MATERIAL SAFETY DATA SHEET
ULTIMA SATIN EMULSION
SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Supplier: Harris Paints Barbados (2003) Limited
Wildey
St. Michael
Barbados
(246) 429-4840
Product Code and Name: A-8420.01 Ultima Satin Emulsion White
A-8420.P Ultima Satin Emulsion Pastel Base
A-8420.I Ultima Satin Emulsion Interior Base
A-8420.A Ultima Satin Emulsion Accent Base
Manufacturer: Harris Paints Barbados (2003) Limited
Wildey
St. Michael
Barbados
MSDS Prepared For: Technical Department Tel: (246) 429-4840
Harris Paints Barbados (2003) Limited Fax: (246) 436-9544 E-Mail: technical@harris.bb
Product Use: Paints
Date of Preparation: August 22, 2003 Revision #: 1
SECTION 2: HAZARDOUS COMPOSITION OF INGREDIENTS AND INFORMATION
INGREDIENTS NAMES COMPOSITION % (Wt /Gal.)
Common Name Chemical Name CAS No. A-8410.01 A-8410.P A-8410.I A8410.A
Propylene Glycol 1,2-Propylene Glycol 57-55-6 5.2 5.3 5.3 5.8
Tamol Maleic Anhydride 108-31-6 1.0 1.1 1.1 1.2
Limestone Calcium Carbonate 1317-65-3 3.5 3.6 13.5 14.8
Titanium Dioxide Titanium Dioxide 13463-67-7 22.3 21.2 8.6 -
Texanol Propanioc Acid, 2, 2, 4- 25265-77-4 1.6 1.6 1.6 1.8
Trimethyl-1, 3-
Pentanediol
Monoisobutyrate
Ammonia Ammonia, Anhydrous 7664-41-7 0.52 0.53 0.53 0.58
Acticides (Mixture) N/A: Microbiocides NA 1.2 1.2 1.2 1.4
mixture
SECTION 3: HAZARDS IDENTIFICATION
Physical State and
Appearance Liquid (viscous)
Emergency Overview
Primary Routes of Exposure Skin contact, Inhalation, Eye contact, Ingestion.
Possible Effects to Overexposure
Skin contact:- Irritation of skin. May aggravate pre-existing skin conditions.
Inhalation:- Irritation of respiratory tract. Prolonged inhalation may lead to
mucous membrane irritation, dizziness and/or light-headedness,
headache, nausea, asphyxiation.
Eye contact:- Irritation of eyes. Prolonged or repeated contact may cause
conjunctivitis.
Ingestion:- Ingestion may cause mouth and throat irritation, gastro-intestinal
disturbances.
Medical condition aggravated by exposure: Eye, skin, respiratory disorders, kidney disorders, central nervous
system depression.
Overexposure Signs/ Symptoms: Not Available.
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SECTION 4: FIRST-AID MEASURES
Skin Contact: Flush skin with water. Then wash thoroughly with soap and water. Remove contaminated
clothing. Wash contaminated clothing before re-use.
Inhalation: Remove to fresh air. Restore and support continued breathing. Get emergency medical attention.
Have trained person give oxygen if necessary. Get medical help for any breathing difficulty.
Remove to fresh air if inhalation caused eye watering, headaches, dizziness or other discomfort.
Eye Contact: Flush immediately with large amounts of water, especially under lids for at least 15 minutes. If
irritation or other effects persist, obtain medical treatment.
Ingestion: Flush out mouth. If swallowed, do not induce vomiting. If victim is conscious give at least 2 glasses
of water. Obtain medical treatment immediately.
SECTION 5: FIRE-FIGHTING MEASURES
Flammability of the product: Lower Explosive Limit: Not known
Upper Explosive Limit: Not known
Auto-Ignition Temperature: Not known
>100oC
Flash Points:
Fire Extinguishing Media: Use dry chemical, water foam or fog, carbon dioxide
Products of Combustion: Carbon dioxide, carbon monoxide, other irritating gases
Unusual Fire and Explosion Hazards: Closed containers may burst if expose to extreme heat or fire
Explosive Hazard in Presence
of Various Substances:
Special Remarks on Fire
Hazards:
Special Remarks on
Explosion Hazards:
SECTION 6: ACCIDENTAL RELEASE MEASURES
Small Spill and Leak: Comply with all applicable health and environmental regulations.
Eliminate all sources of ignition. Ventilate area. Spills may be collected with absorbent
materials. Place collected material in an appropriate container.
Complete personal protective equipment must be used during cleanup.
Large Spills and Leaks: Shut off leak if safe to do so. Dike and contain spill. Pump to storage or salvage
vessel. Use absorbent to collect excess residue.
SECTION 7: HANDLING AND STORAGE
Handling: Store cool at a constant temperature. Keep away from heat, sparks and open flames
Minimum: 1oC Maximum: 40oC.
Storage: Lacquer lined steel tins or polypropylene pails.
Other Precautions: Use only with adequate ventilation. Do not take internally. Keep out of reach of
children. Avoid contact with skin and eyes and breathing of vapours. Wash hands
thoroughly after handling, especially before eating or smoking. Keep containers tightly
closed and upright when not in use. Avoid conditions which result in formation of
inhalable particles such as spraying or sanding painted surfaces. If such conditions
cannot be avoided, use appropriate respiratory protection as directed under exposure
control/personal protection. Empty containers may contain residues.
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SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
Common Name CAS No. ACGHI-TLV OSHA-PEL
8-Hour TWA 8-Hour TWA
Propylene Glycol 57-55-6 Not est. Not est.
1 mg/m3 1 mg/m3
Tamol 108-31-6
10 mg/m3 15 mg/m3
Limestone 1317-65-3
10 mg/m3 10 mg/m3
Titanium Dioxide 13463-67-7
Texanol 25265-77-4 Not est. Not est.
Ammonia 7664-41-7 25 ppm 25 ppm
Microbiocides Mixtures NA Not est. Not est.
Personal Protection
Body Impervious clothing should be worn to eliminate possible skin irritation
Hands Impervious gloves such as neoprene or nitrile rubber gloves should be worn.
Respiratory Use in a well ventilated area or provide local exhaust or ventilation to reduce
vapours build up.
Use of an appropriate NIOSH/MSHA approved or equivalent electometric sealing
surface face piece respirator outfitted with organic vapour cartridges and paint
spray (Dust / Mist) prefilters.
Eyes Safety goggles or glasses recommended especially for over head work. Face
shield could be used to protect facial skin also.
N.B.: Keep running water sources on site in cases of emergency and for after work cleaning.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical Sate
and Appearance: Liquid Odour: Slight
pH: ~ 8.5 Colour: Pure White
Soluble / Insoluble: Soluble in water Viscosity: 90 KU
Melting / Freezing Point: Not available Solubility: Not available
Boiling / Condensation Point: Not available Critical Temperatures: Not available
Specific Gravity: 1.09-1.46 Volatility: Not available
Vapour Density: Not available Vapour Pressure: Not available
Evaporation Rate: Not available
SECTION 10: STABILITY AND REACTIVITY
Stability and reactivity: These products are stable. See Section 5 Fire Fighting Measures.
Conditions to avoid: Elevated temperatures, contact with oxidising agents, sparks, freezing, open flame
Materials to avoid: Oxidisers, acids.
SECTION 11: TOXICOLOGICAL INFORMATION
Supplemental Health
Information: No additional effects are anticipated besides those mentioned in Section 5 Fire
Fighting measures.
These products have not been listed by IARC, OSHA, ACGIH, DSL, TSCA.
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SECTION 12: ECOLOGICAL INFORMATION
There is no data available on the products.
General Note: Do not allow undiluted product or large quantities of products to reach ground water,
water courses or sewage systems.
SECTION 13: DISPOSAL CONSIDERATION
Dispose of in accordance with all applicable regulations ensuring no contamination of
surrounding environment.
SECTION 14: TRANSPORTATION INFORMATION
UN ID No.: 1263
These products are not controlled or regulated under DOT, IATA.
DOT: Classification: Paints 鈥減rotect from freezing鈥?
IATA: Classification: Paints 鈥減rotect from freezing鈥?
SECTION 15: REGULATORY INFORMATION
Products
As of the date of this MSDS, these products were not being regulated or controlled.
Product Components:
EINECS No.: Texanol - 246-771-9, Maleic Anhydride 鈥? 203-571-6, Titanium Dioxide 鈥? 236-675-5
DSCL (EEC) Microbiocide constituents - Xn 鈥? Harmful
Trade names Acticide BG and Acticide EPW classified
according to 91/155 EC obtained from THOR Gmbh.
IARC Titanium Dioxide
SARA Title III
Section 311: Maleic Anhydride - Immediate (Acute) Health Hazard, Delayed(Chronic)
Health Hazard
Propylene Glycol - Acute
Section 313: Maleic Anhydride 100%
WHMIS: Maleic Anhydride - Class D, Div 1, Subdiv B: Material causing immediate
and serious toxic effects(TOXIC)
Class D, Div 2, Subdiv A and B: Material causing other
toxic effects (VERY TOXIC)
Class E: Corrosive Solid
DSL: Maleic Anhydride - Listed
Propylene Glycol - Listed
Ammonia - Listed
TSCA: Maleic Anhydride - Listed
Propylene Glycol - Listed
ATSDR: Ammonia - Inhalation :- Acute 0.5 ppm
Chronic 0.3 ppm
Oral :- 0.3 mg/kg/day
Propylene Glycol - Inhalation :- Intermediate 0.009 ppm
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SECTION 16: OTHER INFORMATION
The information contained herein is based on data available at the time of preparation of this data sheet and which
is believed to be reliable. However, it is the users' responsibility to ensure safe conditions for handling, storage
and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. This
information is given in good faith, but no warranty, expressed or implied is made.
This MSDS complies with MSDS requirements for Canada, the USA and the European Union and fulfils the ISO
standards for format and content.
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