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MSDS Material Safety Data Sheet
CAS

23564-05-8

File Name: clearychemical_com---4162M.asp
                          MATERIAL SAFETY DATA SHEET
3336庐 GC Page 1 of 4
Please read the entire document. This Material Safety Data Sheet contains important environmental,
health and toxicology information for your employees, and anyone who will use, transport, store,
dispose of or handle this product. Please make sure this information is given to them. It also contains
information to help you meet community right-to-know/emergency response reporting requirements
under SARA Title III and many other laws. If you resell this product, this MSDS must be given to the
buyer or the information contained herein must be incorporated in your MSDS.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3336 GC
EPA REGISTRATION NUMBER(S): 1001-70
CHEMICAL NAME: Dimethyl-4-4麓-o-phenylenebis-3-thioallophanate
SYNONYM: Thiophanate methyl
GENERAL USE: Turf and ornamental fungicide
FRAC GROUP CODE: 1

EMERGENCY TELEPHONE NUMBERS
COMPANY
CLEARY CHEMICAL CORP. PROSAR:
Cleary Chemical Corporation M-F 9-5 EST (800) 324-7598
178 Ridge Road, Suite A (800) 524-1662 OR CHEMTREC 24 HOUR:
Dayton, New Jersey 08810 (732) 329-8399 (800) 424-9300


SECTION 2: INFORMATION ON INGREDIENTS

Active Ingredient(s)/ % by Wt. CAS# ACGIH OSHA
Hazardous Inert Ingredient(s) TLV PEL

Dimethyl-4-4麓-o-phenylenebis- 2.08 23564-05-8 NDA NDA
3-thioallophanate


SECTION 3: HEALTH HAZARD INFORMATION
Acute Health Hazards
Harmful if swallowed, absorbed through the skin or inhaled. Causes moderate eye irritation. Avoid contact
with skin, eyes or clothing. Avoid breathing dust or spray mist. Wash thoroughly with soap and water after
handling.

SECTION 4: FIRST AID MEASURES
If Inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give
artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for
further treatment advice.
If On Skin Or Clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for
15-20 minutes. Call a poison control center or doctor for further treatment advice.
If In Eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses,
if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for
continued on page 2
further treatment advice.

Effective Date: 3.01.06
NDA = No Data Available NA = Not Applicable
3336庐 GC Page 2 of 4

SECTION 4: FIRST AID MEASURES (continued from page 1)

If Swallowed: Call poison control center or doctor immediately for treatment advice. Have person sip a
glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center
or doctor. Do not give anything by mouth to an unconscious person.

Have the product container or label with you when calling a poison control center or doctor, or when going
for treatment. For 24-Hour Emergency Assistance Call Chemtrec 1-800-424-9300.

SECTION 5: FIRE AND EXPLOSION INFORMATION

Flash Point (Method): NA
Flammable Limits (vol % in air): NA
Autoignition Temperature: NA
Extinguishing Media: Carbon dioxide, foam, water, earth, dry chemical.
Special Fire Fighting Procedures: Self-contained breathing apparatus.
Unusual Fire and Explosion Hazards: None

SECTION 6: ACCIDENTAL RELEASE MEASURES

Steps to be Taken in Case Material is Released or Spilled: Sweep or scoop up and remove, flush area
with water. Dispose of in compliance with all federal, state and local laws.

SECTION 7: HANDLING AND STORAGE

Precautions to be Taken in Handling and Storing: Store in original sealed containers in a cool dry
area not accessible to children or unauthorized persons.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Protective Clothing: Long sleeve shirt, long pants, or coveralls, shoes with socks.
Eye Protection: Chemical goggles or safety glasses with side shields recommended.
Ventilation: Use product outdoors or in a well ventilated area.
Respiratory Protection: For exposures in enclosed areas: dusk mask or OSHA approved respirator.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance: light tan granule
Boiling Point: NA
Vapor Pressure (@25掳 C): NA
Melting Point: 181.5 - 182.5掳 C
Freezing Point: NA
Bulk Density: 30 lb/cu.ft.
Solubility in Water: Insoluble (dispersible)
% VOC: Zero




Effective Date: 3.01.06
NDA = No Data Available NA = Not Applicable
3336庐 GC Page 3 of 4

SECTION 10: STABILITY AND REACTIVITY
Stability: Stable
Incompatible Materials: Highly alkaline materials, oxidizing agents, lime sulfur, bordeux mixture, cop-
per compounds.
Conditions to Avoid: Extreme heat
Hazardous Decomposition: Thermal decomposition generates oxides of nitrogen, sulfur, and carbon.
Hazardous Polymerization: NA

SECTION 11: TOXICOLOGICAL INFORMATION

Oral (Acute) LD50: > 7,500 mg/kg (male rat); 6,640 mg/kg (female rat)
Dermal (Acute) LD50: > 10,000 mg/kg (rabbit)
Inhalation (acute): > 20.8 mg/L (LC50 rat 4 hour)
Chronic (oral): No oncogenicity, no observed effect level, 160 ppm in diet for two years (rat) and 50
mg/kg/day in single dose for two years (dog).
NOEL:
Subchronic (oral): No observable effect level, 1,600 ppm in diet for 180 days (rats and mice).
Neurotoxicity: No delayed neurotoxicity or cholinesterase inhibition.
Oncogenicity: No oncogenicity to mice consuming diets containing levels as high as 640 ppm over a
two year period.
Teratogenicity: No teratology to rats or mice dosed throughout pregnancy with levels as high as 1,000
mg/kg/day.
Reproductive Toxicity: No effect on spermatogenesis, testosterone assimilation. Three generation
study showed no evidence of effects on fertility, fecundity or offspring.
Mutagenicity: Ames, Mammalian Somatic, Cytogenicity, Dominant Lethal, DNA Damage/Repair, all
test negative.

SECTION 12: ECOLOGICAL INFORMATION
This pesticide is toxic to fish. Do not apply directly to water, or to areas where surface water is present,
or to intertidal areas below the mean high water mark. Do not contaminate water by disposal of equip-
ment washwaters. Do not apply, allow to drift, or drain or flush equipment onto non-target areas.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Methods: Improper disposal of excess pesticide, spray mixture or rinsate is a violation
of federal law. If these wastes cannot be disposed of by intended use according to label instructions,
contact the appropriate agency in your state or the nearest EPA Regional Office for guidance.

SECTION 14: TRANSPORTATION INFORMATION

DOT Shipping Description: Fungicide, Agricultural, Solid NOI
DOT Hazard Classification: Not DOT regulated
UN Identification Number: NA
OSHA Hazard Classification: NA
Reportable Quantity: NA
Hazardous Substance: NA
DOT Label Requirements: NA




Effective Date: 3.01.06
NDA = No Data Available NA = Not Applicable
3336庐 GC Page 4 of 4

SECTION 15: REGULATORY INFORMATION
EPA SARA Title III Data: Positive rating for acute hazard
Section 302 Substances: NA
RCRA Waste Number: U409
Section 311/312 Hazardous Categories: NA
Hazard Categories Under Criteria of SARA Title III Rules (40 CFR Part 370)
Immediate Health: Yes
Delayed Health: Yes
Fire: No
Reactive: No
Sudden Pressure: No
Section 313 Toxic Chemicals: This product does contain chemical(s) which are defined as toxic
chemicals under and subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. Thiophanate Methyl
CERCLA RQ: 1 lb.
California Prop 65: Developmental Toxins
This product does contain the following chemical as indicated below, currently on the California list
of Developmental Toxins.
Thiophanate methyl
NFPA Ratings: Flamability: 0 Reactivity: 0 Health: 1

SECTION 16: OTHER INFORMATION

Please note: Cleary Chemical Corp. believes that the information and recommendations contained here-
in are accurate as of the date hereof. The information provided herein applies only to the specific prod-
uct designated and may not be valid where said product is used in combination with any other material
or in any process. It is the users responsibility to determine the suitability of the information for their pur-
poses. No warranty of fitness for any particular purpose, warranty of merchantability, or any other war-
ranty, expressed or implied, is made concerning the information provided.

Reason for issue: update
Prepared by: Rick Fletcher
Effective date: 3.01.06
Replaces: 1/00

Copyright 漏 2006 Cleary Chemical Corporation
3336庐 is a registered trademark of Cleary Chemical Corporation




2M3/06
Effective Date: 3.01.06
NDA = No Data Available NA = Not Applicable

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