limits,
use a NIOSH approved respirator with acid gas cartridges.
Ventilation: Provide exhaust ventilation sufficient to keep the airborne concentration of this product
below its exposure limits, typically 10 air changes per hour.
Protective Gloves: Rubber or neoprene waterproof gloves are recommended.
Eye Protection: Safety glasses with side shields (or goggles).
Other Protective Clothing or Equipment: Rubber or plastic apron or other protective clothing
suitable for the exposure risk.
Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands
after use, before smoking or using the toilet.
Engineering Controls: Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
Exposure Guidelines: See Section 2.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance And Odor: Light straw color, sulfur dioxide odor. Solubility In Water: Complete
Boiling Point: >100°C Vapor Pressure: 18 mm Hg @ 20°C Ph: 1.76
Date: 6/19/07 Rapid E-6 Developer Part B 2/4
MATERIAL SAFETY DATA SHEET
Specific Gravity: 1.09/ml Melting Point: Not applicable Freezing Point: N.E.
Evaporation Rate: N.E. Vapor Density: 0.6 (air=1) Percent Volatile: 78.13
Molecular Weight: Not applicable Pounds Per Gallon: 9.11
V.O.C. = 0
10. STABILITY AND REACTIVITY
Stability: Stable
Conditions To Avoid: None
Incompatibility: Strong bases and oxidizers.
Hazardous Decomposition Or By Products: May produce oxides of sulfur, carbon, and nitrogen.
Hazardous Polymerization: Will Not Occur
11. TOXICOLOGICAL INFORMATION
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators.
Any disposal practice must be in compliance with federal, state, and local regulations. Do not
dump into sewers, ground, or any body of water.
14. TRANSPORT INFORMATION
Ship Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Contains CD-3)
Hazard Class: 8
UN No.: 3265
Packing Group: II
Guide No: 153
Limited Quantity Exception may apply to this product, for “inner packagings not over 1.0L (0.3 gal)
for liquids and 1.0 kg (2.2 lb) for solids�. 173.154 (b) (1). Each package must conform to the
packaging requirements of Subpart B of Part 173 and may not exceed 30 kg (66 lb) gross weight.
For further information consult the 49 CFR.
DOT Class: CONSUMER COMMODITY, ORM-D
Hazard Class: NOT APPLICABLE
UN No.: NOT APPLICABLE
Packing Group: NOT APPLICABLE
Guide No: NOT APPLICABLE
Ship Name: NOT APPLICABLE
15. REGULATORY INFORMATION
TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY.
SARA TITLE III: NONE
CALIF. PROP. 65: NONE
CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC,
NTP, OR OSHA AS A CARCINOGEN.
Date: 6/19/07 Rapid E-6 Developer Part B 3/4
MATERIAL SAFETY DATA SHEET
SCAQMD Rule 443.1
Photochemically Reactive: No
Maximum Grams of VOC per Liter: 0 gm/L
Vapor Pressure: N.E. mmHg@ 20 °C
16. OTHER INFORMATION (HMIS)
Health: 2
Flammability: 1
Reactivity: 0
Protective: B
OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data
available to us and is believed to be accurate. However, no warranty is expressed or implied
regarding the accuracy of this data or the results to be obtained from the use thereof. We assume
no responsibility for the injuries from the use of the product described herein.
Date: 6/19/07 Rapid E-6 Developer Part B 4/4
MATERIAL SAFETY DATA SHEET
ARISTA
RAPID E-6 BLIX PART A
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 BLIX PART A
Product Number: 101262, 101272, 101292 Date Prepared: 04/23/2007
Customer Information Phone Number: 1-800-521-4042
CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS OHSA PEL ACGIH TLV Weight %
AMMONIUM THIOSULFATE 7783-18-8 N.E. N.E. 65-75
SODIUM SULFITE 7757-83-7 N.E. N.E. 1-3
3. HAZARDOUS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Eye Contact: Causes irritation.
Inhalation: May cause irritation mucous membranes and to upper respiratory tract.
Ingestion: May cause irritation to gastrointestinal track. Some asthmatics or sulfite-sensitive
persons may experience wheezing, chest tightness, stomach upset, hives, faintness,
weakness, and diarrhea.
Skin Contact: May cause irritation or reddening.
Signs And Symptoms Of Exposure: Eye irritation, respiratory irritation, dermatitis, difficulty
breathing, abdominal pain, skin irritation, mucus membrane irritation, coughing, nausea,
diarrhea.
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate
medical attention.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
Skin Contact: Immediately wash skin with plenty of soap. Remove contaminated clothing and
shoes. Wash contaminated clothing before reuse.
Aggravated Medical Conditions: Asthmatics or hypersensitive individuals may experience difficult
breathing.
Supplemental Health Information: None of the components in this product is listed by IARC, NTP,
or OSHA as carcinogen.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
Flash Point: Nonflammable Flash Point Method: Not applicable Auto-ignition: Not applicable
LEL: Not applicable UEL: Not applicable
Extinguishing Media: Any applicable to the primary cause of the fire. Flood with water.
Date: 6/19/07 Rapid E-6 Blix Part A 1/3
MATERIAL SAFETY DATA SHEET
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
Unusual Fire And Explosion Hazards: None known.
Combustion Products: Carbon dioxide, carbon monoxide, oxides of sulfur and nitrogen.
6. ACCIDENTAL RELEASE MEASURES
Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards
and safety precautions before proceeding with cleanup. Use appropriate personal protective
equipment during cleanup. For small amount less than one gallon flush to sewer with large
amounts of water. For larger spills, dike the spill. Prevent liquid from entering sewers, waterways
or low areas. Soak up with sawdust, sand, oil dry, or other absorbent material. Absorb spillage in
inert material. Remove non-usable solid material and/or contaminated soil for disposal. Discharge
to sewer may require approval of local authorities. Contaminated surfaces may be cleaned using
water.
7. HANDLING AND STORAGE
Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well ventilated area. Keep
containers closed. Do not store with incompatible materials. Do not store or consume food, drink,
or tobacco where they may become contaminated with this material.
Other Precautions: All labeled precautions must be observed when handling, storing and
transporting empty containers due to product residues. Do not reuse containers. Triple rinse before
disposal.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: When this product is used in the intended way, no respiratory protection is
anticipated to be necessary.
Ventilation: Avoid breathing vapors or mist. Local exhaust ventilation is recommended. Ventilation
must be adequate to keep hazardous ingredients below their exposure limits.
Protective Gloves: Impervious gloves and aprons recommended.
Eye Protection: Chemical safety glasses with side shields (or goggles).
Other Protective Clothing or Equipment: Rubber or plastic apron.
Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands
after use, before smoking or using the toilet.
Engineering Controls: Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
Exposure Guidelines: See Section 2.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance And Odor: Clear, colorless solution; ammonia odor.
Solubility In Water: Complete Boiling Point: 100° C Specific Gravity: 1.24
Vapor Pressure: 18m Hg @ 20° C Melting Point: Not applicable Freezing Point: N.E.
Evaporation Rate: N.E. Vapor Density: N.E. Percent Volatile: 56.56
Ph: 7.38 Molecular Weight: Not applicable
Pounds Per Gallon: 10.33 V.O.C. = 0
10. STABILITY AND REACTIVITY
Stability: Stable
Date: 6/19/07 Rapid E-6 Blix Part A 2/3
MATERIAL SAFETY DATA SHEET
Conditions To Avoid: Strong acids and alkali.
Incompatibility Strong acids will liberate sulfur dioxide; strong bases of sodium hydroxide will
liberate ammonia fumes.
Hazardous Decomposition Or By Products: Sulfur dioxide, ammonia.
Hazardous Polymerization: Will Not Occur
11. TOXICOLOGICAL INFORMATION
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
The preferred options for disposal are to send to licensed reclaimers. Any disposal practice must
be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or
any body of water.
14. TRANSPORT INFORMATION
DOT Class: NOT REGULATED
Hazard Class: NONE
UN No: NOT APPLICABLE
Packing Group:
Guide No:
Ship Name:
15. REGULATORY INFORMATION
TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY.
SARA TITLE III: NONE
CALIF. PROP. 65: NONE
CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC,
NTP, OR OSHA AS A CARCINOGEN.
SCAQMD Rule 443.1
Photochemically Reactive: No
Maximum Grams of VOC per Liter: 0 gm/L
Vapor Pressure: N.E. mmHg@ 20 °C
16. OTHER INFORMATION (HMIS)
Health: 1
Flammability: 0
Reactivity: 0
Protective: B
OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data
available to us and is believed to be accurate. However, no warranty is expressed or implied
regarding the accuracy of this data or the results to be obtained from the use thereof. We assume
no responsibility for the injuries from the use of the product described herein.
Date: 6/19/07 Rapid E-6 Blix Part A 3/3
MATERIAL SAFETY DATA SHEET
ARISTA
RAPID E-6 BLIX PART B
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 BLIX PART B
Product Number: 101262, 101272, 101292 Date Prepared: 04/23/2007
Customer Information Phone Number: 1-800-521-4042
CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS OHSA PEL ACGIH TLV Weight %
FERRIC AMMONIUM EDTA 21265-50-9 50 ppm 25 ppm 75-85
3. HAZARDOUS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Eye Contact: May cause transient irritation.
Inhalation: Low hazard for recommended handling.
Ingestion: Expected to be low hazard if swallowed. May cause irritation of the mouth, throat, and
stomach.
Skin Contact: May cause redness and irritation.
Signs And Symptoms Of Exposure: Redness of eyes and skin.
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate
medical attention.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash
contaminated clothes before reuse. Get medical attention if irritation develops.
Aggravated Medical Conditions: Dermatitis, asthma, and sulfite sensitiveness for working solution.
Supplemental Health Information: None of the components in this product is listed by IARC, NTP,
or OSHA as a carcinogen.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
Flash Point: Nonflammable Flash Point Method: Not applicable Auto ignition: Not applicable
LEL: Not applicable UEL: Not applicable
Extinguishing Media: Use agent appropriate for surrounding fire.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
Unusual Fire And Explosion Hazards: Not considered a fire hazard. When involved in a fire, does
not contribute any unusual hazards.
Combustion Products: Oxides of carbon and nitrogen are produced by the combustion of this
product.
Date: 6/19/07 Rapid E-6 Blix Part B 1/3
MATERIAL SAFETY DATA SHEET
6. ACCIDENTAL RELEASE MEASURES
Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards
and safety precautions before proceeding with cleanup. Use appropriate personal protective
equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from
entering sewers, waterways or low areas. Absorb spillage in inert material. Soak up with sawdust,
sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for
disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting
authority. Working solution should be able to be flushed to sewer with large amounts of water.
Contaminated surfaces should be cleaned using water.
7. HANDLING AND STORAGE
Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well ventilated area. Keep
containers closed. Do not store with incompatible materials. Do not store or consume food, drink,
or tobacco where they may become contaminated with this material.
Other Precautions: All labeled precautions must be observed when handling, storing and
transporting empty containers due to product residues. Do not reuse containers. Triple rinse before
disposal.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: When this product is used in the intended way, no respiratory protection is
anticipated to be necessary. If engineering controls do not maintain airborne concentrations
below recommended exposure limits, an approved respirator should be worn of organic vapor
type.
Ventilation: Good ventilation of 10 room volumes per hour. Ventilation rates should match
conditions of use.
Protective Gloves: Latex, rubber, or neoprene waterproof gloves are recommended.
Eye Protection: Safety glasses with side shields (or goggles).
Other Protective Clothing or Equipment: Rubber or plastic apron.
Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands
after use, before smoking or using the toilet.
Engineering Controls: Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
Exposure: See Section 2.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance And Odor: Reddish brown solution; ammonia odor Solubility In Water: Complete
Boiling Point: > 100 ºC Vapor Pressure: 18m Hg @ 20ºC Specific Gravity: 1.25
Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E.
Vapor Density: N.E. Percent Volatile: 59.26 Ph: 7.34
Molecular Weight: Not applicable Pounds Per Gallon: 10.43
V.O.C. is 0.
10. STABILITY AND REACTIVITY
Stability: Stable
Conditions To Avoid: Metals such as aluminum, copper, copper alloys, nickel, and zinc. Aqueous
solution in contact with aluminum evolves hydrogen.
Date: 6/19/07 Rapid E-6 Blix Part B 2/3
MATERIAL SAFETY DATA SHEET
Incompatibility: Strong oxidizers, alkalis, acids.
Hazardous Decomposition Or By Products: May produce oxides of nitrogen, carbon dioxide,
carbon monoxide, and ammonia.
Hazardous Polymerization: Will Not Occur
Conditions To Avoid: None
11. TOXICOLOGICAL INFORMATION
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
Discharge, treatment or disposal may be subject to Federal, State (provincial in Canada) or local
laws.
14. TRANSPORT INFORMATION
DOT Class: NOT REGULATED
Hazard Class: NONE
UN No.: NOT APPLICABLE
Packing Group:
Guide No:
Ship Name:
15. REGULATORY INFORMATION
TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY.
SARA TITLE III: NONE
CALIF. PROP. 65: NONE
CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC,
NTP, OR OSHA AS A CARCINOGEN.
SCAQMD Rule 443.1
Photochemically Reactive: No
Maximum Grams of VOC per Liter: 0 gm/L
Vapor Pressure: N.E. mmHg@ 20 °C
16. OTHER INFORMATION (HMIS)
Health: 1
Flammability: 0
Reactivity: 0
Protective: B
OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data
available to us and is believed to be accurate. However, no warranty is expressed or implied
regarding the accuracy of this data or the results to be obtained from the use thereof. We assume
no responsibility for injuries from the use of the product described herein.
Date: 6/19/07 Rapid E-6 Blix Part B 3/3
MATERIAL SAFETY DATA SHEET
ARISTA
RAPID E-6 BLIX PART C
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer: Photo Systems, Inc. Product Name: RAPID E-6 BLIX PART C
Product Number: 101262, 101272, 101292 Date Prepared: 04/23/2007
Customer Information Phone Number: 1-800-521-4042
CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS OHSA PEL ACGIH TLV Weight %
SODIUM METABISULFITE 7681-57-4 N.E. 5 mg/m³ 15-20
ACETIC ACID 64-19-7 25 mg/m³ TWA = 25 mg/m³ <2
STEL = 37 mg/m³
POTENTIAL HEALTH EFFECTS
Eye Contact: May cause temporary irritation.
Inhalation: Expected to be a low hazard for usual industrial or commercial handling by trained
personnel. In contact with strong acids or if heated, sulfites may liberate sulfur dioxide gas.
Sulfur dioxide gas is irritating to the respiratory tract.
Ingestion: May be harmful if swallowed. May cause irritation to gastrointestinal tract. Some
asthmatics or sulfite-sensitive persons may experience wheezing, chest tightness, stomach
upset, hives, faintness, weakness, and diarrhea.
Skin Contact: This material has a low potential to cause allergic skin reactions; however, cases of
human skin sensitization have been reported.
Signs And Symptoms Of Exposure: Eye irritation, respiratory irritation, dermatitis, difficulty
breathing, wheezing, chest tightness, stomach upset, hives, faintness, weakness, and diarrhea.
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate
medical attention.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
Skin Contact: Immediately wash skin with plenty of soap. Remove contaminated clothing and
shoes. Wash contaminated clothing before reuse.
Aggravated Medical Conditions: Asthmatics or hypersensitive individuals may experience difficult
breathing.
Supplemental Health Information: None of the components in this product is listed by IARC, NTP,
or OSHA as a carcinogen.
5. FIRE FIGHTING MEASURES
Flash Point: Nonflammable Flash Point Method: Not applicable Auto-ignition: Not applicable
LEL: Not applicable UEL: Not applicable
Extinguishing Media: Any applicable to the primary cause of the fire. Flood with water.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Fire or excessive heat may produce hazardous
decomposition products.
Date: 6/19/07 Rapid E-6 Blix Part C 1/3
MATERIAL SAFETY DATA SHEET
Unusual Fire And Explosion Hazards: Sulfur dioxide can be emitted under high temperatures.
Combustion Products: Carbon dioxide, carbon monoxide, oxides of sulfur.
6. ACCIDENTAL RELEASE MEASURES
Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards
and safety precautions before proceeding with cleanup. Use appropriate personal protective
equipment during cleanup. For small amount less than one gallon flush to sewer with large
amounts of water if permitted. For larger spills, dike the spill. Prevent liquid from entering sewers,
waterways or low areas. Soak up with sawdust, sand, oil dry, or other absorbent material. Absorb
spillage in inert material. Remove non-usable solid material and/or contaminated soil for disposal.
Discharge to sewer may require approval of local authorities. Contaminated surfaces may be
cleaned using water.
7. HANDLING AND STORAGE
Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well ventilated area. Keep
containers closed. Do not store with incompatible materials. Keep from contact with oxidizing
materials, highly oxygenated or halogenated solvents, and organic compounds containing
reducible functional groups. Keep away from combustible material. Do not store or consume food,
drink, or tobacco where they may become contaminated with this material. Remove and wash
contaminated clothing promptly.
Other Precautions: All labeled precautions must be observed when handling, storing and
transporting empty containers due to product residues. Do not reuse containers. Triple rinse before
disposal.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: None should be needed. A respirator should be worn if hazardous
decomposition products are likely to be or have been released. Respirator type: Acid gas.
Ventilation: Avoid breathing vapors or mist. Local exhaust ventilation (typically 10 air changes per
hour) is recommended. Ventilation must be adequate to keep hazardous ingredients below their
exposure limits.
Protective Gloves: Impervious gloves are recommended.
Eye Protection: Chemical safety glasses with side shields (or goggles).
Other Protective Clothing or Equipment: Rubber or plastic apron.
Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands
after use, before smoking or using the toilet.
Engineering Controls: Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
Exposure Guidelines: See Section 2.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance And Odor: Clear, colorless liquid with a strong vinegar odor.
Solubility In Water: Complete Boiling Point: 100 ºC Vapor Pressure: N.E.
Specific Gravity: 1.14 Melting Point: Not applicable Freezing Point: N.E.
Evaporation Rate: N.E. Vapor Density: N.E. Percent Volatile: 82.13
Ph: 3.46 Molecular Weight: Not applicable Pounds Per Gallon: 9.50
V.O.C. 12.27 g/L or 1.08%, or 0.17 lb. /gal.
Date: 6/19/07 Rapid E-6 Blix Part C 2/3
MATERIAL SAFETY DATA SHEET
10. STABILITY AND REACTIVITY
Stability: Stable
Conditions To Avoid: Strong bases.
Incompatibility Strong bases will liberate sulfur dioxide.
Hazardous Decomposition Or By Products: Sulfur dioxide
Hazardous Polymerization: Will Not Occur
11. TOXICOLOGICAL INFORMATION
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
The preferred options for disposal are to send to licensed reclaimers. Any disposal practice must
be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or
any body of water.
14. TRANSPORT INFORMATION
DOT Class: NOT REGULATED
Hazard Class: NONE
UN No: NOT APPLICABLE
Packing Group:
Guide No:
Ship Name:
15. REGULATORY INFORMATION
TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY.
SARA TITLE III: NONE
CALIF. PROP. 65: NONE
CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC,
NTP, OR OSHA AS A CARCINOGEN.
SCAQMD Rule 443.1
Photochemically Reactive: No
Maximum Grams of VOC per Liter: 12.27 gm/L
Vapor Pressure: N.E. mmHg@ 20 °C
16. OTHER INFORMATION (HMIS)
Health: 2
Flammability: 0
Reactivity: 0
Protective: C
OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data
available to us and is believed to be accurate. However, no warranty is expressed or implied
regarding the accuracy of this data or the results to be obtained from the use thereof. We assume
no responsibility for the injuries from the use of the product described herein.
Date: 6/19/07 Rapid E-6 Blix Part C 3/3
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