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MSDS Material Safety Data Sheet
CAS

23564-05-8
36734-19-7

File Name: clearychemical_com---4217M.asp
                                                                                                              Page 1 of 1




MATERIAL SAFETY DATA SHEET

SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

COMPANY ADDRESS: EMERGENCY TELEPHONE NUMBERS:
Cleary Chemical Corp. (800) 424-9300 (CHEMTREC, transportation and spills)
178 Ridge Road (800) 900-4000 (Poison Control Center, human health)
Dayton, NJ 08810 (800) 345-4735 (ASPCA, animal health)
(800) 524-1662

PRODUCT NAME : EMBLEM
CHEMICAL NAME : 3-(3,5-dichlorophenyl)-N-(1-methylethyl)-2,4-dioxo-1-
imidazolidine carboxamide (iprodione)
(dimethyl[1,2-phenylene)-bis(iminocarbonothioyl)]
bis[carbamate]) (thiophanate-methyl)
CHEMICAL FAMILY : Dicarboxamide and Thiollophanate fungicides
PRODUCT CODE : EPA Reg. No. 51036-387-1001

SECTION 2 - COMPOSITION, INFORMATION OF INGREDIENTS

COMPONENT PERCENTAGE CAS NUMBER OSHA PEL ACIGH TLV

Thiophanate-methyl 19.65 23564-05-8 Not listed Not listed

Iprodione 19.65 36734-19-7 Not listed Not listed

SECTION 3 - HAZARDS IDENTIFICATION SUMMARY
(As defined by OSHA Hazard Communication Standard, 29 CFR 1910.1200)

EMERGENCY OVERVIEW: Off white viscous liquid with slight odor.
- May be harmful if swallowed, inhaled or absorbed through skin.
- Causes slight eye irritation.
- Avoid breathing vapor or spray mist.
- Avoid contact with eyes, skin or clothing.
- Keep out of reach of children.
Symptoms of over exposure are nausea, vomiting, abdominal cramps, and loss of coordination.

POTENTIAL HEALTH HAZARDS:
EYE - Moderately irritating to the eyes. Degree of injury will depend on the amount of material that gets into eye and the
speed and thoroughness of the first aid treatment.
SKIN - Prolonged or repeated skin contact may cause irritation.
INHALATION - Slightly irritating to respiratory tract
INGESTATION - May be harmful if swallowed.

SECTION 4 - FIRST AID MEASURES
IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present,
after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes.
Call a poison control center or doctor for treatment advice.
IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water
if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything
by mouth to an unconscious person.

NOTE TO PHYSICIAN: Treat symptomatically. No specific antidote available. Consideration should be given to
overexposure to other products.
Page 2 of 2



SECTION 5 - FIRE FIGHTING MEASURES
FLASHPOINT (method): > 93 C (165 F) (TCC)
FLAMMABLE LIMITS (LFL-UFL): Unknown.
FIRE A ND EXPLOSION HAZARD: Can burn in fire, releasing irritating and toxic gases due to thermal decomposition or
combustion.
EXTINGUISHING MEDIA: Use foam, dry chemical, carbon dioxide, or water spray when fighting fires involving this material.
FIRE FIGHTING INSTRUCTIONS: Evacuate area and fight fire upwind from a safe distance to avoid hazardous vapors and
decomposition products. Dike and collect water used to fight fire to prevent environmental damage due to run off. Foam or
dry chemical fire extinguishing systems are preferred to prevent environmental damage from excessive water run off.
FIRE FIGHTING EQUIPMENT: Full fire fighting turn-out gear (Bunker gear).
HAZARDOUS COMBUSTION PRODUCTS: Oxides of nitrogen and carbon.

SECTION 6 - ACCIDENTAL RELEASE MEASURES
Clean up spills immediately, observing precautions in Section 8 of this document.
Isolate hazard area. Keep unnecessary and unprotected personnel from entering.

SMALL SPILL: Absorb small spills on sand, vermiculite or other inert absorbent. Place contaminated material in
appropriate container for disposal.
LARGE SPILL: Dike large spills using absorbent or impervious material such as clay or sand. Recover and contain as much
free liquid as possible for reuse. Allow absorbed material to solidify, and scrape up for disposal. Pick up wash liquid with
additional absorbent and place in a disposable container. After removal, flush contaminated area thoroughly with water. This
material should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water.

SECTION 7 - HANDLING AND STORAGE
KEEP OUT OF REACH OF CHILDREN!
HANDLING: Use only in a well-ventilated area. Do not reuse this container.
STORAGE: Keep away from food, feed and drinking water.

SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
EXPOSURE LIMITS (8 HOUR TWA): (Refer to Section 3)
ENGINEERING CONTROLS: Proper ventilation is required when handling or using this product to keep exposure to airborne
contaminants below the exposure limit. Facilities storing or utilizing this material should be equipped with an eyewash facility
and a safety shower.

PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION - Safety glasses with side shields.
CLOTHING - Long-sleeved shirt and long pants, Shoes plus socks, Chemical resistant apron when cleaning equipment,
mixing, or loading.
GLOVES - Chemical-resistant gloves, such as barrier laminate, butyl rubber, nitrile rubber, neoprene rubber, polyvinyl
chloride (PVC), viton
RESPIRATOR 鈥? When handling in enclosed areas where exposure limits may be exceeded, use a NIOSH approved
respirator with any N, R, P or HE filter.

Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's
concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning and maintaining PPE. If no such
instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry.
USER SAFETY RECOMMENDATIONS:
鈥? Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet.
鈥? Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing.
鈥? Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as
possible, wash thoroughly and change into clean clothing.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL DESCRIPTION: Off-white viscous liquid.
ODOR: Slight.
Molecular Weight (Iprodione): 330.17
Molecular Formula (Iprodione): C13H13Cl2N3O3
Molecular Weight (Thiophanate Methyl: 342.4
Molecular Formula (Thiophanate Methyl): C12H14N4O4S2
DENSITY: 1.145 g/l (9.55 lbs./gl)
Page 3 of 3


pH: 5.5 - 6.0
VAPOR PRESSURE: Unknown.
% VOLATILE: < 5%.
WATER SOLUBILITY: Dispersible.

SECTION 10 - STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable, however may decompose if heated.
CONDITIONS TO AVOID: Avoid temperatures above 150掳F and below 20掳F.
INCOMPATIBILITY WITH OTHER MATERIALS: Alkaline and acidic conditions, Oxidizing materials, and some copper
compounds.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of nitrogen, and carbon.
HAZARDOUS POLYMERIZATION: Product will not undergo polymerization.

SECTION 11 - TOXICOLOGICAL INFORMATION
ACUTE TOXICITY for Thiophanate Methyl:
Oral LD50 (rat) - > 5,000 mg/Kg
Dermal LD50 (rat) - > 2,000 mg/Kg
Inhalation LC50 (rat) - > 1.8 mg/L/4 hour
Eye Irritation (rabbit) - Slight
Skin Irritation (rabbit) - Slight
Sensitization (guinea pig) - Non-sensitizer

ACUTE TOXICITY for Iprodione:
Oral LD50 (rat) - > 2,000 mg/Kg
Dermal LD50 (rat) - > 1,000 mg/Kg
Inhalation LC50 (rat) - > 3.5 mg/L/4 hour
Eye Irritation (rabbit) - Slight
Skin Irritation (rabbit) - Slight
Sensitization (guinea pig) - Non-sensitizer

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Inhalation may aggravate existing tendency to respiratory or
bronchial infections and existing skin sensitivities.

CARCINOGEN STATUS:
OSHA - Not listed.
NTP - Not listed.
IARC - Not listed.

MUTAGENIC DATA: No evidence of effects during in vivo or in vitro studies.

SECTION 12 - ECOLOGICAL INFORMATION
ENVIRONMENTAL SUMMARY: This product is toxic to fish and invertebrates. Do not apply directly to water, or to areas
where surface water is present or to intertidal areas below the mean high water mark. Drift and runoff from treated areas may
be hazardous to fish in adjacent areas. Do not contaminate water when disposing of equipment washwaters.

Fish Toxicity for Thiophanate Methyl (Technical):
96 hour LC50, Rainbow trout 鈥? 7.8 ug/L


Avian Toxicity for Thiophanate Methyl (Technical):
Oral LD50, Bobwhite Quail - >5,000 mg/kg

Fish Toxicity for Iprodione (Technical):
96 hour LC50, Rainbow trout 鈥? 6.7 ug/L
96 hour LC50, Bluegill 鈥? 2.2 ug/L

Avian Toxicity for Iprodione (Technical):
Oral LD50, Bobwhite Quail - 930 mg/kg

BEE TOXICITY: Non-toxic to bees.
Page 4 of 4


SECTION 13 - DISPOSAL CONSIDERATIONS

WASTE: Pesticide wastes are toxic/acutely hazardous. Dispose of in accordance with applicable Federal, state and local
laws and regulations.

CONTAINER: Triple rinse (or equivalent). Then offer for recycling or reconditioning or puncture and dispose of in a sanitary
landfill or by incineration, or if allowed by state and local authorities, by burning. If burned, stay out of smoke.

SECTION 14 - TRANSPORT INFORMATION
DOT SHIPPING DESCRIPTION: Agricultural Fungicide, Liquid, N.O.I.B.N.
DOT HAZARD CLASS: N/A
UN NUMBER: N/A
DOT PACKING GROUP: N/A
DOT PRIMARY/SECONDARY LABEL: N/A
DOT PRIMARY/SECONDARY PLACARD: N/A
DOT EMERGENCY RESPONSE GUIDE #: N/A

SECTION 15 - REGULATORY INFORMATION
FIFRA: All pesticides are governed under the Federal Insecticide, Fungicide, and Rodenticide Act. The regulatory
information presented below is pertinent only when this product is handled outside of the normal use and application as a
pesticide.

OSHA HAZARD COMMUNICATION STANDARD STATUS: Regulated
CERCLA REPORTABLE QUANTITY: N/A
SARA TITLE III STATUS:
302 Extremely Hazardous Substance - No
311/312 Hazard Categories - Yes, Immediate, Delayed
313 Toxic Chemicals - Thiophanate Methyl (CAS # 23564-05-8)

CALIFORNIA PROP 65 STATUS: Listed (cancer), Developmental toxin.

SECTION 16 - OTHER INFORMATION
DISCLAIMER: The information presented herein is based on available data from reliable sources and is correct to the best of
Cleary Chemical Corporations knowledge. Cleary makes no warranty, express or implied, regarding the accuracy of the data
or the results obtained from the use of this product. Nothing herein may be construed as recommending any practice or any
product in violation of any law or regulations. The user is solely responsible for determining the suitability of any material or
product for a specific purpose and for adopting any appropriate safety precautions. We disclaim all liability for injury or
damage stemming from any improper use of the material or product described herein.

REVISION DATE: Sept 23, 2004
REPLACES: July 19, 2004
REVISED FOR: Cleary Sub-registration

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