MATERIAL SAFETY DATA SHEET
Product Name: ClearSpray E.P.A. Registration Number: Not regulated
W.A.Cleary Product Code: 4751 (1gal), Chemical Name: Acrylic polymer
4752 (2.5 gal), 4755 (55 gal) Synonyms: Aqueous acrylic emulsion
Active Ingredient (CAS #) Percent Exposure Limits
Acrylic polymer 47.00% N/E
Ammonia 0.02% 25 ppm ACGIH
Formaldehyde 0.05% 3 ppm OSHA
Inert Ingredients 52.75%
HEALTH HAZARD DATA
Inhalation: Vapors may be irritating to mucous membranes and respiratory tract.
Eye Contact: Direct contact with may result in slight irritation.
Skin Contact: Prolonged or repeated skin contact may cause irritation.
Chronic Effects Of Overexposure: May produce sumptoms of headache and/or nausea in poorly ventilated areas.
EMERGENCY AND FIRST AID PROCEDURES
Ingestion: If victim is conscious, give water to drink. Call physician.
Skin Contact: Wash skin thoroughly with soap and water. If drenched, remove clothing and wash before reuse.
Eye Contact: Flush immediately with plenty of water for at least 15 minutes. If irritation persists,seek medical attention.
Inhalation: Remove subject to fresh air.
FIRE & EXPLOSION DATA
Flash Point: Not flammable
Flammable Limits (vol % in air): LEL N/A, UEL N/A
Autoignition Temperature: N/A
Extinguishing Media: Non-combustible
Special Fire Fighting Procedures: Wear MSHA/NIOSH approved self-contained breathing apparatus.
Unusual Fire and Explosion Hazards: Acrylic emulsions will not burn. They may spatter if temperature exceeds boiling point.
Dried polymer films are capable of burning.
ACCIDENTAL RELEASE MEASURES
Steps to be taken in case material is released or spilled: Dike and contain spill with inert material (dry sand, earth, etc.) and
transfer the liquids to containers for recovery or disposal. Keep spill out of sewers and open bodies of water. Floors may be
slippery. Care should be exercised to avoid falls.
HANDLING AND STORAGE
Precautions to be taken in handling and storing: Maximum storage temperature 140掳F. Minimum storage temperature 32掳F.
Store in original, sealed container, not exposed to the atmosphere. Keep from freezing. Product may coagulate.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Protective Clothing: Impervious gloves recommended.
Eye Protection: Splash-proof safety goggles (ANSI Z87.1, 1979).
Ventilation: Mechanical local exhaust at point of containment (vapor or mist release).
Respiratory Protection: None required if good ventilation is maintained. Otherwise, wear MHSA/NIOSH approved dust/mist
mask suitable for the vapor concentrations encountered.
Other: Eyewash station, emergency shower.
Cleary Chemical Corporation
178 Ridge Road, Dayton, NJ 08810-1501
Emergency Phone Numbers:
M-F ET 800-524-1662 732-329-8300
24 Hour CHEMTREC 900-424-9300
Effective Date: December, 1997
PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: 212掳F (100掳C) % Volatile: ~ 53
Melting Point: N/A Evaporation Rate: < 1
Freezing Point: 32掳F (0掳C) Solubility In Water: 100%
Specific Gravity: 1.06 Appearance And Odor: Milky white liquid, slight ammonia odor.
Vapor Pressure (@ 20掳C mm Hg): 17 mm Hg
REACTIVITY HAZARD DATA
Stability: Stable at normal conditions
Conditions To Avoid: N/A
Hazardous Polymerization: Will not occur
Hazardous Decomposition Products: Thermal decomposition may yield oxides of carbon and monomer fumes.
Oral (acute): LD50 > 5.0 mg/kg (rat)
Dermal (acute): LD50 > 5.0 mg/kg (rabbit)
Inhalation (acute): N/A
Chronic (oral): N/A
Subchronic (oral): N/A
Waste Disposal Methods: If product cannot be used in accordance with label instructions, dispose of waste in compliance with all
federal, state, and local laws.
DOT Shipping Description: Adjuvants, sprayable OSHA Hazard Classification: N/A
product Reportable Quantity: N/A
DOT Hazard Classification: Not regulated Hazardous Substance: None
UN Identification Number: None DOT Label Requirements: Not required
EPA SARA TITLE III DATA: ACUTE LOW
SECTION 302 Substances: N/A SECTION 313 TOXIC CHEMICALS: N/A
RCRA Waste Number: N/A CERCLA RQ: N/A
SECTION 311/312 Hazardous Categories: N/A CALIFORNIA PROP 65: N/A
Immediate Health: No NFPA RATINGS
Delayed Health: No Flammability: 0
Fire: Low Reactivity: 0
Reactive: None Health: 1
Sudden Pressure: No
PLEASE NOTE: W.A.CLEARY CHEMICAL CORPORATION believes that the information and recommendations contained herein are accurate as of the date
hereof. The information provided herein applies only to the specific product designated and may not be valid where said product is used in combination with any
other material or in any process. It is the user鈥檚 responsibility to determine the suitability of the information for their purposes. No warranty of fitness for any
particular purpose, warranty of merchantability, or any other warranty, expressed or implied, is made concerning the information provided herein.
Prepared By: Richard F. Fletcher, M.S. and C. L. Palmer, Ph.D., Cleary Chemical Effective: December 1997 Document Number: WAC4151