MSDS PAGE: CAS N/A MSDS clearychemical

MATERIAL SAFETY DATA SHEET
®
ENDORSE Page 1 of 6

Please read the entire document. This Material Safety Data Sheet contains important environmental, health
and toxicology information for your employees, and anyone who will use, transport, store, dispose of or
handle this product. Please make sure this information is given to them. It also contains information to help
you meet community righttoknow/emergency response reporting requirements under SARA Title III and
many other laws. If you resell this product, this MSDS must be given to the buyer or the information
contained herein must be incorporated in your MSDS.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
®
PRODUCT NAME: ENDORSE
EPA REGISTRATION NUMBER(S): 66330411001
SYNONYM(S): Polyoxin D Zinc Salt, TM43801, STOPIT

COMPANY EMERGENCY TELEPHONE NUMBERS
Cleary Chemical Corporation HEALTH EMERGENCY: SPILL EMERGENCY:
178 Ridge Road, Suite A
18663036952, or 18004249300, or
Dayton, NJ 08810
16516328946 17035273887

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

Active Ingredient(s)/ CAS # Exposure Limits* % %
Hazardous Inert Ingredient(s) Weight Volume

a
Zinc 5[[2amino5O 146659781 TWA 2.5 NA
b
(aminocarbonyl)2deoxyL OSHA PEL : None
c
xylonoyl]amino]1(5carboxy ACGIH TLV : None
d
3,4dihydro2,4dioxo1(2H) NIOSH REL : None
pyrimidinyl)1,5dideoxybD
allofuranuronate

Only the identities of the active ingredient(s) and any hazardous inert ingredients are listed. Specific information on all of
this product’s ingredients can be obtained by the treating medical professional or spill emergency responder for the
management of exposures, spills, or safety assessments.

*Source: Guide to Occupational Exposure Values 2000, published by ACGIH
a
TWA: Timeweighted average exposure concentration for a conventional 8hour (TLV, PEL) or up to a 10hour (REL)
workday and a 40hour workweek.
b
OSHA PEL: Occupational Safety and Health Administration Permissible Exposure Limits.
c
ACGIH TLV: American Conference of Governmental Industrial Hygienists, Inc., Threshold Limit Values.
d
NIOSH REL: National Institute for Occupational Safety and Health Recommended Exposure Limits.

EMERGENCY TELEPHONE #: 18663036952 or 16516328946
MSDS Number: 00155 Issue Date: 03/05/06
NDA = No Data Available NA = Not Applicable
®
ENDORSE Page 2 of 6

SECTION 3: HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

CAUTION: MAY CAUSE SLIGHT EYE AND SKIN IRRITATION
PROLONGED EXPOSURE MAY CAUSE SKIN SENSITIZATION
KEEP OUT OF REACH OF CHILDREN

Acute Health Hazards
Eye: May cause slight eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap
and water after handling.

Skin: May cause slight skin irritation. Avoid contact with skin and clothing. Wash thoroughly with
soap and water after handling. Prolonged exposure may cause skin sensitization.

Ingestion: Not expected to be an ingestion hazard under normal handling procedures.

Inhalation: Not expected to be an inhalation hazard under normal handling procedures.

Chronic Health Hazards (Including Cancer): No evidence of carcinogenicity or other treatmentrelated
effects following chronic exposure in laboratory animals.

Reproductive and developmental Toxicity: No evidence of reproductive or developmental toxicity.

SECTION 4: FIRST AID MEASURES

Eyes: Hold eye open and rinse slowly and gently with water for 1520 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for
treatment advice.

Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 1520 minutes. Call a
poison control center or doctor for treatment advice.

Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass
of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor.
Do not give anything by mouth to an unconscious person.

Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give
artificial respiration, preferably mouthtomouth if possible. Call a poison control center or doctor for
treatment advice.

EMERGENCY TELEPHONE #: 18663036952 or 16516328946
MSDS Number: 00155 Issue Date: 03/05/06
NDA = No Data Available NA = Not Applicable
®
ENDORSE Page 3 of 6

SECTION 5: FIRE FIGHTING MEASURES

Flammable Limits in Air (% by volume):
Upper: NDA
Lower: NDA
Flash Point: NDA
Method Used: NDA
Autoignition Temperature: NDA
LEL/UEL: NDA
NFPA Hazard Classification:
Health: 1
Flammability: 0
Reactivity: 0
Other: None
Extinguishing Media: Water spray or dry chemical
Special Fire Fighting Procedures: NDA
Hazardous Combustion Products: NDA

SECTION 6: ACCIDENTAL RELEASE MEASURES

EMERGENCY PHONE NUMBERS
Exposure Calls (PROSAR): 18663036952 or 16516328946 (International)
Spill Calls (CHEMTREC): 18004249300 or 17035273887

Sweep up spilled material and place in covered, dry container. Wash spill response materials thoroughly
before reuse.

SECTION 7: HANDLING AND STORAGE

It is a violation of federal law to use this product in a manner inconsistent with its labeling. Read entire label.
Use strictly in accordance with label precautionary statements and directions. Read and observe all
precautions on product label. Handle and open container with care. Avoid inhaling this material. Avoid eye
and skin contact with this material. Wash contaminated clothes thoroughly before reuse. Use with adequate
ventilation. Wash thoroughly with soap and water after handling. Keep container closed or equipped with a
local air exhauster. Handle the container carefully. Do not drop or drag the container. Avoid impacts to the
container. Store container in dry conditions without direct sunlight.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Eye Protection: Wear suitable eye protection.

Respiratory/Ventilation Requirements: Dustproof mask.

Skin Protection: Wear appropriate protective clothing and gloves to prevent skin contact.

EMERGENCY TELEPHONE #: 18663036952 or 16516328946
MSDS Number: 00155 Issue Date: 03/05/06
NDA = No Data Available NA = Not Applicable
®
ENDORSE Page 4 of 6

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance and Physical State: Gray brownish fine powder
Odor: Characteristic odor
pH: 5.57.5
Boiling Point: NA
Melting Point: > 240°C
Freezing Point: NA
Vapor Pressure: NA
Vapor Density: NA
Specific Gravity: 0.250.37 g/cc
Evaporation Rate: NA
Solubility:
Water, acetone, DMSO: Up to 0.1 g/L
0.1N hydrochloric acid: 43.5 g/L
0.1N sodium hydroxide: 4.0 g/L
Percent Solids by Weight: NA
Percent Volatile: NA
Volatile Organic Compounds:
with water: NDA
without water: NDA
Molecular Weight: NDA
Viscosity: NA

SECTION 10: STABILITY AND REACTIVITY

Chemical Stability: Stable for at least one year
Hazardous Polymerization: NDA
Flash Point: NDA
Flammable Point: NDA
Auto Ignition: NDA
Incompatibility With Other Materials: NDA
Hazardous Decomposition Products: NDA

SECTION 11: TOXICOLOGICAL INFORMATION

Acute:
Eye Irritation: Slight eye irritant (cleared within 4 days following exposure)

Skin Irritation: Slight skin irritant (P.I.I. = 0.8)

Skin Sensitization: A mild skin sensitizer in guinea pigs

Dermal Toxicity: LD50 (rat) =>2,000 mg/kg

Oral Toxicity: LD50 (rat) => 15,000 mg/kg (M) and 10,000 to 15,000 mg/kg (F)

Inhalation Toxicity: 4hour LC50 (aerosol) => 2.78 mg/L

Subchronic Toxicity: No treatmentrelated effects were observed following chronic exposure in laboratory
animals to polyoxin D technical.

EMERGENCY TELEPHONE #: 18663036952 or 16516328946
MSDS Number: 00155 Issue Date: 03/05/06
NDA = No Data Available NA = Not Applicable
®
ENDORSE Page 5 of 6
Chronic Health Hazards (including Cancer): No evidence of carcinogenicity or other treatmentrelated
effects following chronic exposure in laboratory animals.

Reproductive and Developmental Toxicity: No evidence of reproductive or developmental toxicity.

Genotoxicity: No evidence of genotoxicity.

SECTION 12: ECOLOGICAL INFORMATION

Environmental Fate and Distribution: Product decomposes

Aquatic Organism Toxicity (based upon technical material):
Rainbow trout (Oncorhynchus mykiss) 96hr LC50 = 5.1 ppm
Daphnid (Daphnia magna) EC50 = 1.4 ppm

Avian Toxicity (based upon technical material):
Mallard duck oral LD50 > 2150 ppm
Mallard duck dietary LC50 > 5000 ppm

SECTION 13: DISPOSAL CONSIDERATIONS

End users must dispose of any unused product as per the label recommendations and in accordance with
all applicable laws and regulations. Check governmental regulations and local authorities for approved
disposal of this material.

SECTION 14: TRANSPORT INFORMATION

D.O.T. Shipping Name: Pesticide, nonregulated
Technical Shipping Name: NA
Packing Group: NA
D.O.T. Hazard Class: NA
U.N/N.A. Number: NA
Product RQ (lbs): NA
D.O.T. Label: NA
D.O.T. Placard: NA
Marine Pollutant: NA

IMO :
IMO Label: NA
IMO Placard: NA

European Road/Rail:
Class: NA

SECTION 15: REGULATORY INFORMATION

U.S Federal Regulations
FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act): All pesticides are governed under
FIFRA. Therefore, the regulations presented below are pertinent only when handled outside of the
normal use and applications of pesticides. This includes waste streams resulting from
manufacturing/formulation facilities, spills or misuse of products, and storage of large quantities of
products containing hazardous or extremely hazardous substances.

EMERGENCY TELEPHONE #: 18663036952 or 16516328946
MSDS Number: 00155 Issue Date: 03/05/06
NDA = No Data Available NA = Not Applicable
®
ENDORSE Page 6 of 6
CERCLA (Comprehensive Response Compensation, and Liability Act): NA

EPCRA (Emergency Planning and Community RighttoKnow Act) Section 313: None

OSHA (Occupational Safety and Health Administration): NA

RCRA (Resource Conservation and Recovery Act): None

SARA Title III (SUPERFUND Amendments and Reauthorization Act):
Section 302 (EHS) TPQ: NONE

Section 304 (EHS) RQ: NONE

Section 311/312 CATEGORIES 1. Immediate (Acute) Health Effects; YES
2. Delayed (Chronic) Health Effect; NO
3. Fire Hazard; NDA
4. Sudden Release of Pressure Hazard; NDA
5. Reactivity Hazard; NDA

TSCA (Toxic Substance Control Act): This product is exempt from TSCA Regulation under
FIFRA Section 3 (2)(B)(ii) when used as a pesticide.

State Regulations: Each state may promulgate standards more stringent than the federal government.
This section cannot encompass an inclusive list of all state regulations. Therefore, the user should consult
state or local authorities.

International Regulations:
EEC Classification: NA

Risk Phrases: NA

Safety Phrases: NA

SECTION 16: OTHER INFORMATION

Reason for issue: Changes to Company Address (Section 1) and Telephone Number
(Section 16)
Arysta MSDS Prepared by: James J. Reilly, Jr.
Cleary MSDS Prepared by: Pedro Perdomo
Issue date: 03/05/06
Supersedes date: 09/06/05
MSDS number: CL00155

The information in this MSDS is based on data available to us as of the issue date given herein, and
believed to be correct. Contact Arysta LifeScience North America Corporation at (919) 6784900 to
determine if additional data and information have become available since the issue date.

Judgments as to the suitability of information herein for the individual’s own uses or purposes are
necessarily the individual’s own responsibility. Although reasonable care has been taken in the preparation
of such information, Arysta LifeScience North America Corporation extends no warranties, makes no
representations, and assumes no responsibility as to the accuracy or suitability of such information for
application to the individual's purposes or the consequences of its use.

EMERGENCY TELEPHONE #: 18663036952 or 16516328946
MSDS Number: 00155 Issue Date: 03/05/06
NDA = No Data Available NA = Not Applicable

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