Material Safety Date Issued: 03/06/2008
Date-Revised: New MSDS
Data Sheet Product Code:: ?????
RB 414 X Page 1 of 6
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Product Name: RB 414 X Grit Range: 24, 36 - 80
Synonyms: N/A
Product Use: Coated abrasive product
Manufacturer: HERMES ABRASIVES, LTD.
524 Viking Drive
Virginia Beach, VA 23452
Ph. No.: (757) 486-6623
Fax No.: (757) 431-2370
E-mail: www.hermesabrasives.com
24-Hour Emergency Telephone Numbers: CHEMTREC (U.S.): (800) 424-9300
SECTION 2 鈥? HAZARDOUS INGREDIENTS
INGREDIENTS C.A.S. NO. & BY WEIGHT
Aluminum Oxide 1344-28-1 8.2 鈥? 14.5
Alumina Zirconia 12.3 鈥? 32.2
Quartz 14808-60-7 <1.0
Trisodium Hexafluoroaluminate 15096-52-3 1.1 鈥? 1.4
Potassium-tetrafluoroborate 14075-53-7 2.2 鈥? 2.8
Calcium Carbonate (2BG, 4BG) 1317-65-3 3.8 鈥? 6.2
Note: The user of this product should perform an assessment of the workpiece material(s) to fully understand the
scope of hazards associated with the use of this product.
SECTION 3 鈥? HAZARDS IDENTIFICATION
There are no known hazards associated with the abrasive product itself other than what is contained in the Exposure
Controls section of this document.
There can be hazards associated with the use of this product. Always review completely all operational instructions
provided by the manufacturer of any tools or machinery that this product may be used with. It is also recommended
that before this product is used for grinding purposes, a risk assessment should be performed on the material being
abraded.
Potential Health Effects
Inhalation: Exposure to dust generated from the use of this product can result in respiratory system irritation.
Signs/symptoms may include throat or nasal irritation, wheezing, coughing, congestion, or headaches.
Eye Contact: Eye irritation. Signs/symptoms may include redness, discomfort, or in some cases, scratching of the
corneal tissue.
Skin Contact: Skin irritation. Signs/symptoms may include itching, abrasion, or redness.
Material Safety Date Issued: 03/06/2008
Date-Revised: New MSDS
Data Sheet Product Code:: ?????
RB 414 X Page 2 of 6
Ingestion: No harmful effects are known.
SECTION 4 鈥? FIRST AID MEASURES
Inhalation: Move exposed person to fresh air. If signs/symptoms persist, seek medical attention.
Eye Contact: Immediately flush eye with water. If signs/symptoms persist, seek medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms persist, seek medical attention.
Ingestion: No treatment expected. If signs/symptoms persist, seek medical attention.
SECTION 5 鈥? FIRE FIGHTING MEASURES
Toxic fumes may occur, Use respiratory protective equipment.
Extinguishing Media: water, foam, sand powder or CO2 as appropriate for surrounding materials.
SECTION 6 鈥? ACCIDENTAL REALEASE MEASURES
Not applicable.
SECTION 7 鈥? HANDLING AND STORAGE
This product should be inspected carefully prior to use for cracks or tears. Damaged product can break apart during
use and cause serious injury. Personal protective equipment should be worn to protect the eyes, face and hands. Dust
and particulate generated from the use of this product can cause injury to the respiratory system if proper respiratory
equipment is not worn during use. Sparks can be generated from the use of this product. Care should be taken to
prevent fires.
Product should be stored in a cool dry place. Recommended conditions: 68 (卤2) 0F, [200C], 45-65% relative humidity.
SECTION 8 鈥? EXPOSURE CONTROLS / PERSONAL PROTECTIVE EQUIPMENT
A risk assessment should be performed before using this product. Local mechanical exhaust ventilation is
recommended while using this product to control airborne dust, fumes, and/or particulate. Respiratory protection
equipment is also recommended. Refer to Section 2 for Occupational Exposure Limits of key ingredients and dust.
See below for specific recommended personal protective equipment.
Respiratory Protection:
Avoid breathing fumes and dust generated by the use of this product. Select and use an OSHA-approved respirator
based upon the airborne concentrations of this abrasive鈥檚 ingredients and the workpiece material being abraded to
prevent overexposure.
Material Safety Date Issued: 03/06/2008
Date-Revised: New MSDS
Data Sheet Product Code:: ?????
RB 414 X Page 3 of 6
Skin Protection:
Care should be taken to avoid contact with the skin. Use appropriate gloves and protective clothing to minimize skin
contact and reduce the possibility of physical abrasion.
Eye Protection:
Always wear eye and face protection. Goggles or full face shield are recommended.
Hearing Protection:
Hearing protection may be desired, depending on specific application or machinery.
Exposure Limit Values:
OSHA PEL (mg/m3) ACGIH / TWA (mg/m3)
INGREDIENT C.A.S. NO. E.C. NO. TOTAL RESPIRABLE TOTAL RESPIRABLE
Aluminum Oxide 1344-28-1 215-691-6 15 5 10
Alumina Zirconia 15 5 10
Quartz (Silica, Crystalline) 14808-60-7 238-878-4 0.1 0.025
Trisodium
15096-52-3 239-148-8 2.5 2.5
Hexafluoroaluminate
Potassium-
14075-53-7 237-928-2 2.5 2.5
tetrafluoroborate
Calcium Carbonate (2BG,
1317-65-3 215-279-6 15 5 10
4BG)
Dust 10 3
SECTION 9 鈥? PHYSICAL AND CHEMICAL PROPERTIES
General Physical Form: Solid
Flash Point: Not Applicable
Boiling Point: Not Applicable
Melting Point: Not Applicable
Specific Gravity: Not Applicable
Solubility in Water: Insignificant
SECTION 10 鈥? STABILITY AND REACTIVITY
Stability: Coated abrasives are stable when handled or stored.
Reactivity: Unknown.
Conditions to avoid: No decomposition in normal use.
Materials to avoid: No dangerous reactions known.
Material Safety Date Issued: 03/06/2008
Date-Revised: New MSDS
Data Sheet Product Code:: ?????
RB 414 X Page 4 of 6
Hazardous decomposition: At temperatures exceeding 4820F (2500C) hazardous or toxic decomposition products
may be generated.
SECTION 11 鈥? TOXICOLOGICAL INFORMATION
Acute Toxicity
Acute oral toxicity No data available.
Acute dermal toxicity No data available.
Acute inhalation toxicity No data available.
Irritant/Corrosive Effects
Irritant effect on skin In case of prolonged, frequent contact, irritation is possible.
Irritant effect on eyes In case of prolonged, frequent contact, irritation is possible.
Sensitization No data available.
Effects after repeated or prolonged exposure (sub-acute, sub-chronic, chronic)
Mutagenicity No data available.
Reproduction toxicity No data available.
Carcinogenicity
CAS No.: 14808-60-7
IARC: Group 1 carcinogen
Experience in practice
Repeated and prolonged skin contact may lead to defatting and irritation of the skin.
SECTION 12 鈥? ECOLOGICAL INFORMATION
Ecotoxic effects: No data available
Daphnia toxicity: No data available
Algae toxicity: No data available
Bacteria toxicity: No data available
General Information / Ecology: Do not discharge product unmonitored into the environment
SECTION 13 鈥? DISPOSAL CONSIDERATIONS
Product:
Dispose in accordance with federal, state and local regulations.
Packaging:
Uncontaminated packaging may be taken for recycling.
Packaging that cannot be cleaned should be disposed of as a product waste.
It is highly recommended to consult all applicable local, state and national regulations regarding waste disposal in your
area.
Material Safety Date Issued: 03/06/2008
Date-Revised: New MSDS
Data Sheet Product Code:: ?????
RB 414 X Page 5 of 6
SECTION 14 鈥? TRANSPORT INFORMATION
This product is not defined under USDOT, IMDG, GGVSee, or ICAO/IATA regulations as a hazardous material.
SECTION 15 鈥? REGULATORY INFORMATION
U.S. Federal Regulations:
TSCA (Toxic Substances Control Act)
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Clean Water Act (CWA)
None of the ingredients are listed.
Clean Air Act
None of the ingredients are listed.
OSHA: Hazardous by definition of the Hazard Communication Standard (29 CFR 1910.1200)
The following ingredients are hazardous by definition of Hazard Communication Standard:
CAS No: 14075-53-7; 14808-60-7; 15096-52-3; 1317- 65-3;
SARA Section 302 (RQ)
None of the ingredients are listed.
SARA Hazard Category (Section 311/312)
Not classified as hazardous in accordance with the regulations.
SARA Section 313 Information
None of the ingredients are listed.
HAPS (Hazardous Air Pollutants)
None of the ingredients are listed.
IARC
None of the ingredients are listed.
NTP Report on Carcinogens
The following ingredients are listed:
CAS No.: 14808-60-7
State Regulations:
New Jersey Worker and Community Right to Know Act
The following ingredients are listed:
CAS No.: 14808-60-7; 15096-52-3; 1344-28-1
California Proposition 65
This product contains a substance known to the state of California to cause cancer.
CAS No.: 14808-60-7 Silica, Crystalline.
Pennsylvania Hazardous Substance List
The flowing ingredients are listed:
CAS No.: 14808-60-7; 15096-52-3; 1317-65-3
Material Safety Date Issued: 03/06/2008
Date-Revised: New MSDS
Data Sheet Product Code:: ?????
RB 414 X Page 6 of 6
Canada Federal Regulations
Workplace Hazardous Materials Information System (WHMIS) 鈥? Canada
WHMIS Classification: Not a controlled product. This product meets the definition of a 鈥渕anufactured article鈥? under
WHMIS regulations.
SECTION 16鈥? OTHER INFORMATION
HMIS Classification
Flammability: 1
Health: 1
PPE: B
Reactivity: 0
NFPA Rating
Fire Hazard: 1
Health: 1
Reactivity: 0
This data is based on our present knowledge and do not signify any warranty with regard to the properties of the
products. Observance of existing laws and regulations is the sole responsibility of the consumer.
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