HENKEL CONSUMER ADHESIVES 06/22/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 01 of 05
Loctite Extra Time Epoxy
01-81504
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Loctite Extra Time Epoxy
Item No.: 01-81504
Part No.:
Product Type: Epoxy
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
RESIN
Epoxy resin 25068-38-6 60-100
HARDENER
Polyamide resin 68410-23-1 60-100
N-(2-Aminoethyl)piperazine 140-31-8 10-30
Triethylenetetramine 112-24-3 5-10
Aminoethylethanolamine 111-41-1 1-5
Silica, amorphous, fumed,
Crystalline-free 112945-52-5 1-5
DIETHYLENETRIAMINE 111-40-0 1-5
Hydroxyethylpiperazine 103-76-4 1-5
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
RESIN
None
HARDENER
6mg/m3 TWA 10mg/m3 TWA 3mg/m3 TWA
Silica, amorphous, fumed,
Crystalline-free Respirable
Dust
DIETHYLENETRIAMINE 1 ppm TWA None None
(skin)
Aminoethylethanolamine none none 1 ppm skin TWA, WEEL
3. HAZARDS IDENTIFICATION
Toxicity: Causes eye and skin burns.
May cause allergic skin and respiratory reaction.
May cause respiratory tract irritation.
May be harmful if absorbed through skin.
HENKEL CONSUMER ADHESIVES 06/22/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Loctite Extra Time Epoxy
Item No.: 01-81504
3. HAZARDS IDENTIFICATION (continued)
Primary Routes of Entry: Ingestion, skin, inhalation, eye contact
Signs and Symptoms
of Exposure: Eye or skin irritation or injury. Allergic
responses such as sensitization or dermatitis.
Existing Conditions
Aggravated by Exposure: Skin disorders. Skin allergies. Respiratory disorders.
Eye disorders. Asthma
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
RESIN
Epoxy resin ALG IRR NO NO NO
HARDENER
Polyamide resin
N-(2-Aminoethyl)piperazine IRR COR ALG NO NO NO
Triethylenetetramine ALG IRR MUT NO NO NO
Aminoethylethanolamine ALL IRR NO NO NO
Silica Nuisance dust NO NO NO
DIETHYLENETRIAMINE ALG EYE IRR NO NO NO
Hydroxyethylpiperazine ALL CNS IRR NO NO NO
-------------------------------------------------------------------------------
Abbreviations
ALG Allergen BLO Blood
COR Corrosive EYE Eyes
IRR Irritant KID Kidney
NR No Records SPL Spleen
MUT Mutagen CNS Central Nervous System
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: RESIN: Not Applicable
HARDENER: Remove to fresh air. If symptoms
persist, obtain medical attention.
Skin Contact: Wash immediately with soap and water. Do not use
solvents for cleaning skin.
Eye Contact: Flush copiously with water for 15 minutes and get prompt
Medical attention.
HENKEL CONSUMER ADHESIVES 06/22/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 03 of 05
Loctite Extra Time Epoxy
01-81504
5. FIRE FIGHTING MEASURES
Flash Point: More than 224.6 掳C (436掳F) Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Special Firefighting
Procedures: Wear self-contained breathing apparatus and full
protective clothing, such as turn-out gear.
Hazardous Products formed
by Fire or Thermal Decomp: Before use, amine vapors may be evolved at high
temperatures; oxides of carbon; unidentified
organic compounds.
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Avoid skin contact. Scrape up as much as possible.
Clean residues with solvent or soap and water.
7. HANDLING AND STORAGE
Handling: Keep away from heat, spark and flame. Do not breathe mist or
vapors. Keep container closed. Avoid contact with eyes, skin
and clothing. Wash thoroughly after handling.
Storage: Store at or below 100掳F. Store in original container until ready
to use. Keep in a cool, well-ventilated area away from heat,
sparks and open flame. Keep container tightly closed until ready
for use.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration
below TLV.
Respiratory Use a NIOSH approved air-purifying respirator if the
potential to exceed established exposure limits exists.
See Section 2 for Exposure Limits.
HENKEL CONSUMER ADHESIVES 06/22/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Loctite Extra Time Epoxy
Item No.: 01-81504
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Hardener: Yellowish, viscous liquid Resin: clear
Odor: Mild
Boiling Point: More than 225掳F
pH: Not Applicable
Solubility in Water: Slight
Specific Gravity Resin 1.17, Hardener 0.98
Volatile Organic Compound
0.113% Resin and Hardener together
Vapor Pressure: Less than 5mm Hg at 20掳C (68掳F)
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not Available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizers, acids, Halogonated compounds.
Conditions to Avoid: Excessive heat. Storage with incompatible materials.
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
All shipping descriptions result from components in hardener. Resin is not
regulated.
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity ORM-D (Not more than 1 liter);
Corrosive liquids, basic, organic, n.o.s.
(Contains triethylenetetramine/aminoethylpiperazine)
Class 8, Packing Group II (More than four liters)
UN 3267
HENKEL CONSUMER ADHESIVES 06/22/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Loctite Extra Time Epoxy
Item No.: 01-81504
IATA
Proper Shipping Name: Corrosive liquids, basic, organic, n.o.s.
(Contains triethylenetetramine/aminoethylpiperazine)
Class or Division: Class 8, Packing Group II
UN or ID Number: UN 3267
IMO/IMDG
Proper Shipping Name: Corrosive liquids, basic, organic, n.o.s.
(Contains triethylenetetramine/aminoethylpiperazine)
Class or Division: Class 8, Packing Group II
UN or ID Number: UN 3267
Marine Pollutant: None known
15. REGULATORY INFORMATION
CA Proposition 65: This product contains a chemical known to the state of
California to cause cancer.
16. OTHER INFORMATION
TSCA 8(b) Inventory Status: All components are listed or are exempt from listing
on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None
CERCLA/SARA Section 302 EHS: None
CERCLA/SARA Section 311/312: Immediate health hazard
CERCLA/SARA Section 313: Resin: None. Hardener: This product contains the
following toxic chemicals subject to the reporting requirements of section 313 of
the Emergency Planning and Community Right-to-know Act of 1986 (40 CFR 372).
Diethanolamine. (CAS#111-42-2)
Estimated HMIS(R) Code:
Health Hazard: 3
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared by:
Company: Henkel Consumer Adhesive
Regulatory Affairs (440) 937-7000
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