MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
TRADE NAME (AS LABELED): NUTRI-GROW MAGNUM
CHEMICAL NAME/CLASS: Inorganic Salt Mixture
PRODUCT NUMBER: 2-40-16
PRODUCT USE: Fertilizer
MANUFACTURER'S NAME BIAGRO WESTERN SALES, INC.
ADDRESS: 35803 Road 132
Visalia, CA 93292
EMERGENCY PHONE: CHEMTREC: 1-800-424-9300
BUSINESS PHONE: (559) 635-4784
FAX PHONE: (559) 625-9255
DATE OF PREPARATION: October 23, 2001
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL OTHER
TWA STEL TWA STEL IDLH
3 3 3 3 3 3
mg/m mg/m mg/m mg/m mg/m mg/m
Ammonium Compounds Proprietary >1 NE NE NE NE NE NE
Organic Acid Proprietary >1 NE NE NE NE NE NE
Potassium Compounds Proprietary >1 NE NE NE NE NE NE
Potassium Citrate Compound Proprietary >1 NE NE NE NE NE NE
Water and other components. Each of the Balance None of the other components contribute significant, additional, hazards at the
other components are present in less than 1 concentrations present in this product. All pertinent hazard information has been provided
percent concentration (or 0.1% concentration in this document, per the requirements of the Federal Occupational Safety and Health
for potential carcinogens, reproductive toxins, Administration Standard (29 CFR 1910.1200), U.S. State equivalent Standards and
respiratory tract sensitizers, and mutagens). Canadian Workplace Hazardous Materials Identification System Standards (CPR 4).
NE = Not Established See Section 16 for Definitions of Terms Used
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format.
NOTE (2): Phosphorous Acid, Ammonium Hydroxide, and Potassium Hydroxide are part of the formulation for this solution; however, they are added to
adjust the pH and do not contribute any significant, additional hazards to this product. Subsequently, these compounds are not considered further in this
document.
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This is a water-clear, solution with a no appreciable odor. This product presents a slight
health hazard (in terms of irritation of contaminated skin, eyes, or mucous membranes). This product presents no
significant flammability or reactivity hazards. Emergency responders must wear the personal protective equipment suitable
for the situation to which they are respond
NUTRI-GROW MAGNUM (2-40-16) [PROPRIETARY] MSDS
PAGE 1 OF 8
3. HAZARD IDENTIFICATION (Continued)
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
chief routes of overexposure to this product are inhalation of mists or sprays
generated by the product and contact with skin or eyes. The symptoms of
overexposure, via route of entry, are as follows:
HEALTH (BLUE) 1
INHALATION: Inhalation of sprays, aerosols, or mists of this solution may
irritate the nose, throat, and exposed mucous membranes. Symptoms of
such exposure may include coughing, sneezing, and sore throat.
Symptoms are generally alleviated when overexposure ends.
FLAMMABILITY (RED) 0
CONTACT WITH SKIN or EYES: Contact with skin may irritate and redden
exposed tissue. The Organic Acid component of this solution is a potential
allergen. Prolonged or repeated skin contact can cause allergy-like
symptoms (e.g., dermatitis). Contact with eyes will cause tearing, pain,
REACTIVITY (YELLOW) 0
reddening, and irritation.
SKIN ABSORPTION: Skin absorption is not anticipated to be a significant
route of exposure to any component of this product.
PROTECTIVE EQUIPMENT D
INGESTION: Though not a likely route of occupational exposure, ingestion
may irritate the throat, esophagus, and other tissues of the digestive
system. Symptoms of such exposure would include coughing, nausea, EYES HANDS BODY
RESPIRATORY
vomiting, and diarrhea.
INJECTION: Injection of this product, via puncture with a contaminated SEE SECTION 8 SEE SECTION 8
object, may cause a burning sensation, reddening, and swelling around the
site of injection.
For routine fertilizer applications.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay
Terms.
See Section 16 for Definition of Ratings
ACUTE: Symptoms of short-term exposures would include pain, reddening,
and irritation of exposed tissue. Severe inhalation or ingestion overexposure may be harmful.
CHRONIC: Prolonged or repeated skin contact may cause dermatitis and other allergy-like skin reactions. Refer to Section
11 (Toxicology Information) for further information on the components of this solution.
TARGET ORGANS: ACUTE: Skin and eyes. CHRONIC: Skin
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Contaminated individuals must be taken for medical attention if any adverse reaction occurs. Rescuers should be taken for
medical attention, if necessary. Take a copy of the label and MSDS to physician or health professional with victim.
SKIN EXPOSURE: If the product contaminates the skin, decontaminate the affected area with running water. The minimum
recommended flushing time is 15 minutes, especially if adverse skin reactions occur. If necessary, remove exposed or
contaminated clothing, taking care not to contaminate eyes.
EYE EXPOSURE: If this product enters the eyes, open the contaminated individual's eyes while under gently running water.
Use sufficient force to open eyelids. Have the contaminated individual "roll" eyes. Minimum flushing is for 15 minutes.
INHALATION: If mists or sprays of this product are inhaled, remove the contaminated individual to fresh air. If necessary,
use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers.
INGESTION EXPOSURE: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST
CURRENT INFORMATION. DO NOT INDUCE VOMITING. Rinse mouth with water immediately, if victim is conscious.
Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or unable to
swallow. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an
open airway and prevent aspiration. If contaminated individual is convulsing, maintain an open airway and obtain immediate
medical attention.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Preexisting respiratory problems, dermatitis, and other skin
disorders can be aggravated by exposure to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure.
NUTRI-GROW MAGNUM (2-40-16) [PROPRIETARY] MSDS
PAGE 2 OF 8
5. FIRE-FIGHTING MEASURES
FLASH POINT: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
NFPA RATING
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable. FLAMMABILITY
Upper (UEL): Not applicable.
FIRE EXTINGUISHING MATERIALS:
0
Water Spray: YES Carbon Dioxide: YES
Foam: YES Dry Chemical: YES
1 0
HEALTH REACTIVITY
Halon: YES Other: Any "ABC" Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: When involved in a fire and
exposed to extremely high temperatures, the components of this product will
decompose to produce irritating vapors and toxic gases (e.g., phosphorous
oxides, phosphine, carbon oxides, and ammonia). OTHER
See Section 16 for
Explosion Sensitivity to Mechanical Impact: Not applicable.
Definition of Ratings
Explosion Sensitivity to Static Discharge: Not applicable.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters
must wear Self-Contained Breathing Apparatus and full protective equipment. If possible, prevent runoff water from entering
storm drains, bodies of water, or other environmentally sensitive areas.
6. ACCIDENTAL RELEASE MEASURES
RELEASE RESPONSE: In case of a release, clear the affected area and protect people. Uncontrolled releases should be
responded to by appropriately trained personnel in proper personal protective equipment, using pre-planned procedures. In
terms of small, incidental releases (e.g., 1 gallon from a leaking container), the minimum personal protective equipment
should be as follows: gloves, goggles, and appropriate body protection (e.g., boots, Tyvek suit). For large releases (e.g.,
55-gallon drum), the minimum personal protective equipment should be Level C: triple-gloves (rubber gloves and nitrile
gloves over latex gloves), chemical resistant suit and boots, hardhat, and an Air-Purifying respirator with a high-efficiency
particulate filter. In the event of a spill in which excessive amounts of mists are generated or one in which the level of
oxygen is below 19.5% or is unknown, the minimum equipment should be Level B: triple-gloves (rubber gloves and nitrile
gloves over latex gloves), chemical resistant suit and boots, hard hat, and Self-Contained Breathing Apparatus. If
necessary, dike the spill to prevent releases from contaminating environmentally sensitive areas. Absorb spilled liquid
with polypads or other suitable absorbent materials. Rinse area thoroughly with water. Decontaminate the area
thoroughly. Place all spill residue in an appropriate container and seal. Reuse this product or dispose of in accordance
U.S. Federal, State, or local procedures and appropriate Canadian standards (see Section 13, Disposal Considerations).
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid
breathing vapors or mists generated by this product. Use in a well-ventilated location. Remove contaminated clothing
immediately.
STORAGE AND HANDLING PRACTICES -- NON-BULK CONTAINERS: All employees who handle this material should be
trained to handle it safely. Open containers and drums slowly on a stable surface. Open drum bunks carefully to relieve any
pressure build-up, which may have developed during storage. All containers of this product must be properly labeled. Empty
containers may contain residual amounts of this product; therefore, empty containers should be handled with care. Store
containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store
away from incompatible materials (see Section 10, Stability and Reactivity). Material should be stored in secondary
containers or in a diked area, as appropriate. Keep container tightly closed when not in use. Inspect all incoming containers
before storage to ensure that containers are properly labeled and are not damaged.
STORAGE AND HANDLING PRACTICES -- BULK CONTAINERS: Bulk containers (e.g., 250 gallon "mini-bulk" tanks)
holding this product should be loaded and unloaded in strict accordance with container manufacturer鈥檚 recommendation and
all established on-site safety procedures. Appropriate personal protective equipment must be used (see Section 8,
Engineering Controls and Personal Protection). All transfer and dilution equipment must be inspected prior to each use.
Transfer and dilution operations must be attended at all times. Hoses must be verified to be clean and free of incompatible
chemicals prior to connection to the tank. Valves and hoses must be verified to be in the correct positions prior to starting
transfer and dilution operations.
NUTRI-GROW MAGNUM (2-40-16) [PROPRIETARY] MSDS
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7. HANDLING and STORAGE (Continued)
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely, if
necessary. Collect all rinsates and dispose of in accordance U.S. Federal, State, or local procedures and appropriate
Canadian standards (see Section 13, Disposal Considerations).
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to prevent inhalation of sprays or mists.
All operations should be directed at minimizing the generation of aerosols, sprays, or mists. Eyewash stations/safety
showers should be near areas where this product is used or sprayed.
RESPIRATORY PROTECTION: None required under normal circumstances of use. If operations generate aerosols, mists,
or sprays which cause exposures in excess of the guidelines listed in Section 2 (Composition and Information on
Ingredients), respiratory protection may be needed (e.g., air-purifying respirator with a high efficiency particulate filter) and
must comply with the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the appropriate
standards of Canada and its Provinces. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres,
use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air
supply is required under OSHA鈥檚 Respiratory Protection Standard (1910.134-1998).
EYE PROTECTION: Splash goggles or safety glasses. Wear face shield for operations involving more than 5 gallons of this
solution in which splashes or sprays can be generated.
HAND PROTECTION: Wear Neoprene gloves for routine industrial use. Use triple gloves for spill response, as stated in
Section 6 (Accidental Release Measures) of this MSDS.
BODY PROTECTION: Use body protection appropriate for task (e.g., coveralls, or rubber apron).
9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): Not established. EVAPORATION RATE (n-BuAc = 1): Not established.
DENSITY: 13.7 lb/gal MELTING/FREEZING POINT: Not established.
SOLUBILITY IN WATER: Completely soluble. BOILING POINT: Not established.
VAPOR PRESSURE, mm Hg @ 20掳C (68掳F): Not established. pH: 6.5
ODOR THRESHOLD: Not established.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not available.
APPEARANCE AND COLOR: This is a clear, colorless, solution with no appreciable odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance and odor may act as distinguishing
characteristics of this product.
10. STABILITY and REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: When exposed to extremely high temperatures, the components of this product will
decompose to produce irritating vapors and toxic gases (e.g., phosphorous oxides, phosphine, carbon oxides, and
ammonia).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong bases, strong oxidizers, strong reducers, and water-
reactive materials.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Exposure to extreme temperatures and incompatible materials.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The specific toxicology data available for components greater than 1% in concentration are as follows.
AMMONIUM COMPOUND 1: ORGANIC ACID: ORGANIC ACID (continued):
LCLo (inhalation, rat) = 580 ppm/1 hour Skin Irritancy (rabbit) = 500 mg/24 hours; LD50 (oral, rat) = 3 g/kg
LCLo (inhalation, guinea pig) = 288 ppm/2 hours moderate LD50 (intraperitoneal, rat) = 883 mg/kg
Skin Irritancy (rabbit) = 500 mg/24 hours; mild LD50 (intraperitoneal, rat) = 290 mg/kg
AMMONIUM COMPOUND 2:
Eye Irritancy (rabbit) = 750 碌g/24 hours; severe LD50 (subcutaneous, rat) = 5500 mg/kg
There are currently no toxicology data available
Eye Irritancy (rabbit) = 750 mg/24 hours; severe LD50 (oral, mouse) = 5040 mg/kg
for this compound.
LD50 (intraperitoneal, mouse) = 903 mg/kg
LD50 (subcutaneous, mouse) = 2700 mg/kg
NUTRI-GROW MAGNUM (2-40-16) [PROPRIETARY] MSDS
PAGE 4 OF 8
11. TOXICOLOGICAL INFORMATION (Continued)
TOXICITY DATA (continued):
ORGANIC ACID (continued):
LD50 (intravenous, mouse) = 42 mg/kg; Behavioral: convulsions or effect on seizure threshold, Lungs, Thorax, or Respiration: cyanosis, Gastrointestinal:
changes in structure or function of salivary glands
LDLo (oral, rabbit) = 7000 mg/kg; Behavioral; tremor, convulsions or effect on seizure threshold, muscle contraction or spasticity
LD50 (intravenous, rabbit) = 330 mg/kg; Behavioral: convulsions or effect on seizure threshold, Lungs, Thorax, or Respiration: cyanosis, Gastrointestinal:
changes in structure or function of salivary glands
POTASSIUM COMPOUND 1:
There are currently no toxicology data available for this compound.
PHOSPHITE COMPOUND 2:
There are currently no toxicology data available for this compound.
PHOSPHITE SALT COMPOUND 1:
There are currently no toxicology data available for this compound.
PHOSPHITE COMPOUND 2:
There are currently no toxicology data available for this compound.
POTASSIUM CITRATE COMPOUND:
There are currently no toxicology data available for this compound.
SUSPECTED CANCER AGENT: The components of this product are not found on the following lists: U.S. FEDERAL OSHA
Z LIST, NTP, IARC, and CAL/OSHA and therefore are neither considered to be nor suspected to be cancer-causing agents
by these agencies
IRRITANCY OF PRODUCT: This product may irritate contaminated tissue upon prolonged or repeated exposure.
SENSITIZATION TO THE PRODUCT: The Organic Acid component of this product is a potential skin sensitizer. Prolonged
or repeated skin contact can cause allergy-like skin reactions (e.g., dermatitis, rashes).
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its
components on the human reproductive system.
Mutagenicity: Human mutation data are available for the Triol Alcohol component of this product; these data were
obtained during clinical studies on specific human tissues exposed to high doses of this compound.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans. Clinical studies on test
animals exposed to relatively high doses of the Triol Alcohol component of this product provided reproductive toxicity data.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first
eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a
chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A
reproductive toxin is any substance which interferes in any way with the reproductive process.
ACGIH BIOLOGICAL EXPOSURE INDICES: Currently, there are no ACGIH Biological Exposure Indices (BEIs) determined
for the components of this product.
12. ECOLOGICAL INFORMATION
WORK PRACTICES MUST PREVENT UNINTENTIONAL, ENVIRONMENTAL RELEASES.
ENVIRONMENTAL STABILITY: The components of this solution are relatively stable, but will decompose over time to
generate other inorganic compounds. The following environmental data are available for the components of this product:
ORGANIC ACID:
Water Solubility = 59.2% (20掳C); 84% (100掳C)
Biological Oxygen Demand (BOD): 40%, 5 days; 60%, 10-20 days.
Food Chain Concentration Potential: Very Low
Experimental Log P = -1.64
Persistence: Can ferment on standing. Biodegrades quite rapidly. It is dangerous to aquatic life in high concentrations. Lowers pH in water but does not
dissociate to any great extent.
NUTRI-GROW MAGNUM (2-40-16) [PROPRIETARY] MSDS
PAGE 5 OF 8
12. ECOLOGICAL INFORMATION (Continued)
ENVIRONMENTAL STABILITY (continued):
TRIOL ALCOHOL:
Water Solubility = Miscible.
Log Kow = -1.76.
5-Day Biological Oxygen Demand = 0.54 p/p; 10 day BOD = 0.98 p/p; 20 Day BOD = 1.0 p/p:
Terrestrial Fate: If released to soil, this compound is expected to undergo rapid biodegradation under aerobic conditions. Biodegradation is also expected
under anaerobic condition. Based on its Log Kow of -1.76 and its water solubility, the soil absorption coefficients for this compound can be estimated at 3
and 2, respectively, using regression-derived equations. These values indicated that this compound will be highly mobile in soil. This compound is not
expected to significantly volatilize from most or dry soil to the atmosphere.
Aquatic Fate: If released to an aquatic environment, this compound is expected to rapidly degrade under aerobic conditions. Degradation is also likely in
seawater and under anaerobic conditions. Based on water solubility and its Log Kow, the bioconcentration factors for this compound can be estimated at
3 and 0.2, respectively. These values indicate that bioconcentration is not significant in aquatic organisms.
Atmospheric Fate: If released to the atmosphere, this compound may undergo a gas-phase oxidization with photochemically produced hydroxyl radicals. An
estimated reaction rate indicates that the atmospheric half-life of this compound in the atmosphere to be 33 hours. The water solubility of this compound
indicates that is may also undergo atmospheric removal by wet deposition processes.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This solution may irritate contaminated animals. Refer to Section 11
(Toxicology Information) for information on this product's components and their effects on test animals. This product is a
fertilizer. Releases of large quantities into an area can substantially alter the nutrient composition affect terrestrial plant life.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product is a fertilizer. Releases of large quantities into a body of water
can substantially alter the nutrient composition affect aquatic plant and animal life. The following aquatic toxicity information
is available for the components of this product.
ORGANIC ACID: ORGANIC ACID (continued):
EC0 (Pseudomonas putida bacteria) 16 hours = > 10,000 mg/L Period of survival at pH 4.0 (goldfish) 48 hours = 894 mg/L
EC0 (Microcystis aeruginosa algae) 8 days - 80 mg/L Period of survival at pH 4.5 (goldfish) = 625 mg/L
EC0 (Scenedesmus quadricauda green algae) 7 days = 640 mg/L TLm (shore crab) 48 hours = 160 ppm salt water
EC0 (Entosiphon sulcatum protozoa) 72 hours = 485 mg/L TRIOL ALCOHOL:
EC0 (Uronema parduczi Chatton-Lwoff protozoa) = 622 mg/L LC50 (Pimephales promelas, fathead minnow) = 44000 mg/L
LD0 (Daphnia magna giant water flea) = 80 mg/L, long-time exposure in soft LC50 (Carassius auratus, goldfish) = 5000 mg/L
water EC0 (Pseudomonas putida, bacteria) >10,000 mg/L/ 16 hours
LD0 (goldfish) 625 mg/L, long-time exposure in hard water EC0 (Microcystis aeruginosa, algae) = 2,900 mg/L/ 8 days
LD100 (Daphnia magna giant water flea) = 120 mg/l long-time exposure in EC0 (Scenedesmus quadricauda, green algae) >10,000 mg/L/ 7 days
soft water EC0 (Entosiphon sulcatum, protozoa) = 3,200 mg/L/ 72 hours
LD100 (goldfish) 894 mg/L, long-time exposure in hard water EC0 (Uronema parduczi Chatton-Lwoff, protozoa) >10,000 mg/L
Toxic (Daphnia water flea) = 100 mg/L LC50 (goldfish) 5,000 mg/L/ 24 hours
Toxic (goldfish) 4 hours = 894 ppm fresh water
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and
local regulations or those of Canada and its Provinces. This product, if unaltered by use, may be disposed of by treatment at
a permitted facility or as advised by your local hazardous waste regulatory authority.
U.S. EPA WASTE NUMBER: Not applicable.
14. TRANSPORTATION INFORMATION
THIS MATERIAL IS NOT HAZARDOUS, PER 49 CFR 172.101, U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME: Not applicable.
HAZARD CLASS NUMBER and DESCRIPTION: Not applicable.
UN IDENTIFICATION NUMBER: Not applicable.
PACKING GROUP: Not applicable.
DOT LABEL(S) REQUIRED: Not applicable.
NORTH AMERICAN EMERGENCY RESPONSE GUIDE NUMBER - 1996: Not applicable.
MARINE POLLUTANT: No component of this product is listed as a DOT Marine Pollutant (49 CFR 172.101, Appendix B).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: THIS MATERIAL IS NOT
CONSIDERED AS DANGEROUS GOODS.
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are not subject to the reporting requirements
of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization.
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for any component
of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may
apply, per 40 CFR 370.20.
NUTRI-GROW MAGNUM (2-40-16) [PROPRIETARY] MSDS
PAGE 6 OF 8
15. REGULATORY INFORMATION (Continued)
U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
U.S. STATE REGULATORY INFORMATION: Components of this product are covered under specific State regulations, as
denoted below:
Alaska - Designated Toxic and Hazardous Michigan - Critical Materials Register: No. Pennsylvania - Hazardous Substance List:
Triol Alcohol.
Substances: Triol Alcohol Mist. Minnesota - List of Hazardous Substances:
Triol Alcohol Mist. Rhode Island - Hazardous Substance List:
California - Permissible Exposure Limits for
Triol Alcohol Mist.
Missouri - Employer Information/Toxic
Chemical Contaminants: Triol Alcohol Mist.
Texas - Hazardous Substance List: No.
Substance List: Triol Alcohol Mist.
Florida - Substance List: No.
West Virginia - Hazardous Substance List: No.
New Jersey - Right to Know Hazardous
Illinois - Toxic Substance List: Triol Alcohol
Wisconsin - Toxic and Hazardous
Mist. Substance List: No.
Substances: No.
Kansas - Section 302/313 List: No. North Dakota - List of Hazardous Chemicals,
Massachusetts - Substance List: No. Reportable Quantities: No.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of this
product is on the California Proposition 65 lists.
ANSI LABELING (Z129.1): CAUTION! MAY CAUSE SKIN, EYE, AND RESPIRATORY SYSTEM IRRITATION.
PROLONGED SKIN CONTACT MAY CAUSE ALLERGIC REACTIONS. HARMFUL IF SWALLOWED. FOR
AGRICULTURAL USE ONLY. KEEP AWAY FROM CHILDREN. Avoid contact with skin, eyes, and clothing. Avoid
prolonged skin contact. Wash thoroughly after handling. Use in well-ventilated area. Use gloves, safety goggles, and
appropriate body protection. FIRST-AID: In case of skin or eye contact, flush with copious amounts of water.
Recommended flushing time is for 15 minutes. If inhaled, remove to fresh air. If ingested, do not induce vomiting. If adverse
reactions occur, get medical attention. IN CASE OF FIRE: Use water fog, dry chemical, CO2 or "alcohol" foam. IN CASE
OF SPILL: Absorb with an inert material (e.g., polypads), then place in a suitable container. Consult Material Safety Data
Sheet.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are on the DSL Inventory List.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION AGENCY (CEPA) PRIORITY SUBSTANCES LISTS: Not applicable
CANADIAN WHMIS SYMBOLS: Class D2B: Other Toxic Effects
16. OTHER INFORMATION
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
9163 Chesapeake Drive, San Diego, CA 92123-1002
(619) 565 - 0302
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the
accuracy of these data or the results to be obtained from the use thereof. Biagro Western Sales, Inc. assumes no responsibility for
injury to the vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as
stipulated in the data sheet. Additionally, Biagro Western Sales, Inc. assumes no responsibility for injury to vendee or third persons
proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee
assumes the risk in his use of the material.
NUTRI-GROW MAGNUM (2-40-16) [PROPRIETARY] MSDS
PAGE 7 OF 8
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following:
CAS #: This is the Chemical Abstract Service Number which uniquely identifies each constituent. It is used for computer-related searching.
EXPOSURE LIMITS IN AIR: FLAMMABILITY LIMITS IN AIR:
Much of the information related to fire and explosion is derived from the
ACGIH - American Conference of Governmental Industrial Hygienists, a
National Fire Protection Association (NFPA). Flash Point - Minimum
professional association which establishes exposure limits. TLV -
temperature at which a liquid gives off sufficient vapors to form an ignitable
Threshold Limit Value - an airborne concentration of a substance which
mixture with air. Autoignition Temperature: The minimum temperature
represents conditions under which it is generally believed that nearly all
required to initiate combustion in air with no other source of ignition. LEL -
workers may be repeatedly exposed without adverse effect. The duration
the lowest percent of vapor in air, by volume, that will explode or ignite in the
must be considered, including the 8-hour Time Weighted Average (TWA),
presence of an ignition source. UEL - the highest percent of vapor in air, by
the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling
volume, that will explode or ignite in the presence of an ignition source.
Level (C). Skin absorption effects must also be considered.
OSHA - U.S. Occupational Safety and Health Administration. TOXICOLOGICAL INFORMATION:
PEL - Permissible Exposure Limit - This exposure value means exactly the Human and Animal Toxicology: Possible health hazards as derived from
same as a TLV, except that it is enforceable by OSHA. The OSHA human data, animal studies, or from the results of studies with similar
Permissible Exposure Limits are based in the 1989 PELs and the June, compounds are presented. Definitions of some terms used in this section
1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed
40191). Both the current PELs and the vacated PELs are indicated. The animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed
phrase, 鈥淰acated 1989 PEL,鈥? is placed next to the PEL which was vacated
animals; ppm concentration expressed in parts of material per million parts
by Court Order. IDLH - Immediately Dangerous to Life and Health - This 3
of air or water; mg/m concentration expressed in weight of substance per
level represents a concentration from which one can escape within 30-
volume of air; mg/kg quantity of material, by weight, administered to a test
minutes without suffering escape-preventing or permanent injury. The DFG -
subject, based on their body weight in kg. Other measures of toxicity include
MAK is the Republic of Germany鈥檚 Maximum Exposure Level, similar to the
TDLo, the lowest dose to cause a symptom and TCLo the lowest
U.S. PEL. NIOSH is the National Institute of Occupational Safety and
concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo,
Health, which is the research arm of the U.S. Occupational Safety and
LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic
Health Administration (OSHA). NIOSH issues exposure guidelines called
effects. Cancer Information: The sources are: IARC - the International
Recommended Exposure Levels (RELs). When no exposure guidelines are
Agency for Research on Cancer; NTP - the National Toxicology Program,
established, an entry of NE is made for reference.
RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and
HAZARD RATINGS: CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health Hazard: 0 potential to cause human cancer with rankings from 1 to 4. Subrankings
(minimal acute or chronic exposure hazard); 1 (slight acute or chronic (2A, 2B, etc.) are also used. Other Information: BEI - ACGIH Biological
Exposure Indices, represent the levels of determinants which are most likely
exposure hazard); 2 (moderate acute or significant chronic exposure
to be observed in specimens collected from a healthy worker who has been
hazard); 3 (severe acute exposure hazard; onetime overexposure can result
exposed to chemicals to the same extent as a worker with inhalation
in permanent injury and may be fatal); 4 (extreme acute exposure hazard;
exposure to the TLV. Ecological Information: EC is the effect
onetime overexposure can be fatal). Flammability Hazard: 0 (minimal
concentration in water. BCF = Bioconcentration Factor, which is used to
hazard); 1 (materials that require substantial pre-heating before burning); 2
determine if a substance will concentrate in lifeforms which consume
(combustible liquid or solids; liquids with a flash point of 38-93掳C [100-200掳
contaminated plant or animal matter. Coefficient of Oil/Water Distribution
F]); 3 (Class IB and IC flammable liquids with flash points below 38掳C [100掳
is represented by log Kow or log Koc and is used to assess a substance鈥檚
F]); 4 (Class IA flammable liquids with flash points below 23掳C [73掳F] and
behavior in the environment.
boiling points below 38掳C [100掳F]. Reactivity Hazard: 0 (normally stable); 1
(material that can become unstable at elevated temperatures or which can REGULATORY INFORMATION:
react slightly with water); 2 (materials that are unstable but do not detonate This section explains the impact of various laws and regulations on the
or which can react violently with water); 3 (materials that can detonate when material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is
initiated or which can react explosively with water); 4 (materials that can the U.S. Department of Transportation. SARA is the Superfund
detonate at normal temperatures or pressures). Amendments and Reauthorization Act. TSCA is the U.S. Toxic Substance
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 Control Act. CERCLA (or Superfund) refers to the Comprehensive
(material that on exposure under fire conditions would offer no hazard Environmental Response, Compensation, and Liability Act. Labeling is per
beyond that of ordinary combustible materials); 1 (materials that on the American National Standards Institute (ANSI Z129.1). CANADA:
exposure under fire conditions could cause irritation or minor residual injury); CEPA is the Canadian Environmental Protection Agency. WHMIS is the
2 (materials that on intense or continued exposure under fire conditions Canadian Workplace Hazardous Materials Information System. TC is
could cause temporary incapacitation or possible residual injury); 3 Transport Canada. DSL/NDSL are the Canadian Domestic/Non-Domestic
(materials that can on short exposure could cause serious temporary or Substances Lists.
residual injury); 4 (materials that under very short exposure causes death or
major residual injury). Flammability Hazard and Reactivity Hazard: Refer to
definitions for 鈥淗azardous Materials Identification System鈥?.
NUTRI-GROW MAGNUM (2-40-16) [PROPRIETARY] MSDS
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