COGNIS CORPORATION
Material Safety Data Sheet
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SECTION 1: CHEMICAL PRODUCT and COMPANY IDENTIFICATION
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Revised: 01/02/2000
Supercedes: 07/23/1999
PRODUCT NAME: EMERY 5724
PRODUCT DESCRIPTION: N-Cyanoethyl-N-Hydroxyethyl Aniline
CASRN: See Section 2
MANUFACTURER: Cognis Corporation
4900 Este Avenue
Cincinnati,OH 45232
Phone: 800-543-7370 Fax: 513-482-5515
EMERGENCY NUMBERS:
CHEMTREC: 800-424-9300
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SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
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CHEMICAL CONCENTRATION(Wt.%) EXPOSURE LIMITS
N-Cyanoethyl-N-Hydroxy-Ethyl Aniline
CASRN 92-64-8 98.0 None Established
N-Hydroxyethylaniline
CASRN 122-98-5 < 5.0 None Established
N-Cyanoethylaniline
CASRN 1075-76-9 0.3000 None Established
Ethylphenyl Ethanolamine
CASRN 92-50-2 0.5000 None Established
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SECTION 3: HAZARDS IDENTIFICATION
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*************** Emergency ****************
*************** Overview ****************
WARNING!
Harmful if swallowed, inhaled or absorbed through skin. Causes skin,
eye and respiratory irritation.
Brown liquid with ammonia-like odor
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SKIN CONTACT:
Can cause irritation, especially on prolonged contact.
EYE CONTACT:
Causes severe irritation.
INHALATION:
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Mist or vapor may cause respiratory tract irritation and possible
methemoglobinemia exhibited by bluish lips and fingernails,
headache, nausea or fatigue. Possible symptoms similar to cyanide
poisoning may also occur.
INGESTION:
May cause gastrointestinal tract irritation nausea, vomiting, diarrhea
and methemoglobinemia.
CHRONIC EFFECTS:
Dermatitis, methemoglobinemia. May aggravate existing skin, eye, lung
and blood conditions.
OTHER HEALTH EFFECTS:
May be toxic if absorbed through skin.
PRIMARY ROUTES OF EXPOSURE: Inhalation,Skin,Oral
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SECTION 4: FIRST AID MEASURES
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SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing and
footwear. Wash clothing before reuse. If irritation should develop,
get medical attention.
EYE CONTACT:
Immediately flush with plenty of water for at least 15 minutes holding
eyelids apart to ensure flushing of the entire surface. Washing within
one minute is essential to achieve maximum effectiveness. Get medical
attention.
INHALATION:
Remove to fresh air.
INGESTION:
Do not induce vomiting. If vomiting should occur spontaneously, keep
airway clear. Get medical attention. Never give anything by mouth to
an unconscious person.
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SECTION 5: FIRE FIGHTING MEASURES
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Flash Point: 345 Deg F ( Cleveland Open Cup )
LFL: Not Determined UFL: Not Determined
AUTOIGNITION TEMPERATURE Not Determined
RECOMMENDED EXTINGUISHING MEDIA:
Carbon dioxide,Dry chemical,Foam,Water spray
SPECIAL FIRE FIGHTING PROCEDURES:
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Cool exposed containers with water spray. Self-contained breathing
apparatus in confined areas.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
None Known
HAZARDOUS COMBUSTION PRODUCTS:
Carbon dioxide, carbon monoxide, oxides of nitrogen and cyanide.
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SECTION 6: ACCIDENTAL RELEASE MEASURES
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STEPS TO TAKE IN CASE OF SPILL OR LEAK:
Stop leaks. Clean up large spills with vacuum truck. Soak up small
spills with absorbent material and place in labeled waste container for
disposal. Wear adequate personal protective clothing and equipment.
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SECTION 7: HANDLING AND STORAGE
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Store in a cool, dry location away from oxidizing agents. Keep
containers tightly closed when not in use. Store away from low
flashpoint materials.
Wash thoroughly after handling.
FOR INDUSTRIAL USE ONLY.
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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
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EYE PROTECTION:
Chemical splash goggles or face shield.
SKIN PROTECTION:
Rubber gloves
RESPIRATORY PROTECTION:
NIOSH/MSHA-approved respirator if necessary. Follow manufacturer's
recommendations.
ENGINEERING CONTROLS:
Local exhaust ventilation recommended.
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SECTION 9: PHYSICAL and CHEMICAL PROPERTIES
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PHYSICAL STATE: Liquid
APPEARANCE: Brown liquid with ammonia-like odor
ODOR: Ammonia-like
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ODOR THRESHOLD: Not Determined
pH: Not Determined
MELTING POINT: Not Determined
BOILING POINT: Not Determined
SPECIFIC GRAVITY: 1.02
SOLUBILITY IN WATER: Slight (0.1 to 1 %)
PERCENT VOLATILES(by Wt.): Not Determined
VAPOR DENSITY: Heavier than Air
VAPOR PRESSURE: Not Determined
EVAPORATION RATE(N-BUTYL ACETATE=1): Not determined
VOC CONTENT(EPA Method 24): Not Determined
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SECTION 10: STABILITY AND REACTIVITY
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STABILITY: Normally Stable
HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBLE MATERIALS:
Strong oxidizing agents.
CONDITIONS TO AVOID:
None known.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon dioxide, carbon monoxide, oxides of nitrogen and cyanide.
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SECTION 11: TOXICOLOGICAL INFORMATION
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N-Cyanoethyl-N-Hydroxyethyl Aniline:
Acute Oral LD50 = 3.41 g/kg (rat)
N-Hydroxyethylaniline
Acute Oral LD50 = 2.23 g/kg (rat)
Acute Dermal LD50 = 63 mg/kg (rabbit)
Acrylonitrile is considered a suspect human carcinogen based on
animal studies.
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SECTION 12: ECOLOGICAL INFORMATION
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ECOLOGICAL TOXICITY:
Not Determined
ENVIRONMENTAL FATE:
Not Determined
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SECTION 13: DISPOSAL CONSIDERATIONS
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Dispose of product by incineration in an approved chemical waste
facility (or by other approved methods) in accordance with applicable
Federal, State and local regulations. Avoid landfilling liquids. Since
emptied container retains product residues, all labeled hazard
precautions must be observed.
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SECTION 14: TRANSPORTATION INFORMATION
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PROPER SHIPPING NAME: NOT REGULATED BY THIS MODE OF TRANSPORTATION
UN/NA: N/A
DOT HAZARD CLASS: Not Determined
DOT HAZARDOUS MATERIALS:
Not Applicable
EMERGENCY RESPONSE GUIDE NUMBER: Not Determined
PACKAGING GROUP: Not Determined
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SECTION 15: REGULATORY INFORMATION
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TSCA INVENTORY STATUS:
This product and/or all of its components are included on the TSCA
Inventory of Chemical Substances.
TSCA 12(b) COMPONENTS:
None
SARA 311/312 HAZARD CATEGORIES: Acute,Chronic
SARA 313 TOXIC CHEMICALS:
None
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES:
Acrylonitrile(107-13-1) < 0.0750 %
Ethylene Oxide(75-21-8) < 0.0020 %
CERCLA HAZARDOUS SUBSTANCES:
Acrylonitrile(107-13-1) < 0.0750 %
Ethylene Oxide(75-21-8) < 0.0020 %
1,4-Dioxane(123-91-1) < 0.0500 %
Acetaldehyde(75-07-0) < 0.0900 %
CALIFORNIA PROPOSITION 65 COMPONENTS:
WARNING ! This product contains a chemical (or chemicals) known to the
State of California to cause cancer, birth defects and/or other
reproductive harm.
Acrylonitrile(107-13-1) < 0.0750 %
Ethylene Oxide(75-21-8) < 0.0020 %
1,4-Dioxane(123-91-1) < 0.0500 %
Acetaldehyde(75-07-0) < 0.0900 %
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SECTION 16: OTHER INFORMATION
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HMIS RATINGS: HEALTH: 2* FLAMMABILITY: 1 REACTIVITY: 0
NFPA RATINGS: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 OTHER: None
THE FOLLOWING WARNING INFORMATION IS PROVIDED ON THE LABEL FOR THIS PRODUCT:
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WARNING!
Harmful if swallowed, inhaled or absorbed through skin. Causes skin,
eye and respiratory irritation.
CHRONIC EFFECTS:
Dermatitis, methemoglobinemia. May aggravate existing skin, eye, lung
and blood conditions.
FIRST AID - INHALATION:
Remove to fresh air.
FIRST AID - SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing and
footwear. Wash clothing before reuse. If irritation should develop,
get medical attention.
FIRST AID - EYE CONTACT:
Immediately flush with plenty of water for at least 15 minutes holding
eyelids apart to ensure flushing of the entire surface. Washing within
one minute is essential to achieve maximum effectiveness. Get medical
attention.
FIRST AID - INGESTION:
Do not induce vomiting. If vomiting should occur spontaneously, keep
airway clear. Get medical attention. Never give anything by mouth to
an unconscious person.
STEPS TO TAKE IN CASE OF SPILL OR LEAK:
Stop leaks. Clean up large spills with vacuum truck. Soak up small
spills with absorbent material and place in labeled waste container for
disposal. Wear adequate personal protective clothing and equipment.
HANDLING AND STORAGE:
Store in a cool, dry location away from oxidizing agents. Keep
containers tightly closed when not in use. Store away from low
flashpoint materials.
Wash thoroughly after handling.
FOR INDUSTRIAL USE ONLY.
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ABBREVIATIONS USED:
ND or N/D = Not Determined
NA or N/A = Not Applicable or Not Available
NE or N/E = Not Established
N/AP = Not Applicable
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All information, recommendations, and suggestions appearing herein
concerning our product are based upon tests and data believed to be
UCM05724R\946000001572 Cognis MSDS Page: 6
reliable. However, it is the user's responsibility to determine the
safety, toxicity, and suitability for his own use of the product
described herein. Since the actual use by others is beyond our
control, no guarantee, express or implied, is made by Cognis
Corporation as to the effects of such use, the results obtained, or the
safety and toxicity of the product nor does Cognis Corporation assume
any liability arising out of use, by others, of the product referred to
herein. The information herein is not to be construed as absolutely
complete since additional information may be necessary or desirable
when particular or exceptional conditions or circumstances exist or
because of applicable laws or government regulations.
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PREPARED BY:
Cognis Corporation
Product Safety/Regulatory Affairs
4900 Este Avenue
Cincinnati, OH 45232
Phone: 215/628-1000 Fax: 215/628-1153
UCM05724R\946000001572 Cognis MSDS Page: 7
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