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HI 83740D-0 Copper
Reagent D
Health & Safety data sheet
According to EC Directive 91/155/EC and following amendments
Date of issue: 22 march 2006
1U - IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY
USECTION
Product name: Application:
鈥? HI 83740D-0 Copper Reagent D 鈥? Reagent for wine analysis
Hanna Instruments Italia s.r.l.
Manufacturer identification:
viale delle Industrie, 12/A
35010 Villafranca Padovana, Italy
tel. n.掳: +39-049-9070211
+39-02-66101029
Emergency Telephone n.掳:
CENTRO ANTIVELENI
OSPEDALE NIGUARDA (MI) - ITALY
2U 鈥? COMPOSITION/INFORMATION ON INGREDIENTS
USECTION
Hazardous Ingredients:
NAME EC-Index-No. CAS No. EC No. LABELLING
(EC directives) (EC directives)
Hydroxylammonium 612-123-00-2 5470-11-1 226-798-2 Xn, N
chloride R 22-36/38-43-48/22-50
(full text of R phrases in section 16).
3U - HAZARD IDENTIFICATION
USECTION
Harmful if swallowed. Irritating to eyes and skin. May cause sever sensitization by skin contact. Harmful: danger
of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms.
4U - FIRST AID MEASURES
USECTION
鈥? After inhalation : fresh air.
鈥? After skin contact : wash off with plenty of water. Remove contaminated clothing.
鈥? After eye contact : rinse out with plenty of water with the eyelid held wide open. Call in
ophthalmologist.
鈥? After swallowing : make victim drink plenty of water, induce vomiting, call in physician
5U 鈥? FIRE-FIGHTING MEASURES
USECTION
鈥? Suitable extinguishing media
- foam, powder, spray water.
鈥? Special risks:
- Combustible. Formation of hazardous combination gases of vapors possible in event of fire. Danger of dust
explosion. The following may develop in event of fire: hydrochloric acid, nitrogen oxides.
鈥? Special protective equipment for fire fighting:
- Do not stay in dangerous zone without suitable chemical protection clothing and self-contained breathing
apparatus. In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.
鈥? Additional information:
- Contain escaping vapours with water. Prevent fire residues and contaminated fire fighting water from
entering surface water or groundwater.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
鈥? Personal precautions:
- Avoid substance contact. Avoid inhalation of dusts. Ensure supply of fresh air in enclosed rooms.
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HI 83740D-0 Copper
Reagent D
Health & Safety data sheet
According to EC Directive 91/155/EC and following amendments
鈥? Environmental precautions:
- Do not allow to enter sewerage system.
鈥? Additional notes:
- Take up dry. Clean up affected area and dispose according to local regulation. Avoid generation of dusts.
SECTION 7 - HANDLING AND STORAGE
鈥? Handling: 鈥? Storage:
- No further requirements. - Store at room temperature (+15 to +25 掳C
recommended).
- Tightly closed and away from sources of ignition
and heat.
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
鈥? Specific control parameter
EC
Name Hydroxylammonium chloride
Sensitization Danger of sensitization of the skin
鈥? Personal protective equipment:
- Protective clothing should be selected specifically for the working place, depending on concentration and
quantity of the hazardous substances handled.
鈥? Respiratory protection: 鈥? Protective gloves: 鈥? Eye protection:
- Required when dusts are - Rubber or plastic - Goggles or face mask
generated.
SECTION 9 - PHYSICAL/CHEMICAL PROPERTIES
鈥? Appearance 鈥?
: white powder pH value at 20潞C : 2.5 鈥? 3.5 @ 50 g/L in water
鈥? Odor 鈥?
: odorless Density at 20潞C : NA
鈥? Solubility in water : 鈭? 830 g/L 鈥? Ignition temperature : NA
鈥? Melting point 鈥?
: 159掳C Flash point : NA
鈥? Boiling point 鈥?
: NA log Pow : -2.66 (calculated)
SECTION 10 - STABILITY AND REACTIVITY
鈥? Conditions to be avoided: 鈥? Substances to be avoided:
- Heating (decomposition) - fire-promoting substances, oxidizing agent
(explosive decomposition); alkaline substances
(heat): formed could be: Hydroxylamine
鈥? Hazardous decomposition products: 鈥? Further information:
- in the event of fire (see Section 5) - Unsuitable working materials: aluminum, zinc, tin,
copper.
SECTION 11 - TOXICOLOGICAL INFORMATION
Acute toxicity
LDB50 (oral, rat): 141 mg/kg (RTECS).
B
Subacute to chronic toxicity
Experience in man: may cause sensitization.
鈥? In case of inhalation : mucosal irritations.
鈥? In case of skin contact : irritations. Dermatitis. Risk of skin sensitization.
鈥? In case of eye contact : irritations.
鈥? In case of ingestion : irritations of gastrointestinal tract.
鈥? After absorption : drop on blood pressure, cyanosis, Risk of methaemoglobin formation.
鈥? Further data : the product should be handled with the care usual when dealing with chemicals.
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HI 83740D-0 Copper
Reagent D
Health & Safety data sheet
According to EC Directive 91/155/EC and following amendments
SECTION 12 - ECOLOGICAL INFORMATION
Biologic degradation:
Methods for the determination of biodegradability are not applicable to inorganic substances.
Behavior in environmental compartments:
Distribution: log p(o/w): -2.66 (calculated).
No bioaccumulation is to be expected (log P(o/w <1).
Ecotoxic effects:
Quantitative data on the ecological effect of this product are not available.
Biological effects: Highly toxic for aquatic organisms.
Further ecologic data:
Do not allow to enter waters, waste water, or soil!
SECTION 13 - DISPOSAL CONSIDERATIONS
鈥? Waste disposal:
- Chemical residues are generally classified as special waste and thus covered by local regulations. Contact
local authorities or disposal companies for advice.
- Handle contaminated packaging in the same way as the substance itself.
SECTION 14 - TRANSPORT INFORMATION
These transport data apply to the reagents supplied with the instrument:
鈥? Land transport ADR/RID : 9, II
UN-No. : 3316
Name : CHEMICAL KIT
鈥? Sea transport IMDG : 9/UN 3316/PG II
Name : CHEMICAL KIT
鈥? Air transport ICAO/IATA : 9/UN 3316/PG II
Name : CHEMICAL KIT
These transport data apply to the complete reagent set HI 83740-20:
鈥? Land transport ADR/RID : 3, II
UN-No. : 1105
Name : PENTANOLS
鈥? Sea transport IMDG : 3/UN 1105/PG II
Name : PENTANOLS
鈥? Air transport ICAO/IATA : 3/UN 1105/PG II
Name : PENTANOLS
!
SECTION 15 - REGULATORY INFORMATION
Labeling according to EC Directives:
Symbol: Xn Harmful
N Dangerous for the environment
R-phrases : 22-36/38-43-48/22-50 Harmful if swallowed. Irritating to eyes and skin. May
cause sensitization by skin contact. Harmful: danger
of serious damage to health by prolonged exposure if
swallowed. Very toxic to aquatic organisms.
S-phrases : 22-24-37-61 Do not breathe dust. Avoid contact with skin. Wear
suitable gloves. Avoid release to the environment.
Refer to special instructions/Safety data sheets.
Contains : Hydroxylammonium chloride
EC No.: 226-798-2
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ETIC83740D
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HI 83740D-0 Copper
Reagent D
Health & Safety data sheet
According to EC Directive 91/155/EC and following amendments
Reduced Labelling (1999/45/EC, Art.10,4)
Symbol: Xn Harmful
N Dangerous for the environment
R-phrases : 22-43-48/22 Harmful if swallowed. May cause
sensitization by skin contact. Harmful:
danger of serious damage to health by
prolonged exposure if swallowed.
S-phrases : 24-37 Avoid contact with skin. Wear suitable
gloves.
Contains : Hydroxylammonium chloride
EC No.: 226-798-2
SECTION 16 - OTHER INFORMATION
鈥? Text of any R phrases referred to under heading 2:
22 Harmful if swallowed
36/38 Irritating to eyes and skin.
43 May cause sensitization by skin contact.
48/22 Harmful: danger of serious damage to health by prolonged exposure if
swallowed.
50 Very toxic to aquatic organisms.
鈥? Supersedes edition of : 19 May 2005
鈥? Reasons for revision : SECTION 2: change in composition/information on ingredients
SECTION 14: change in transport information
SECTION 15: change in regulatory information
General update
鈥? Legend : NA Not applicable
ND Not determined
THE INFORMATION CONTAINED HEREIN IS BASED ON THE PRESENT STATE OF OUR KNOWLEDGE. IT
CHARACTERIZES THE PRODUCT WITH REGARD TO THE APPROPRIATE SAFETY PRECAUTIONS. IT
DOES NOT REPRESENT A GUARANTEE OF THE PROPERTIES OF THE PRODUCT.
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