Material Safety Data Sheet
NFPA Transport Symbol
Not regulated
Preparation Date 12-Sep-2006 Revision Date 12-Sep-2006 Revision Number 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name ACETOCURE TEDA-33L
Product Code 3610700
Synonyms Misture of Dipropylene Glycol and Triethylenediamine
Formula Unspecified
CAS Number Mixture of 25265-71-8 & 280-57-9
Contact Manufacturer
ACETO CORPORATION
One Hollow Lane
Lake Success, NY 11042-1215
Phone: (516) 627-6000
Fax: (516) 627-6093
Email: regulatory@aceto.com
ChemTrec Emergency Telephone 1-800-424-9300
Numbers 1-703-527-3887
2. HAZARDS IDENTIFICATION
Emergency Overview
Toxic by inhalation. May be harmful if swallowed. Irritant. May cause sensitization by skin contact.
Appearance Colorless, Mobile. Physical State Liquid. Odor Not available
OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200).
Mexico - Grade Slight risk, Grade 1
Potential Health Effects
Principle Routes of Exposure Eye contact, Skin contact, Ingestion.
Acute Effects
Eyes Irritating to eyes. Pain. May cause corneal injury. Avoid contact with eyes.
Skin Irritating to skin. Dryness. Pain. Avoid contact with skin.
Inhalation Toxic by inhalation. Irritating to mucous membranes. Irritating to respiratory system.
Coughing and chest pain may result.
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Ingestion May be harmful if swallowed.
Chronic Effects May cause sensitization by skin contact. Prolonged skin contact may defat the skin
and produce dermatitis. Kidney injury may occur. May cause chemical conjunctivitis.
Nasal dryness. Avoid repeated exposure.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Not available
Interactions with Other Not available
Chemicals
Potential Environmental Effects There is no known ecological information for this product
3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS Number Mixture of 25265-71-8 & 280-57-9
Formula Unspecified
Hazardous Components
Chemical Name CAS-No Weight %
Dipropylene Glycol 25265-71-8 60 - 100
Triethylenediamine 280-57-9 30 - 60
4. FIRST AID MEASURES
General Advice Show this safety data sheet to the doctor in attendance.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Consult a physician.
Skin Contact Wash off immediately with soap and plenty of water removing all contaminated
clothes and shoes. Consult a physician.
Inhalation Move to fresh air. If breathing is difficult, give oxygen. Consult a physician.
Ingestion Rinse mouth. Never give anything by mouth to an unconscious person. Call a
physician immediately.
Notes to Physician Treat symptomatically
Protection of First-aiders Use personal protective equipment. Avoid contact with skin, eyes and clothing.
5. FIRE-FIGHTING MEASURES
Flammable Properties Not available
Suitable Extinguishing Media Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical.
Dry sand. Limestone powder.
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Unsuitable Extinguishing Media Not available
Hazardous Combustion Products Not available
Explosion Data
Sensitivity to mechanical impact Not available
Sensitivity to static discharge Not available
Specific Hazards Arising from the Chemical
Keep product and empty container away from heat and sources of ignition
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear
NFPA Health 2 Flammability 1 Instability 0
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Evacuate personnel to safe areas. Remove all sources of ignition. Use personal
protective equipment. Avoid contact with skin, eyes and clothing. In case of
insufficient ventilation, wear suitable respiratory equipment.
Environmental Precautions Local authorities should be advised if significant spillages cannot be contained.
Prevent product from entering drains. Do not allow material to contaminate ground
water system. Should not be released into the environment.
Methods for Containment Not available
Methods for Cleaning up Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical
waste container. Clean contaminated surface thoroughly.
Other Information Not applicable
7. HANDLING AND STORAGE
Handling Use only in an area equipped with a safety shower. Ensure adequate ventilation. Use
only in well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact
with skin, eyes and clothing. Avoid repeated exposure.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in
properly labelled containers. Do not store in reactive metal containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
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Chemical Name ACGIH TLV OSHA PEL Ontario TWAEV Mexico
Triethylenediamine = 1 ppm TWAEV
= 4.6 mg/m3 TWAEV
Absorption through skin,
eyes, or mucous
membranes
Engineering Controls Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/face Protection Tightly fitting safety goggles. Face-shield.
Skin Protection Protective gloves. Neoprene gloves. Impervious butyl rubber gloves. Nitrile rubber.
Impervious gloves. Long sleeved clothing.
Respiratory Protection In case of insufficient ventilation wear suitable respiratory equipment.
General Hygiene Considerations
Handle in accordance with good industrial hygiene and safety practice
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Colorless, Mobile
Physical State Liquid
Odor Not available
pH 10.20
Flash Point > 110掳C / > 230掳F
Method Closed cup
Autoignition Temperature Not available
Boiling Point/Range >149掳C
Melting Point/Range Not available
Flammability Limits in Air Lower Not available Upper Not available
Vapor Pressure 2 mmHg @ 21 掳C
Vapor Density Not available
Specific Gravity 1.03
Water Solubility Soluble
Reactivity in Water Not available
Molecular Weight Mixture
10. STABILITY AND REACTIVITY
Chemical Stability Stable under normal conditions
Conditions to Avoid Heat, flames and sparks
Incompatible Materials Mineral acids. Organic acids. Reactive metals. Sodium
hypochlorite. Calcium hypochlorite. Dehydrating agents.
Product slowly corrodes:. Copper. Aluminium. Zinc.
Galvanized surfaces.
Hazardous Decomposition Products Carbon monoxide, Carbon dioxide (CO2), Nitrogen oxides
(NOx), Ammonia, Nitric acid, Aldehydes, Flammable
hydrocarbon fragments.
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Possibility of Hazardous Reactions None under normal processing
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Product Information
LD50 Oral: 3,200 mg/kg (rat)
LD50 Dermal: > 2,000 mg/kg (rabbit)
LC50 Inhalation: > 10.1mg/L 1H (rat)
Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Dipropylene Glycol = 13300 mg/kg Oral LD50 Rat = 20600 mg/kg Dermal LD50
Rabbit
Triethylenediamine = 1700 mg/kg Oral LD50 Rat
Chronic Toxicity
Carcinogenicity There are no known carcinogenic chemicals in this product
Irritation Not available
Corrosivity Not available
Sensitization May cause sensitization by skin contact.
Neurological Effects Not available
Mutagenic Effects Not available
Reproductive Effects Not available
Developmental Effects Not available
Target Organ Effects Kidney, Nerves, Liver, Eyes, Skin.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants
Dipropylene Glycol
Microtox Data
= 10000 mg/L EC50 Pseudomonas putida 16 h
Persistence / Degradability Not available
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Bioaccumulation / Accumulation Not available
Mobility in Soil Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method Contact waste disposal services. Dispose of in accordance with local regulations.
Contaminated Packaging Dispose of in accordance with local regulations. Empty containers should be taken
for local recycling, recovery or waste disposal.
US EPA Waste Number Not available
14. TRANSPORT INFORMATION
DOT Not regulated
TDG Not regulated
MEX Not regulated
ICAO Not regulated
IATA Not regulated
IMDG/IMO Not regulated
RID Not regulated
ADR Not regulated
ADN Not regulated
15. REGULATORY INFORMATION
International Inventories
U.S.A. (TSCA) Complies
Canada (DSL) Complies
EU (ELINCS) Does not Comply
EU (EINECS) Complies
Japan (ENCS) Complies
China Complies
Korea (KECL) Complies
Philippines (PICCS) Complies
Australia (AICS) Complies
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Chemical Name U.S.A. (TSCA) Canada (DSL) EU (EINECS) EU (ELINCS)
Dipropylene Glycol Present Present 246-770-3 -
Triethylenediamine Present Present 205-999-9 -
Chemical Name Japan (ENCS) China Korea (KECL) Philippines (PICCS) Australia (AICS)
Dipropylene Glycol 2-413 Present KE-12226 Present Present
Triethylenediamine 5-1141 Present KE-09862 Present Present
USA
Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not
contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal
Regulations, Part 372.
SARA 311/312 Hazardous Categorization
Acute Health Hazard -
Chronic Health Hazard -
Fire Hazard -
Sudden Release of Pressure Hazard -
Reactive Hazard -
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product does not contain any HAPs.
Chemical Name CAS-No VOCs
Dipropylene Glycol 25265-71-8 Present
State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
State Right-to-Know
Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Dipropylene Glycol sn 2079 Present
Triethylenediamine sn 2839
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all the information required by the CPR.
WHMIS Hazard Class
Not determined
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16. OTHER INFORMATION
Prepared By Environmental Health and Safety, Regulatory Affairs
Preparation Date 12-Sep-2006
Revision Date 12-Sep-2006
Revision Summary Not available
Disclaimer
The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any other material or in any
process, unless specified in the text.
End of MSDS
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