MATERIAL SAFETY DATA SHEET
3336 PLUSTM Page 1 of 3
Please read the entire document. This Material Safety Data Sheet contains important environmental,
health and toxicology information for your employees, and anyone who will use, transport, store,
dispose of or handle this product. Please make sure this information is given to them. It also contains
information to help you meet community right-to-know/emergency response reporting requirements
under SARA Title III and many other laws. If you resell this product, this MSDS must be given to the
buyer or the information contained herein must be incorporated in your MSDS.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3336 PLUS
EPA REGISTRATION NUMBER(S): 1001-78
CHEMICAL NAME: Dimethyl-4,4' - o-phenylenebis-3-thioallophanate (23564-05-8)
SYNONYM: Thiophanate-methyl
GENERAL USE: Turf and ornamental fungicide
EMERGENCY TELEPHONE NUMBERS
COMPANY
CLEARY CHEMICAL CORP. PROSAR:
Cleary Chemical M-F 9-5 EST (800) 324-7598
178 Ridge Road, Suite A (800) 524-1662 OR CHEMTREC 24 HOUR:
Dayton, New Jersey 08810 (732) 329-8399 (800) 424-9300
SECTION 2: INFORMATION ON INGREDIENTS
Active Ingredient(s)/ % by Wt. CAS# ACGIH OSHA
Hazardous Inert Ingredient(s) TLV PEL
Thiophanate-methyl 19.8 23564-05-8 NL NA
SECTION 3: HEALTH HAZARD INFORMATION
Acute Health Hazards
Ingestion: May cause irritation.
Eye Contact: May cause irritation.
Skin Contact: May cause irritation.
Inhalation: N/A
Chronic Effects of Overexposure: Irritation of eyes, nose throat, dermatitis, headache and nausea.
SECTION 4: FIRST AID MEASURES
Ingestion: Call poison control center or doctor for treatment advise. Do not induce vomiting unless told
to do so by the poison control center or doctor. Have person sip a glass of water if able to swallow. Do
not give anything by mouth to an unconscious person.
Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact
lenses, if present, after the first 5 minutes, then continue rinsing eye. Call poison control center or doctor
for further treatment advice.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. Call a poison control center or doctor for further treatment advice.
First Aid Measures continued on next page.
Effective Date: 2.1.05
NDA = No Data Available NA = Not Applicable
3336 PLUSTM Page 2 of 3
SECTION 4: FIRST AID MEASURES (continued)
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give
artificial respiration, preferably mouth-to-mouth, if possible. Call poison control center or doctor for treat-
ment advice.
SECTION 5: FIRE AND EXPLOSION INFORMATION
Flash Point (Method): NA
Flammable Limits (vol & in air): NA
Autoignition Temperature: NA
Extinguishing Media: Dry chemical, carbon dioxide, dry chemical foam.
Special Fire Fighting Procedures: Self-contained breathing apparatus, water to cool heated drums.
Unusual Fire and Explosion Hazards: None
SECTION 6: ACCIDENTAL RELEASE MEASURES
Steps to be Taken in Case Material is Released or Spilled: Absorb with sand or inert materials.
Sweep or scoop up and remove. Wash area thoroughly with water. Dispose of in compliance with all
state, federal and local laws.
SECTION 7: HANDLING AND STORAGE
Precautions to be Taken in Handling and Storing:Store in sealed container in cool, dry area. Keep
away from children.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Protective Clothing: Long sleeve shirt, long pants, or coveralls, water resistant boots.
Eye Protection: Chemical goggles or safety glasses with side shields recommended when handling
concentrate.
Ventilation: Use product outdoors or in a well ventilated area.
Respiratory Protection: None required under normal use.
Other: Protective barrier cream may be applied on exposed skin areas.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Off-White Suspension. Slight ammonia odor.
Boiling Point: 212藲 F
Vapor Pressure (@20掳 C): less than 2 mm Hg
pH: 6.5-7.5
Melting Point: Not determined
Freezing Point: 23掳 F
Specific Gravity (25掳 C): 1.25 @ 20藲 C
Vapor Density: N/A
Evaporation Rate: Not determined
Solubility in Water: Insoluble (dispersible)
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable at normal conditions
Incompatible Materials: Highly alkaline materials, oxidizing agents, lime sulfur, bordeaux mixture, cop-
per compounds
Conditions to Avoid: Extreme heat
Hazardous Decomposition: oxides or carbon, nitrogen and sulfur
Hazardous Polymerization: Will not occur
Effective Date: 2.1.05
NDA = No Data Available NA = Not Applicable
3336 PLUSTM Page 3 of 3
SECTION 11: TOXICOLOGICAL INFORMATION
Oral LD50: >6000 mg/kg
Dermal LD50: >2000 mg/kg
NOEL: 1600 ppm in diet for 180 days
Teratogenicity: No teratogenicity at 1000 mg/kg/day
Mutagenicity: Ames, Mammalian somatic, cytogenicity, Dominant lethal, DNA damage repair all test
negative
SECTION 12: ECOLOGICAL INFORMATION
This pesticide is toxic to fish. Do not apply directly to water or to areas where surface water is present,
or to intertidal areas below the mean high water mark. Do not contaminate water by disposal of equip-
ment wash-waters. Do not allow to drift, drain, or flush equipment onto non-target areas.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Methods: Dispose of in accordance with all applicable federal, state and local regula-
tions. Improper disposal of excess pesticide is a violation of federal law. If these wastes cannot be dis-
posed of by intended use according to label instruction, contact the appropriate agency in your state or
the nearest EPA regional office for guidance.
SECTION 14: TRANSPORTATION INFORMATION
DOT Hazard Class: Fungicide, Agricultural, NOI
Hazardous Substance: Not DOT or OSHA regulated
SECTION 15: REGULATORY INFORMATION
RCRA Waste Number: N/A
California Prop 65: This product can be found on the California List of Developmental Toxins
Thiophanate -methyl
NFPA Ratings: Flamability: 0 Reactivity: 0 Health: 1
EPA SARA Title III Data: NA
Section 302 Substances: NA
Section 311/312/313 Hazardous Categories: NA
SECTION 16: OTHER INFORMATION
Please note: Cleary Chemical Corp. believes that the information and recommendations contained here-
in are accurate as of the date hereof. The information provided herein applies only to the specific prod-
uct designated and may not be valid where said product is used in combination with any other material
or in any process. It is the users responsibility to determine the suitability of the information for their pur-
poses. No warranty of fitness for any particular purpose, warranty of merchantability, or any other war-
ranty, expressed or implied, is made concerning the information provided.
Reason for issue: Initial Registration
Prepared by: R. Fletcher and David Miles
Effective date: 2.1.05
Replaces: NA
Copyright 漏 2005 Cleary Chemical Corporation
Effective Date: 2.1.05
NDA = No Data Available NA = Not Applicable
CLEARY CHEMICAL CORPORATION
178 Ridge Road,
Dayton, NJ 08810-1501
www.clearychemical.com
EMERGENCY PHONE NUMBERS:
M-F 9AM-5PM EDT
800-524-1662
732-329-8399
24-Hour CHEMTREC
800-424-9300
PROSAR
800-324-7598
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