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MSDS Material Safety Data Sheet
CAS

7775-14-6
7775-27-1

File Name: fujifilm_co_uk---957795_A.asp
                                                          According to directive 2001/58/EC


MATERIAL SAFETY DATA SHEET
Date:
Date : 24/10/2004
Catalogue N 掳: 957795


1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
1.1. Identification of the substance or preparation
UNICLEANER A

1.2. Use of the substance/preparation
Photographic developer
1.3. Company/undertaking identification
FUJI HUNT PHOTOGRAPHIC CHEMICALS NV.
EUROPARK NOORD 21-22
9100 SINT-NIKLAAS
BELGIUM
TEL: +32 (0)3 760 02 00
FAX: +32 (0)3 776 91 22
1.4. Emergency telephone
+32 (0)3 760 02 00


2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical characterisation: powder
Components contributing to hazard:



w/w% CAS N掳 EINECS N掳 Components
Symb. R-phrases
50-70 7775-14-6 231-890-0 SODIUM BISULPHATE
. . . Xn R:7-22-31
30-50 7775-27-1 231-892-1 SODIUM PERSULPHATE
. . O Xn R:8-22-36/37/38-42/43
.




3. HAZARDS IDENTIFICATION
Most important hazards :
Harmful if swallowed.
May cause sensitization by inhalation and skin contact.


4. FIRST AID MEASURES
Eye contact
Irrigate with flowing water immediately and continuously for 15 minutes.
Consult medical personnel.
Skin contact
Immediately flush with plenty of water for at least 15 minutes while
removing contaminated clothing
Ingestion
Consult a physician or transport to emergency facility immediately.
Inhalation
Remove to fresh air. Consult a physician.
Further information
Overexposure may lead to allergic skin reactions with sensitized people. In
this case, seek medical advice.
5. FIRE -FIGHTING MEASURES
FIRE-
5.1. Suitable extinguishing media:
Water.
Water fog, carbon dioxide, foam, dry chemicals.
5.2. Extinguishing media to avoid:




957795 - UNICLEANER A 1
None under normal conditions.
5.3. Further information:
Keep containers cool by spraying with water.


6. ACCIDENTAL RELEASE MEASURES
- Wear adequate personal protective equipment, see section 8 ( exposure
control / personal protection ).
- Spills should be contained by and carried with suitable absorbent
material and removed from disposal.
- Dispose of according to local and national regulations.
- Prevent from entering into soil, waterways and groundwater.


7. HANDLING AND STORAGE
7.1. Handling
Avoid eye and skin contact. Wash hands and exposed skin before eating,
drinking or smoking and after work. Use only in a well ventilated area.
Ingestion, exposure to skin and eyes and inhalation of any generated
vapours should be avoided. Wear suitable protective clothing, gloves and
eye/face protection. Do not consume or store food in the working area.
7.2. Storage
Keep containers tightly closed. Store in a well ventilated, cool, dry area.
Storage temperature should be higher than +5掳C.


8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Exposure limit values (INGREDIENTS INFORMATION)
SODIUM BISULPHATE
MAK-value( TRGS 900 ) = NAv
TLV-TWA = NAv
SODIUM PERSULPHATE
MAK-value( TRGS 900 ) = NAv
TLV-TWA = 0,1 mg/m鲁
8.2. Exposure controls
Respiratory protection: no respiratory protection needed under normal
conditions. Good ventilation should be sufficient.
Hand protection: use chemical resistant gloves. In case of prolonged
immersion or frequently repeated contact use gloves made of the materials :
nitrile rubber (thickness >= 0,38 mm, breakthrough time > 480 min)
neoprene (thickness >= 0,65 mm, breakthrough time > 240 min).
butyl rubber (thickness >= 0,36 mm, breakthrough time > 480 min)
For intermittent splash protection corresponding gloves with breakthrough
time > 60 min can be used.
Avoid gloves made of : natural rubber.
Eye protection: use chemical safety goggles. Eye wash fountain should be
located in immediate work area.
Other: appropriate protective clothing.


9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Solid
Flash point 掳C : NA
Density (20掳C) Kg/L : 0.999999
Solubility in water (25掳C) : Completely
pH value (25掳C) : 0.99999



10.
10. STABILITY AND REACTIVITY
10.1. Conditions to avoid
The product is stable under normal storage conditions.
10.2. Materials to avoid
Keep away from oxidising material(s).
10.3. Hazardous decomposition products
Formation of S02 is possible.


11. TOXICOLOGICAL INFORMATION
11.
Acute toxicity (INGREDIENTS INFORMATION)
SODIUM BISULPHATE
LD50 (Oral Rat) = 2490 mg/kg
SODIUM PERSULPHATE
LD50 (Oral Rat) = 930 mg/kg



957795 - UNICLEANER A 2
Skin contact
May cause sensitization by skin contact.
Ingestion
Harmful if swallowed.
Inhalation
May cause sensitization by inhalation.


12. ECOLOGICAL INFORMATION
12.
Ecotoxicity (INGREDIENTS INFORMATION)
SODIUM BISULPHATE
LC50 (Fish, 96 hours) = NAv
SODIUM PERSULPHATE
LC50 (Fish, 96 hours) = NAv


13.
13. DISPOSAL CONSIDERATIONS
Dispose of according to local and national regulations. Containers must be
disposed of in accordance with local regulations.
EWC: 09 01 01 Water-based developer and activator solutions


14. TRANSPORT INFORMATION
14.
UN N掳 : 1505 PSN : SODIUM PERSULPHATE
ADR/RID Class : 5.1 Item :18C TREMCARD :5.1505-001
Pack.gr.: III
IMDG/ADNR Class : 5.1 EmS :F-A Mar.Poll. :N
Pack.gr.: III
ICAO/IATA Class : 5.1 Pass. < :25KG Instr. :516
Pack.gr.: III Cargo < :100KG Instr. :518


15.
15. REGULATORY INFORMATION
EU Classification and User Label Information:
Contains : SODIUM PERSULPHATE
Symbol(s) : Xn
R(isk) phrase(s) :
R22 : Harmful if swallowed.
R42/43 : May cause sensitization by inhalation and skin contact.
S(afety) phrase(s) :
S23 : Do not breathe vapour.
S24 : Avoid contact with skin.
S37 : Wear suitable gloves.
S46 : If swallowed, seek medical advice immediately and show this container or
label.
Other information :
WGK: 1


16. OTHER INFORMATION
16.
The use of the preparation is restricted to professional users!
The above mentioned data correspond to our present state of knowledge and
experience. The safety data sheet serves as description of the products in
regard to necessary safety measures. The indications have not the meaning
of guarantees on properties.
---------------------------------------------------------------------------
Date of issue: 01.04.2004 Supersedes edition of -
---------------------------------------------------------------------------
NAv : Not available NA : Not applicable
RISK PHRASES MENTIONED IN PARAGRAPH 2:
R22 : Harmful if swallowed.
R31 : Contact with acids liberates toxic gas.
R36/37/38: Irritating to eyes, respiratory system and skin.
R42/43 : May cause sensitization by inhalation and skin contact.
R7 : May cause fire.
R8 : Contact with combustible material may cause fire.




List of distributors :



957795 - UNICLEANER A 3
FUJI HUNT Photographic FUJI HUNT Photographic FUJI HUNT Photographic
Chemicals Ltd . Chemicals GmbH .
Chemicals SARL .
Orchard Court V 12 Rue Des Chardonnerets Opelring 5-9
Binley Business Park ZAC Paris Nord II 64572 B眉ttelborn 2
Coventry CV3 2TQ DEUTSCHLAND
BP 60343
UNITED KINGDOM 95941 Roissy CDG Tremblay en Tel: +49 6 15 27 12 20
Tel: +44 2 476 45 55 75 France Fax: +49 6 15 27 12 229
Fax: +44 2 476 54 71 07 FRANCE
Tel: +33 1 48 63 72 57
Fax: +33 1 49 38 00 76
FUJI HUNT Photographic FUJI HUNT Photographic FUJI HUNT Photographic
Chemicals Srl .
Chemicals AB .
Chemicals N .V.
Europark Noord 21-22 Via Torri Bianche 3
Bergk盲llav盲gen
9100 Sint-Niklaas P.O. BOX 321 Edificio Larice
BELGIUM 19230 Sollentuna 20059 Vimercate (MI)
Tel: +32 3 760 02 00 SVERIGE ITALIA
Fax:+32 3 776 91 22 Tel: +46 8 59 47 09 50 Tel: +39 039 69 90 41
Fax: +46 8 59 47 09 59 Fax: +39 039 68 58 486




957795 - UNICLEANER A 4

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