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MSDS Material Safety Data Sheet
CAS

23564-05-8

File Name: clearychemical_com---4150M.asp
                      M AT E R I A L S A F E T Y D ATA S H E E T

PRODUCT IDENTIFICATION ACCIDENTAL RELEASE
MEASURES
Product Name: 3336 WP
Steps to be taken in case material is released or
Cleary Product Code: 4151 (8 oz),
spilled: Sweep up and dispose of in compliance with
4152 (2 oz)
all federal, state and local laws.
E.P.A. Registration Number: 1001-63
Chemical Name: Dimethyl-4-4麓-o-phenylenebis-3- HANDLING AND STORAGE
thioallophanate
Precautions to be taken in handling and storing:
Synonyms: Thiophanate methyl Store in original sealed containers in a cool dry area not
accessible to children or unauthorized persons.
INGREDIENT INFORMATION
EXPOSURE CONTROLS/
Active Ingredient (CAS #) Percent
PERSONAL PROTECTION
Dimethyl-4-4麓-o-phenylenebis-3-
thioallophanate (23564-05-8) 50.0% Protective Clothing: Long sleeve shirt,pants,or cov-
Inert Ingredients 50.0% eralls, water resistant boots.
Exposure Limits Eye Protection: Chemical goggles or safety glasses
TLV鈥檚 and PEL鈥檚 have not been established for with side shields recommended.
listed materials. Ventilation: Use product outdoors or in a well venti-
lated area.
HEALTH HAZARD DATA
Respiratory Protection: Dust mask or OSHA ap-
Inhalation: May cause irritation, coughing. proved respirator in confined spaces.
Eye Contact: May cause transient irritation. Other: Protective barrier cream may be applied on ex-
Skin Contact: Non-irritating, not a known sensitizer. posed skin areas.
Chronic Effects Of Overexposure: Irritation of eyes,
PHYSICAL AND CHEMICAL
nose, and throat, dermatitis, headache and nausea.
PROPERTIES
EMERGENCY AND FIRST AID Boiling Point: N/A
PROCEDURES Melting Point: 181.5-182.5掳C
Ingestion: Drink 1-2 glasses of water, and induce Freezing Point: N/A
vomiting as soon as possible by tickling the back of the
Bulk Density: 16-19 lbs./cu. ft.
throat with the finger or similar blunt object. Seek
Vapor Pressure (@ 25掳C): N/A
medical attention immediately. Do not induce vomit-
ing of an unconscious person. % Volatile: Zero
Skin Contact: Wash exposed area of skin with soap Evaporation Rate: N/A
and warm water. Contaminated clothing including
Solubility In Water: Insoluble (dispersible)
footwear should be thoroughly cleaned before reuse.
Appearance And Odor: Fine, light tan powder, faint
Eye Contact: Flush eyes with plenty of water for at
sulfur odor.
least 15 minutes.Seek medical attention immediately.
REACTIVITY HAZARD DATA
Inhalation: Remove to fresh air.
Stability: Stable
FIRE & EXPLOSION DATE
Conditions To Avoid: N/A
Flash Point (Method): N/A
Incompatibility: Highly alkaline materials,oxidizing
Flammable Limits (vol % in air): N/A
agents, lime sulfur, bordeux mixture, copper com-
Autoignition Temperature: N/A pounds.
Extinguishing Media: Carbon dioxide, foam, water. Hazardous Polymerization: N/A
CLEARY CHEMICAL CORPORATION
Special Fire Fighting Procedures: Self-contained Hazardous Decomposition Products: Thermal de- 178 RIDGE ROAD
breathing apparatus. composition generates oxides of nitrogen, sulfur, and DAYTON, NJ 08810-1501
carbon.
Unusual Fire and Explosion Hazards: None

EMERGENCY PHONE NUMBERS:
M-F 9AM-5PM EDT
800-524-1662 鈥? 732-329-8399
24 Hour CHEMTREC
800-424-9300
M AT E R I A L S A F E T Y D ATA S H E E T

TOXICOLOGICAL TRANSPORTATION
INFORMATION INFORMATION
TOXICITY DATA: LD50 DOT Shipping Description: Fungicide, Agricultural,
Solid, N.O.I.
Oral (acute): > 7500 mg/kg males, 6640 mg/kg fe-
males (rat) DOT Hazard Classification: Not DOT regulated
Dermal (acute): > 10,000 mg/kg (rabbit) UN Identification Number: N/A
Inhalation (acute): > 20.8 mg/L (LC50 rat 4 hour) OSHA Hazard Classification: N/A
Chronic (oral): No oncogenicity, no observed effect Reportable Quantity: N/A
level, 160 ppm in diet for two years (rat) and 50 Hazardous Substance: N/A
mg/kg/day in single dose for two years (dog).
DOT Label Requirements: N/A
Subchronic (oral): No observable effect level, 1,600
ppm in diet for 180 days (rats and mice). REGULATORY INFORMATION
Neurotoxicity: No delayed neurotoxicity or EPA SARA TITLE III DATA: Positive rating for acute
cholinesterase inhibition. hazard.
Oncogenicity: No oncogenicity to mice consuming SECTION 302 Substances: N/A
diets containing levels as high as 640 ppm over a two RCRA Waste Number: N/A
year period.
SECTION 311/312 Hazardous Categories: N/A
Teratogenicity: No teratology to rats or mice dosed Immediate Health: No
throughout pregnancy with levels as high as 1,000 Delayed Health: No
mg/kg/day. Fire: No
Reactive: No
Reproductive Toxicity: No effect on spermatogene-
Sudden Pressure: No
sis, testosterone assimilation. Three generation study
showed no evidence of effects on fertility,fecundity or SECTION 313 TOXIC CHEMICALS: N/A
offspring. CERCLA RQ: N/A
CALIFORNIA PROP 65: Developmental Toxin
Mutagenicity: Ames, Mammalian Somatic,
This product does contain the following
Cytogenicity, Dominant Lethal, DNA Damage/Repair,
chemical(s), as indicated below, currently on
all test negative.
the California List of Developmental Toxins.
ECOLOGY DATA Thiophanate methyl
This pesticide is toxic to fish. Do not apply directly to NFPA RATINGS
water, or to areas where surface water is present, or to Flammability: 0
intertidal areas below the mean high water mark. Do Reactivity: No
not contaminate water by disposal of equipment wash- Health: 1
waters. Do not apply, allow to drift, or drain or flush
equipment onto non-target areas.

DISPOSAL
Waste Disposal Methods: Improper disposal of ex-
cess pesticide,spray mixture or rinsate is a violation of
federal law. If these wastes cannot be disposed of by
intended use according to label instructions,contact the
appropriate agency in your state or the nearest EPA
Regional Office for guidance.



CLEARY CHEMICAL CORPORATION
178 RIDGE ROAD
DAYTON, NJ 08810-1501

EMERGENCY PHONE NUMBERS: Preparation and distribution of this Material Safety Data Sheet done by Cleary Chemical Corporation, 178 Ridge Road, Dayton, New Jersey 08810, pursuant
to the OSHA Hazard Communication Standard (29 CFR 1910.1200).The information contained herein is based on available data. However, no warranty is
M-F 9AM-5PM EDT expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof, and you should make your investigation to de-
800-524-1662 鈥? 732-329-8399 termine safety for the use you contemplated. Cleary Chemical Corporation assumes no responsibility or liability for any incidental or consequential dam-
ages whether related to personal injury or property damage, to vendors, users or third parties, caused by the material and Cleary Chemical Corporation鈥檚
24 Hour CHEMTREC responsibility is limited to replacement of, or repayment of, the purchase price for the materials with respect to which any damages are claimed. All ven-
800-424-9300 dors or users assume all risk associated with the use of the material(s). 3/00

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