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MSDS Material Safety Data Sheet
CAS

8033-22-1
135410-20-7
112926-00-8
1332-58-7

File Name: clearychemical_com---7010M.asp
                         MATERIAL SAFETY DATA SHEET
TRISTARTM 70 WSP - ACETAMIPRID INSECTICIDE Page 1 of 7

Please read the entire document. This Material Safety Data Sheet contains important environmental,
health and toxicology information for your employees, and anyone who will use, transport, store,
dispose of or handle this product. Please make sure this information is given to them. It also contains
information to help you meet community right-to-know/emergency response reporting requirements
under SARA Title III and many other laws. If you resell this product, this MSDS must be given to the
buyer or the information contained herein must be incorporated in your MSDS.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TRISTARTM 70 WSP
CLEARY PRODUCT CODE: 7010
EPA REGISTRATION NUMBER(S): 8033-22-1001
CHEMICAL NAME: Acetamiprid, (E)-N1-[(6-chloro-3-pyridyl)methyl]-N2-cyano-
N1-methylacetamidine
CHEMICAL FAMILY: Nicotinoid
CHEMICAL FORMULATION: C10 H11 CI N4
PRODUCT USE DESCRIPTION: For Commercial Use Only. Ornamental use only. Not for
Woodlands or forest management.

EMERGENCY TELEPHONE NUMBERS
COMPANY
CLEARY CHEMICAL CORP. PROSAR:
Cleary Chemical Corporation M-F 9-5 EST (800) 324-7598
178 Ridge Road, Suite A (800) 524-1662 OR CHEMTREC 24 HOUR:
Dayton, New Jersey 08810 (732) 329-8399 (800) 424-9300

SECTION 2: INFORMATION ON INGREDIENTS

Active Ingredient(s)/ % by Wt. CAS# Exposure Limits
Hazardous Inert Ingredient(s)

Acetamiprid, (E)-N1-[(6-chloro-3- 73.0 135410-20-7
pyridl)methyl]-N2-cyano-N1-
methylacetamidine

Amorphous silicon dioxide hydrate 7.9 112926-00-8
(Amorphous silica)

Hydrous Aluminum Silicate 15.0 1332-58-7

Other Ingredients (Trade Secret) 13.2


SECTION 3: HEALTH HAZARD INFORMATION
Inhalation: Harmful if inhaled. Avoid breathing dust or spray mist.
Eye Contact: Avoid contact with eyes.
Skin Contact: Harmful if absorbed through skin. Avoid contact with skin or clothing.
Ingestion: Harmful if ingested.

Document Number: 7010 Issue Date: 07/03
NDA = No Data Available N/A = Not Applicable N/E = Not Established
TRISTARTM 70 WSP - ACETAMIPRID INSECTICIDE Page 2 of 7
Chronic Effects of Overexposure: This product does not contain any ingredients designated by
IARC, NTP, ACGIH or OSHA as probable or suspected human carcinogens.
Other Toxic Effects: Inhalation of product may aggravate existing chronic respiratory problems such
as asthma, emphysema or bronchitis. Skin contact may aggravate existing skin disease.
Signs and Symptoms: Have the product container or label with you when calling a poison control
center or doctor or going for treatment.
SECTION 4: FIRST AID MEASURES
Ingestion: Immediately call a poison control center or doctor for treatment advice. DO NOT induce
vomiting unless directed to do so by a physician or poison control center. Have a person sip a glass of
water if able to swallow. Do not give anything by mouth to an unconscious person.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. Call a poison control center or doctor for treatment advice.
Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact
lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or
doctor for treatment advice.
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give arti-
ficial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further
treatment advice.
Note to Physician: There is no specific antidote. All treatment should be based on observed signs and
symptoms of distress in the patient. Consideration should be given to the possibility that overexposure
to materials other than this product may have occurred.
SECTION 5: FIRE AND EXPLOSION INFORMATION
Flammability:
Combustion: Will form dust explosive mixtures in air. Dust explosive rating of ST-1 (KsT=165 bar-
meter per second).
Flash Point (Method): N/A
Extinguishing Media: Dry chemical, alcohol foam, water spray, carbon dioxide (CO2)
Special Fire Fighting Procedures: Firefighters should wear NIOSH/MSHA approved self-contained
breathing apparatus and full protective clothing. Keep unnecessary people away, isolate hazard area
and deny entry. Stay upwind if possible. Keep out of low areas. Persons who may have been exposed
to contaminated smoke should be immediately examined by a physician and checked for symptoms of
poisoning. The symptoms should not be mistaken for heat exhaustion or smoke inhalation.
Unusual Fire and Explosion Hazards: Like all organic and most dry chemicals, as a powder or dust,
this product (when mixed with air in critical proportions and in the presence of an ignition source) may
present an explosion hazard.

SECTION 6: ACCIDENTAL RELEASE MEASURES
General and Disposal
Evacuation Procedures and Safety: Personnel handling this material should be thoroughly trained to
handle spills and releases. Wear appropriate gear for the situation. See Personal Protection information
in Section 8.
Cleanup and Disposal of Spill: Sweep up and place in an appropriate closed container (see Section
7: Handling and Storage). No sparking tools should be used. Avoid creation of dusty conditions. Clean
up residual material by washing area with water and detergent. Collect washings for disposal.
Decontaminate tools and equipment following cleanup.
Spill or Leak Procedures
Containment of Spill: Stop leak if it can be done without risk. Follow procedure under Cleanup and
Disposal of Spill.
Environmental and Regulatory Reporting: Do not flush to drain. If spilled on the ground, the affected
area should be scraped clean and placed in an appropriate container for disposal. Prevent material from
entering public sewer system or any waterway. Spills may be reportable to the National Response
Center (800-424-8802) and to state and /or local agencies.



Document Number: 7010 Issue Date: 07/03
NDA = No Data Available N/A = Not Applicable N/E = Not Established
TRISTARTM 70 WSP - ACETAMIPRID INSECTICIDE Page 3 of 7

SECTION 7: HANDLING AND STORAGE
Handling Procedures: KEEP OUT OF REACH OF CHILDREN AND ANIMALS
Personnel handling this product should be thoroughly trained as to its hazards. Use nonsparking tools
and grounded/bonded equipment and containers when transferring. Do not ingest. Do not breathe dust
or mists. Avoid getting material on clothing. Use handling, storage and disposal procedures that will
prevent contamination of water, food or feed.

THIS PRODUCT MAY PRESENT A DUST EXPLOSION HAZARD

Dry powders can build static electricity charges when subjected to the friction of conveying, mixing or
sliding. Provide adequate precautions, such as electrical grounding, or inert atmospheres when material
is used in the presence of flammable materials to prevent ignition.
It is recommended that all dust control equipment and material transport systems involved in handling
of this product contain explosion relief vents or explosion suppression system or an oxygen deficient
environment. In addition, all conductive elements of the system that contact this material should be
electrically bonded and grounded. This powder should not be flowed through non-conductive ducts or
pipes. Use only appropriately classed electrical equipment.

Storing Procedures: Do not store in or around the home. Store unused product in a cool, ventilated,
dry, locked area. Never transfer this product to another container for storage. Do not allow prolonged
storage in areas where temperatures frequently exceed 115掳F (46掳C).

Work/Hygienic Procedures: Personal hygiene is an important work practice exposure control measure
and the following general measures should be taken when working with or handling this material:

Wash hand before eating, drinking, chewing gum, using tobacco or using the toilet.

Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing.
Remove Personal Protective Equipment (PPE) immediately after handling this product. Wash the out-
side of gloves before removing.

Discard clothing and other absorbent materials that have been drenched or heavily contaminated with
this product鈥檚 concentrate. Do not reuse them. Follow manufacturer鈥檚 instructions for cleaning/maintaining
Personal Protective Equipment (PPE). If no such instructions for washables, use detergent and hot
water. Keep and wash PPE separately from other laundry.

Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours.

Do not apply this product in a way that will contact workers or other persons, either directly or through
drift. Only protected handlers may be in the area during application. For any requirements specific to
your State or Tribe, consult the agency responsible for pesticide regulation.

Min/Max Storage: Min Temp: No data Max Temp: 46掳C

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Where engineering controls are indicated by use conditions or a potential for
excessive exposure exists, the following traditional exposure control techniques may be used to effec-
tively minimize employee exposures: general area dilution/exhaust ventilation.
Protective Clothing: Applicators and other handlers must wear long-sleeved shirts and long pants,
waterproof gloves, shoes plus socks and chemical resistant headgear for overhead exposure.
Eye/Face Protection: Eye and face protection requirements will vary dependent upon work environ-
ment conditions and material handling practices. Appropriate ANSI Z87 approved equipment should be
selected for the particular use intended for this material.


Document Number: 7010 Issue Date: 07/03
NDA = No Data Available N/A = Not Applicable N/E = Not Established
TRISTARTM 70 WSP - ACETAMIPRID INSECTICIDE Page 4 of 7

Eye contact should be prevented through use of chemical safety glasses with side shields or splash
proof goggles. An emergency eye wash must be readily accessible to the work area.
Exposure Limits:
Amorphous silicon 112926-00-8 ACGIH TWA 10 mg/m3
dioxide hydrate
(Amorphous silica)
OSHA Z1A TWA 6 mg/m3
US CA OEL TWA PEL 5 mg/m3
Form of Exposure Respirable fraction.
US CA OEL TWA PEL 5 mg/m3
Form of Exposure Respirable fraction.
US CA OEL TWA PEL 10 mg/m3
Form of Exposure Total dust.
US CA OEL TWA PEL 5 mg/m3
Form of Exposure Respirable fraction.
US CA OEL TWA PEL 10 mg/m3
Form of Exposure Total dust.
US CA OEL TWA PEL 10 mg/m3
Form of Exposure Total dust.
Hydrous Aluminum 1332-58-7 ACGIH TWA 2 mg/m3
Silicate
NIOSH REL 5 mg/m3
Form of Exposure Respirable.
NIOSH REL 10 mg/m3
Form of Exposure Total
US CA OEL TWA PEL 2 mg/m3
Form of Exposure Respirable dust.
OSHA Z1 PEL 5 mg/m3
Form of Exposure Respirable fraction.
OSHA Z1 PEL 15 mg/m3
Form of Exposure Total dust.
OSHA Z1A TWA 5 mg/m3
Form of Exposure Respirable fraction.
OSHA Z1A TWA 10 mg/m3
Form of Exposure Total dust.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Physical Appearance and odor: Solid Off-white Powder. No odor determined.
Boiling Point: NDA
Vapor Pressure @20掳C mm Hg: NDA
% Volatile: NDA
Melting Point: NDA
Freezing Point: NDA
Specific Gravity (25掳C): NDA
Evaporation Rate: N/A
Solubility in water: Approximately 2.7 wt/wt % dispersible
pH: 8.5 - 9.5 at 1 wt/wt% dilution in water at 22掳C
Vapor Density (air = 1): N/A
Density: 13-17 lb/cu ft (loose)




Document Number: 7010 Issue Date: 07/03
NDA = No Data Available N/A = Not Applicable N/E = Not Established
TRISTARTM 70 WSP - ACETAMIPRID INSECTICIDE Page 5 of 7

Other Information: Physical and Chemical properties here represent typical properties of this product.
Contact the business area using the Product Information phone number in Section 1 for its exact
specifications.

SECTION 10: STABILITY AND REACTIVITY
Stability: This material is stable under normal handling and storage conditions described in Section 7.
Conditions to Avoid: None known
Incompatibility: Strong bases, strong acids and strong oxidizing agents.
Hazardous Polymerization: Will not polymerize.

SECTION 11: TOXICOLOGICAL INFORMATION
Toxicity Data:
Oral (acute): Rat: LD50: = 1,064 mg/kg
Dermal (acute): Rabbit: LD50: >2,000 mg/kg
Inhalation (acute): Rat: LC50: >2.88 mg/l 4 h Acute Respiratory Irritation: No test data found for product.
Skin Irritation: Rabbit: Slightly irritating
Eye Irritation: Rabbit: Mildly irritating
Sensitization: Guinea pig: Non-sensitizing
Chronic Toxicity: In long term animal feeding studies there was no evidence of carcinogenicity. Not
considered a carcinogen or mutagen.
Assessment Carcinogenicity:
ACGIH
Hydrous Aluminum Silicate 1332-58-7 Group A4
NTP
None
IARC
Amorphous silicon dioxide hydrate 112926-00-8
(Amorphous silica)
OSHA
None
Reproductive & Developmental Toxicity: In reproductive and developmental studies in animals, there
was no effect on reproduction. Not considered a reproductive toxicant.

SECTION 12: ECOLOGICAL INFORMATION
Environmental Precautions: This product is toxic to wildlife. This product is toxic to bees exposed to
direct treatment. Do not apply this product while bees are actively visiting the treated area. Do not con-
taminate surface or ground water by cleaning equipment or disposal of wastes, including equipment
washwater.
Ecological Information: For ecotoxicological data call the product information phone number listed in
Section 1.
Environmental Fate: For environmental fate data call the product information phone number listed in
Section 1.

SECTION 13: DISPOSAL CONSIDERATIONS
General Disposal Guidance: Do not contaminate water, food, or feed by storage or disposal.
Contamination with this product will render water, food or feed unfit for human or animal consumption.
Wastes resulting from use of this product may be disposed of on site or at an approved waste disposal
facility.




Document Number: 7010 Issue Date: 07/03
NDA = No Data Available N/A = Not Applicable N/E = Not Established
TRISTARTM 70 WSP - ACETAMIPRID INSECTICIDE Page 6 of 7

Chemical additions, processing or otherwise altering this material may make the waste management
information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. Please be
advised that state and local requirements for waste disposal may be more restrictive or otherwise differ-
ent from federal laws and regulations. Consult state and local regulations regarding the proper disposal
of this material.
Container Disposal: Do not reuse outer bag. Dispose of outer bag in a sanitary landfill or by incineration,
or if allowed by State and local authorities, by burning. If burned, stay out of smoke.

SECTION 14: TRANSPORTATION INFORMATION
Not regulated for transportation per DOT regulations.


SECTION 15: REGULATORY INFORMATION
US Federal
EPA Registration No. 8033-22-1001
TSCA list
Hydrous Aluminum Silicate 1332-58-7
TSCA12b export notification
None
SARA Title III - section 302 - notification and information
None
SARA Title III - section 313 - toxic chemical release reporting
None
US States Regulatory
CA Prop 65
This product noes not contain any substances known to the State of California to cause cancer.

This product does not contain any substances known to the State of California to cause
reproductive harm.
US State right-to-know ingredients
Amorphous silicon dioxide hydrate 112926-00-8 PA
(Amorphous silica)
Hydrous Aluminum Silicate 1332-58-7 IL,PA, RI

Canadian Regulations
Canadian Registrat. No.
Canadian Domestic Substance List
Amorphous silicon dioxide hydrate 112926-00-8
(Amorphous silica)
Hydrous Aluminum Silicate 1332-58-7

Environmental
CERCLA
None
Clean Water Section 307 Priority Pollutants
None
Safe Drinking Water Act Maximum Contaminant Levels
None

International Regulations
EU Classification
None
European Inventory of Existing Commercial Substances (EINECS)
None

Document Number: 7010 Issue Date: 07/03
NDA = No Data Available N/A = Not Applicable N/E = Not Established
TRISTARTM 70 WSP - ACETAMIPRID INSECTICIDE Page 7 of 7

SECTION 16: OTHER INFORMATION

Health Flammability Reactivity Others
HMIS 2 1 0
NFPA 2 1 0

Please note: Cleary Chemical Corp. believes that the information and recommendations contained here-
in are accurate as of the date hereof. The information provided herein applies only to the specific prod-
uct designated and may not be valid where said product is used in combination with any other material
or in any process. It is the user鈥檚 responsibility to determine the suitability of the information for their pur-
poses. No warranty of fitness for any particular purpose, warranty of merchantability, or any other war-
ranty, expressed or implied, is made concerning the information provided.

Reason for issue: Update
Prepared by: R. Fletcher
Effective date: 07/03
Replaces: 06/03
Document number: 7010

TriStar is a trademark of the Nippon Soda Co., Ltd.




CLEARY CHEMICAL CORPORATION
178 Ridge Road,
Dayton, NJ 08810-1501
www.clearychemical.com
EMERGENCY PHONE NUMBERS:
M-F 9AM-5PM EDT
800-524-1662
732-329-8399
24-Hour CHEMTREC
800-424-9300
PROSAR
800-324-7598

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