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MSDS Material Safety Data Sheet
CAS

122-62-3
1344-95-2

File Name: harwickstandard_com---0820121.asp
                                          MATERIAL SAFETY DATA SHEET
DOS DLC@

Issued: March 6. 2006
Paqe 1 of 4
SECTION I - PRODUCT AND COMPANY IDENTIFICATION

Di'S bL G HMIS RATING
TRADE NAME: Name
HEALTH 1
CHEMICAL NAME: FLAMMABILITY 1
REACTIVITY 0
NATROCHEM,INC.
Company:
P.O. Box 1205
Savannah, GA 31402-1205

Telephone Numbers:
Transportation Emergencies:
CHEMTREC (U.S.A.): (800) 424-9300 (24 hours)
CHEMTREC (International): (202) 483-7616 (24 hours, call collect)
Product Information: (912) 236-4464 (EST, 8:00AM - 4:00PM M-F)

SECTION II - COMPONENTS

CAS#
COMPONENT NAME
DOS 122-62-3
1344-95-2
Synthetic Calcium Silicate

SECTION111- HYSICALDATA
P

Boiling Point: N/A Specific Gravity: 1.11
Percent Volatiles: 72
Vapor Pressure (mm Hg): 0.98C @ 210C
Vapor Density (Air = 1): N/D Evaporation Rate: N/D
Solubility in Water: 0.001
Appearance and Odor: Tan powder, faint oily odor.

SECTION IV - FIRE & EXPLOSION DATA

FLASH POINT: 210C

EXTINGUISHING MEDIA: Chemical powder, foam, C02, water fog. Water and foam may cause frothing when
they come in contact with burning material.

SPECIAL FIRE FIGHTING PROCEDURES: Full face, self-contained breathing apparatus used in positive
pressure mode should be worn to prevent inhalation of airborne contaminants.

UNUSUAL FIRE & EXPLOSION HAZARDS: None known.

HAZARDOUS COMBUSTION PRODUCTS: COx

- HEALTH
SECTION V HAZARD DATA

HEALTH EFFECTS: 5 mg/m3 respirable nuisance dust, OSHA. 10 mg/m3 total nuisance dust, ACGIH
Prolonged or repeated exposure to excessive concentrations of this product dust or nay nuisance dust can cause
chronic pulmonary disease.

ACUTE TOXICITY DATA:

Acute Oral LD50 Acute Dermal LD50 Acute Inhalation LCSO




MARKETED BY
HARWICK STANDARD
DISTRIBUTION CORPORATION
60 S. Seiberling Street. Akron, Ohio 44305
- - -- ----
--
DOS DLC NATROCHEM MSDS PAGE 2 OF 4
SECTION V - HEALTH HAZARD DATA (cont

PRIMARY ROUTE OF ENTRY- Inhalation, dust contact with the eyes.

CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN:
NTP: no IARC: no OSHA: no


EFFECTS OF EXPOSURE-

EYES- Mildly irritating. Excessive contact with powder can cause drying of mucous membranes of eyes due to
absorption of moisture and oils. May cause eye irritation.

SKIN- Mildly irritating.

INHALATION- Nuisance dust. Excessive contact with powder can cause drying of mucous membranes of nose
and throat due to absorption of moisture and oils. This material can also cause nasal irritation and nosebleeds.

INGESTION- Not significantly toxic.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE- Persons with breathing problems or lung disease
should not work in dusty areas unless a physician approves and certifies their fitness to wear respiratory
protection. Pre-existing upper respiratory and lung disease such as, but not limited to bronchitis, emphysema and
asthma.

SECTION VI - EMERGENCY & FIRST AID PROCEDURES

EYE CONTACT: Immediately rinse with clean water for 15 minutes. Retract eyelids often. If irritation persists,
seek medical attention.

SKIN CONTACT: Immediately remove contaminated clothing. Wash skin thoroughly with mild soap and water.
Flush with lukewarm water for 15 minutes. Seek medical attention if ill effect or irritation develops.

INHALATION: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Consult a physician.

INGESTION: N/DA

SECTION VII- REACTIVITY DATA

STABILITY: Stable.

MATERIALS TO AVOID- Hydrofluoric acid

CONDITIONS TO AVOID- Keep away from oxidizing agents and open flame.

HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon when burned.

HAZARDOUS POLYMERIZATION: Will not occur.
DOS DLC NATROCHEM MSDS PAGE 3 OF 4
SECTION VIII - SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: MINIMIZE SPILL AREA. Vacuum
spill material and place in closed plastic bags for disposal.

WASTE DISPOSAL METHOD: In accordance with local, state, and federal regulations.

SECTION IX - SPECIAL PROTECTION INFORMATION

RESPIRATORY PROTECTION: Use a respirator such as 3M 9900 or equivalent for protection against
pneumoconiosis producing dusts.

VENTILATION: Provide explosion proof ventilation as required to control airborne dust levels. The sum total of
all ingredients may emit vapors during normal processing. All possible health effects are not known and individual
sensitivities will vary. Effective exhaust ventilation should always be provided to draw dust, fumes and vapors
away from workers to prevent routine inhalation. Ventilation should be adequate to maintain ambient workplace
atmosphere below the limits listed in Section V.

PROTECTIVE GLOVES: Impervious gloves to protect against contact with product.

EYE PROTECTION: Safety goggles.

OTHER PROTECTIVE EQUIPMENT: Protective clothing, eye wash station, safety shower.

SECTION X - SPECIAL PRECAUTIONS

HANDLING AND STORAGE: Handling can create explosive dust clouds. Eliminate ignition sources, use
explosive proof equipment. Conveying and processing equipment should be spark-proof, well bonded and
grounded. Avoid dust accumulations.


OTHER PRECAUTIONS: Wash with soap and water before eating, drinking, smoking, or using toilet facilities.
Launder contaminated clothing before reuse.

SECTION XI- REGULATORY INFORMATION

TOXIC SUBSTANCE CONTROL ACT (TSCA):

The components of this product are contained on the Inventory of the Toxic Substance Control Act.

CHEMICAL INVENTORIES:

OSHA:
The component(s) listed below is identified as a hazardous chemical under the criteria of the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
AMOUNT ACGIH OSHA
INGREDIENT UNITS
(TLV) (PEL)
Calcium Silicate 28% 10 5 mg/m3




---
PAGE 4 OF 4
NATROCHEM MSDS
DOS DLC
SECTION XI- REGULATORY INFORMATION (Cont.

SARA 313 TOXIC CHEMICALS:
This product does not contain any toxic chemical subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and the Pollution Prevention Act of 1990.
PERCENT BY WEIGHT
CHEMICAL NAME
CAS REGISTRY #


SECTION 311/312 - HAZARD CATEGORIES:
The physical and health hazard categories for the hazardous components exceeding the de minimis amount
subject to reporting under Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 and
of 40 CFR 372

Hazard Percent in Product
Name of Chemical
28%
Acute
Calcium Silicate

ADDITIONAL RIGHT-TO-KNOW INFORMATION ON COMPONENTS:


TRANSPORTATION INFORMATION:

DOT Shipping Name: Not regulated.
DOT Identification Number:


SECTION XII - OTHER INFORMATION
Issue Date: March 6, 2006
Prepared by: Craig Moore

N/A = Not applicable NID = Not determined N/DA = No Data Available N/E = Not established

The information given in this MSDS was obtained from sources which we believe are reliable. However, since
data, safety standards, and government regulations are subject to change and the conditions of handling and use,
or misuse are beyond our control, Natrochem, Inc. makes no warranty express or implied, with respect to the
completeness or continuing accuracy of the information contained herein and disclaims all liability for reliance
thereon.

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