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MSDS Material Safety Data Sheet
CAS

13977-65-6
13492-26-7

File Name: clearychemical_com---4420M.asp
                        MATERIAL SAFETY DATA SHEET
ALUDETM Page 1 of 3

Please read the entire document. This Material Safety Data Sheet contains important environmental,
health and toxicology information for your employees, and anyone who will use, transport, store,
dispose of or handle this product. Please make sure this information is given to them. It also contains
information to help you meet community right-to-know/emergency response reporting requirements
under SARA Title III and many other laws. If you resell this product, this MSDS must be given to the
buyer or the information contained herein must be incorporated in your MSDS.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ALUDE Systemic Fungicide
CLEARY PRODUCT CODE: 4420
EPA REGISTRATION NUMBER(S): 71962-1-1001
CHEMICAL NAME: Mono- and di-potassium salts of Phosphorous Acid

EMERGENCY TELEPHONE NUMBERS
COMPANY
CLEARY CHEMICAL CORP. PROSAR:
Cleary Chemical M-F 9-5 EST (800) 324-7598
178 Ridge Road, Suite A (800) 524-1662 OR CHEMTREC 24 HOUR:
Dayton, New Jersey 08810 (732) 329-8399 (800) 424-9300


SECTION 2: INFORMATION ON INGREDIENTS

Active Ingredient(s)/ % by Wt. CAS# ACGIH OSHA
Hazardous Inert Ingredient(s) TLV PEL

Monopotassium phosphite 13977-65-6 NA NA
and Dipotassium phosphite 45.8 13492-26-7 NA NA

NOT CLASSIFIED AS HAZARDOUS

SECTION 3: HEALTH HAZARD INFORMATION

Acute Health Hazards
Swallowed: Ingestions may cause diarrhea, nausea, vomiting and cramps
Eye: A mild irritant to eyes
Skin: Mildly irritating to skin
Inhaled: Nil
NFPA: Health=0, Fire=0, Reactivity=0
HMIS: Health=0, Fire=0, Reactivity=0




Document Number: 4420 Issue Date: 04/03
NDA = No Data Available NA = Not Applicable
ALUDETM Page 2 of 3

SECTION 4: FIRST AID MEASURES

Swallowed: Call a poison control center immediately for treatment advice. Have person sip a glass of
water if able to swallow. Do not induce vomiting unless told to do so by medical professionals. Do not
give anything by mouth to an unconscious person.
Eye: Hold eyelids open and rinse with plenty of water for at lease 15-20 minutes. Remove contact lens-
es, if present, after first 5 minutes, then continue rinsing. Contact a Doctor or poison control center for
further treatment advice.
Skin: Rinse with plenty of water for 15 minutes. Contact a Doctor or poison control center for further
treatment advice.

SECTION 5: FIRE AND EXPLOSION INFORMATION

Flammability: Not flammable
Combustion: Not combustible
Flash Point & Method: NA
Flammability Limits: NA
Special Fire Fighting Procedures: Some gases such as phosphorous oxides may be released. In
smoke or fumes, wear self-contained breathing apparatus. Advise fire brigade of any hazard, suitable for
more extinguishing media.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Spill or Leak Procedures: Stop leak if possible. Contain product with an inert diking material such as
clay or kitty litter. Reclaim as much liquid as possible. Vacuum or shovel up as much absorbent as pos-
sible. Place reclaimed product in a closed and properly labeled waste drum. Store drum until proper dis-
posal can occur. Flush residue with water. Wash thoroughly after handling.

SECTION 7: HANDLING AND STORAGE

Store away from combustible materials. Store in a temperature controlled, dry place.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Avoid unnecessary contact with product and remove all contaminated clothing. Wash hands and face
before eating. Pesticide Applicators, Mixers, and Loaders must refer to the product label and directions
for use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker
Protection Standard 40 CFR part 170.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Blue, odorless liquid
Boiling Point: > 212掳F
Vapor Pressure: Not determined
pH: 5.5-6.0
Melting Point: NA
Freezing Point: > 8掳F
Specific Gravity: 1.35




Document Number: 4420 Issue Date: 04/03
NDA = No Data Available NA = Not Applicable
ALUDETM Page 3 of 3


SECTION 10: STABILITY AND REACTIVITY

General: This material is stable under normal conditions.
Incompatible Materials: Avoid contact with strong bases, strong oxidizing agents and metals. Product
is corrosive to most.
Hazardous Decomposition: Some gases such as phosphorous oxides may be released.
Hazardous Polymerization: Material is not known to polymerize.

SECTION 11: TOXICOLOGICAL INFORMATION
EPA Class 4, Caution
Acute Inhalation: Not determined
Eye Irritation: Mild eye irritant
Skin Irritation: Mild skin irritant
Acute Dermal: > 5000 mg/Kg (rat)
Acute Oral: > 5000 mg/Kg (rat)

SECTION 12: ECOLOGICAL INFORMATION
Not classified as Hazardous

SECTION 13: DISPOSAL CONSIDERATIONS
Triple rinse empty container with water and add to spray mix. Dispose of container following appropriate
Federal, State and local regulations.

SECTION 14: TRANSPORTATION INFORMATION
Not DOT regulated

SECTION 15: REGULATORY INFORMATION

Not regulated under US EPA SARA Title 3, Sec. 302, 311, 312, or 313
Not Regulated under California Prop 65

SECTION 16: OTHER INFORMATION

Please note: Cleary Chemical Corp. believes that the information and recommendations contained here-
in are accurate as of the date hereof. The information provided herein applies only to the specific prod-
uct designated and may not be valid where said product is used in combination with any other material
or in any process. It is the users responsibility to determine the suitability of the information for their pur-
poses. No warranty of fitness for any particular purpose, warranty of merchantability, or any other war-
ranty, expresser or implied, is made concerning the information provid

Reason for issue: New MSDS (New EPA Registration Number)
Prepared by: R. Fletcher
Effective date: 04/03
Replaces: NA
Document number: 4420




Document Number: 4420 Issue Date: 04/03
NDA = No Data Available NA = Not Applicable

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