HANNA Instruments Buffer Solution pH 10.2 卤 0.2
Health & Safety data sheet
According to EC Directive 91/155/EC and following amendments
Date of issue: 03 January 2008.
SECTION 1 - IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY
Product name: Application:
鈥? Buffer Solution 10.2 卤 0.2. 鈥? Buffer solution.
Manufacturer identification: Hanna Instruments Italia s.r.l.
Viale delle Industrie, 12/A
35010 Villafranca Padovana, Italy
tel.: +39-049-9070211
Emergency Telephone n. 掳: +39-02-66101029
CENTRO ANTIVELENI
OSPEDALE NIGUARDA (MI) - ITALY
SECTION 2 鈥? COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients:
NAME EC-Index-No. CAS No. LABELLING CONTENT
(EC directives) (EC directives)
2-Amino-2-methyl-1-propanol 603-070-00-6 124-68-5 Xi 鈮? 35% - < 50%
R 36/38-52/53
Hydrochloric acid 017-002-01-X 7647-01-0 C, Xi 鈮? 1% - < 10%
R 34-37
(full text of R phrases in section 16)
SECTION 3 - HAZARD IDENTIFICATION
Irritating to eyes and skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
SECTION 4 - FIRST AID MEASURES
鈥? After inhalation : if inhaled remove to fresh air. If breathing becomes difficult, call a physician.
鈥? After skin contact : wash off with water and soap.
鈥? After eye contact : rinse out with plenty of water for at least 15 minutes. If pain persists, summon
medical advice.
鈥? After swallowing : wash out mouth with plenty of water, provided person is conscious. Obtain
medical attention if feeling unwell.
SECTION 5 鈥? FIRE-FIGHTING MEASURES
鈥? Suitable extinguishing media:
- Powder, foam.
鈥? Special risks:
- Development of hazardous combustion gases or vapours possible in the event of fire.
- The following may develop in event of fire: nitrogen oxides.
鈥? Special protective equipment for fire fighting:
- Do not stay in dangerous zone without suitable chemical protection clothing and self-contained breathing
apparatus.
鈥? Additional information:
- Prevent fire-fighting water from entering surface water or groundwater.
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HANNA Instruments Buffer Solution pH 10.2 卤 0.2
Health & Safety data sheet
According to EC Directive 91/155/EC and following amendments
SECTION 6 - ACCIDENTAL RELEASE MEASURES
鈥? Personal precautions:
- Do not inhale vapors/aerosols. Avoid substance contact. Ensure supply of fresh air in enclosed rooms.
鈥? Environmental precautions:
- Do not allow to enter the sewerage system.
鈥? Additional notes:
- Take up dry. Clean up affected area and dispose according to local regulation.
SECTION 7 - HANDLING AND STORAGE
鈥? Handling: 鈥? Storage:
- Avoid generation of vapors/aerosols. - Tightly closed. In a well-ventilated place at +15 to
- Do not inhale substance. +25 掳C.
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
鈥? Engineering controls
- Safety shower and eye bath.
鈥? General hygiene measures
- Wash thoroughly after handling.
鈥? Personal protective equipment:
- Protective clothing should be selected specifically for the working place, depending on concentration and
quantity of the hazardous substances handled.
鈥? Respiratory protection: 鈥? Protective gloves: 鈥? Eye protection:
- Required when - Rubber or plastic - Goggles or face mask
vapors/aerosols are generated.
Work under hood.
SECTION 9 - PHYSICAL/CHEMICAL PROPERTIES
鈥? Appearance : colorless solution Thermal decomposition : ND
鈥?
鈥? Odor : amine-like pH value at 20潞C : 10.2
鈥?
3
鈥? Solubility in water : soluble Density at 20潞C : 0.98 g/cm
鈥?
鈥? Melting point : NA Explosion limits : NA
鈥?
鈥? Boiling point : ND Flash point : ND
鈥?
SECTION 10 - STABILITY AND REACTIVITY
鈥? Conditions to be avoided: 鈥? Substances to be avoided:
- Heating. - Strong oxidizing agents.
鈥? Hazardous decomposition products:
- In the event of fire: see section 5.
SECTION 11 - TOXICOLOGICAL INFORMATION
Quantitative data on the toxicity of this product are not available.
APPLICABLE TO MAIN COMPONENT(S):
- The following applies to 2-Amino-2-methyl-1-propanol, as the pure substance:
Acute toxicity
LD50 (dermal, rabbit): >2000 mg/kg.
LD50 (oral, rat): 2900 mg/kg.
Specific symptoms in animal studies:
Eye irritation test (rabbit): Irritations.
Skin irritation test (rabbit): Irritations.
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HANNA Instruments Buffer Solution pH 10.2 卤 0.2
Health & Safety data sheet
According to EC Directive 91/155/EC and following amendments
Subacute to chronic toxicity
Sensitization:
Sensitization test (guinea pig): No sensitizing effect.
Bacterial mutagenicity: Ames test: negative.
Property of this product must be anticipated on the basis from the components of the preparation:
鈥? In case of skin contact : mucosal irritations, coughing, dyspnoea.
鈥? In case of eye contact : irritant effect.
鈥? In case of ingestion : of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal
tract.
鈥? Systemic effects : CNS disorders, cardiovascular disorders.
鈥? Toxic effect on : liver, kidneys.
鈥? Further data : the product should be handled with the care usual when dealing with chemicals.
SECTION 12 - ECOLOGICAL INFORMATION
Quantitative data on the toxicity of this product are not available.
APPLICABLE TO MAIN COMPONENT(S):
- The following applies to 2-Amino-2-methyl-1-propanol, as the pure substance:
Biologic degradation:
Biodegradation: 40 % /28 d.
Biologically not readily degradable.
Behavior in environmental compartments:
Distribution: log p(o/w): -0.74 (calculated).
No bioaccumulation is to be expected (log P(o/w <1).
Ecotoxic effects:
Biological effects: Harmful effect on aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
Fish toxicity: L.macrochirus LC50: 190 mg/l /96 h.
Daphnia toxicity: Daphnia magna EC50: 65 mg/l /24 h.
Algeal toxicity: Desmodesmus subspicatus IC50: 520 mg/l /72 h.
Bacterial toxicity: Ps.putida EC10: 50 mg/l.
Further ecologic data:
COD: 2.050 g/g.
BOD5: <0.01 g/g.
DO NOT ALLOW TO ENTER WATERS, WASTE WATER, OR SOIL!
SECTION 13 - DISPOSAL CONSIDERATIONS
鈥? Waste disposal:
- Chemical residues are generally classified as special waste and thus covered by local regulations. Contact
local authorities or disposal companies for advice.
- Handle contaminated packaging in the same way as the substance itself.
SECTION 14 - TRANSPORT INFORMATION
Not subject to transport regulations.
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HANNA Instruments Buffer Solution pH 10.2 卤 0.2
Health & Safety data sheet
According to EC Directive 91/155/EC and following amendments
SECTION 15 - REGULATORY INFORMATION
Labeling according to EC Directives:
Symbol Xi Irritant
R-phrases: 36/38-52/53 Irritating to eyes and skin. Harmful to aquatic organisms,
may cause long-term adverse effects in the aquatic
environment.
S-phrases: 61 Avoid release to the environment. Refer to special
instructions/Safety data sheets.
Contains: -
SECTION 16 - OTHER INFORMATION
鈥? Text of any R phrases referred to under heading 2:
34 : Causes burns.
36/38 : Irritating to eyes and skin.
37 : Irritating to respiratory system.
52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
st
鈥? Supersedes edition of : / (1 edition)
鈥? Legend : NA Not applicable
ND Not determined
THE INFORMATION CONTAINED HEREIN IS BASED ON THE PRESENT STATE OF OUR KNOWLEDGE. IT
CHARACTERIZES THE PRODUCT WITH REGARD TO THE APPROPRIATE SAFETY PRECAUTIONS. IT
DOES NOT REPRESENT A GUARANTEE OF THE PROPERTIES OF THE PRODUCT.
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