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MSDS Material Safety Data Sheet
CAS

102-06-7

File Name: harwickstandard_com---1080181.asp
EXCEL POLYMERS                  LLC
MATERIAL SAFETY DATA SHEET


MASTERMIX DPG 5906-72
Version Number 1.1 Page I of 6
Revision Date 10/28/2005 Print Date 11/3/2005


1.PRODUCT AND COMPANY IDENTIFICATION

EXCEL POLYMERS LLC
Burton, OH 44021
14330Kinsman Road,


Telephone Product Stewardship (440) 834-4644
Emergency telephone CHEMTREC 1-800-424-9300 (24hrs for spill, leak, fire, exposure
number or accident).

MASTERMIX DPG 5906-72
Product name
AD3000267860
Product code
Mixture
Chemical Name
Mixture
CAS-No.
Product Use Industrial Applications

2. COMPOSITION/INFORMATION ON REGULATED INGREDIENTS

CAS-No. Weight %
102-06-7 60 - 100

3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

This mixture has not been evaluated as a whole. Information provided on the health effects of this
product is based on individual components. All ingredients are bound and potential for hazardous
exposure as shipped is minimal. However, some vapors may be released upon heating and the end-
user (fabricator) must take the necessary precautions (mechanical ventilation, respiratory protection,
etc.) to protect employees from exposure.


POTENTIAL HEALTH EFFECTS

Routes of Exposure: Inhalation, Ingestion, Skin contact

Acute exposure

Inhalation Particulates, like other inert materials can be mechanically irritating.
Ingestion May be harmful if swallowed.
Eyes Particulates, like other inert materials can be mechanically irritating.
Skin Experience shows no unusual dermatitis hazard from routine handling.


Refer to Section II for Toxicological Information.
Chronic exposure

Medical Conditions None known.
Aggravated by Exposure:

MARKETED BY
HARWICK STANDARD
DISTRIBUTION CORPORATION
60 S. Seiberling Street. Akro~, Ohio 44305
- - -- -
EXCEL POLYMERS LLC
E~EL
MATERIAL SAFETY DATA SHEET
/ \
POLYMERS
MASTERMIX DPG 5906-72
Page 2 of 6
Version Number 1.1
Print Date 11/3/2005
Revision Date 10/28/2005




r I
4. FIRST AID MEASURES

Move to fresh air in case of accidental inhalation of fumes from
Inhalation
overheating or combustion. When symptoms persist or in all cases of
doubt seek medical advice.

Do not induce vomiting without medical advice. When symptoms
Ingestion
persist or in all cases of doubt seek medical advice.

Rinse immediately with plenty of water, also under the eyelids, for at
Eyes
least 15 minutes. If eye irritation persists, seek medical attention.

Skin Wash off with soap and plenty of water. If skin irritation persists
seek medical attention.

I
1 5. FIRE-FIGHTING MEASURES

Not applicable
Flash point

Flammable Limits
Not applicable
Upper explosion limit
Not applicable
Lower explosion limit
Not applicable
Autoignition temperature
: water spray, dry powder, foam, carbon dioxide (C02)none.
Suitable extinguishing media

Fullface self-contained breathing apparatus (SCBA) used in positive
Special Fire Fighting
Procedures pressure mode should be worn to prevent inhalation of airborne
contaminants.
Carbon dioxide (C02), carbon monoxide (CO), oxides of nitrogen
Unusual Fire/Explosion
Hazards (NOx), other hazardous materials, and smoke are all possible.

I
T 6. ACCIDENTAL RELEASE MEASURES

Wear appropriate personal protection during cleanup, such as
Personal precautions
impervious gloves, boots and coveralls.

Should not be released into the environment. The product should not
Environmental precautions
be allowed to enter drains, water courses or the soil.

Clean up promptly by sweeping or vacuum. Package all material in
Methods for cleaning up
plastic, cardboard or metal containers for disposal. Refer to Section
13 of this MSDS for proper disposal methods.

I
I 7. HANDLING AND STORAGE

Take measures to prevent the build up of electrostatic charge. Heat
Handling
only in areas with appropriate exhaust ventilation.
EXCELPOLYMERSLLC
MATERIAL SAFETY DATA SHEET


MASTERMIX DPG 5906-72
Version Number 1.1 Page 3 of 6
Revision Date 10/28/2005 Print Date 11/3/2005


Storage Keep containers dry and tightly closed to avoid moisture absorption
and contamination. Keep in a dry, cool place.

I 1
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Respiratory protection No personal respiratory protective equipment normally required when
handling the product itself. See "EngineeringMeasures" section
below for precautions to be taken when heating or processing this
material.

Eye/Face Protection Safety glasses with side-shields.

Hand protection Protective gloves.

Skin and body protection Long sleeved clothing.

Additional Protective Safety shoes.
Measures

General Hygiene Handle in accordance with good industrial hygiene and safety
Considerations practice. Wash hands before breaks and at the end of workday.

Engineering measures Heat only in areas with appropriate exhaust ventilation. Adequate
ventilation and/or appropriate respiratory protection may also be
necessary to minimize employee exposure to processing vapors.

Exposure limit(s)



I l
9. PHYSICAL AND CHEMICAL PROPERTIES

Form Solid Not applicable
Evaporation rate
Appearance Pellets, Slabs, sheets Not determined
Specific Gravity:
Color NO PIGMENT Not established
Bulk density
Odor Characteristic rubber odor Vapor pressure Not applicable
Not determined
Melting point/range Not applicable
Vapour density
Boiling Point: Not applicable Not applicable
pH
Insoluble
Water solubility

I 1
1o. STABILITY AND REACTIVITY

Stable.
Stability

Will not occur.
Hazardous Polymerization

Conditions to avoid Keep away from oxidizing agents and open flame. To avoid thermal
decomposition, do not overheat.




---
EXCEL POLYMERS LLC
EEL
MATERIALSAFETYDATASHEET
\
/ POLYMERS
MASTERMIX DPG 5906-72
Version Number 1.1 Page 4 of 6
Revision Date 10/28/2005 Print Date 11/3/2005


Incompatible Materials Incompatible with strong acids and oxidizing agents.

Hazardous decomposition Carbon dioxide (C02), carbon monoxide (CO), oxides of nitrogen
products (NOx), other hazardous materials, and smoke are all possible.

11. TOXICOLOGICAL INFORMATION

This mixture has not been evaluated as a whole for health effects. Exposure effects listed are based on existing
health data for the individual components which comprise the mixture.

Toxicitv Overview
This product contains the following components which in their pure form have the following characteristics:

CAS-No. Chemical Name Effect Target Organ
102-06-7 Systemic effects
1,3-Diphenylguanidine Respiratory system.
toxic Refer to LC50 / LD50 Data on
MSDS..

LC50 / LD50
This product contains the following components which, in their pure form, have the following toxicity data:

CAS-No. Chemical Name Route Value Species
102-06-7 Oral LD50 rat
1,3-Diphenylguanidine 323 mg/kg
Dermal LD50 rabbit
> 794 mg/kg

12. ECOLOGICAL INFORMATION

: Not readily biodegradable.
Persistence and degradability

Environmental Toxicity Chemicals are not readily available as they are bound within the
polymer matrix.

Bioaccumulation Potential Chemicals are not readily available as they are bound within the
polymer matrix.

Additional advice Not applicable

13. DISPOSAL CONSIDERATIONS

Product Where possible recycling is preferred to disposal or incineration. The
generator of waste material has the responsibility for proper waste
classification, transportation and disposal in accordance with
applicable federal, state/provincial and local regulations.

Contaminated packaging Recycling is preferred when possible. The generator of waste
material has the responsibility for proper waste classification,
transportation and disposal in accordance with applicable federal,
state/provincial and local regulations.



'$/
EXCEL POLYMERS LLC
E~EL
MATERIAL SAFETY DATA SHEET
\
/ POLYI\I\ERS
MASTERMIX DPG 5906-72
Version Number 1.1 Page 5 of 6
Print Date 11/3/2005
Revision Date 10/28/2005




14. TRANSPORT INFORMATION


u.s. DOT Classification Refer to specific regulation.

ICAO/IATA (air) Refer to specific regulation.

IMO / IMDG (maritime) Refer to specific regulation.

15. REGULATORY INFORMATION

us Regulations:

OSHA Status Classified as hazardous based on components.

TSCA Status All components of this product are listed on or exempt from the
TSCA Inventory.

us. EPA CERCLA Hazardous Substances (40 CFR 302)

Not applicable




California Proposition Not applicable
65

SARA Title III Section 302 Extremely Hazardous Substance
Not applicable


SARA Title III Section 313 Toxic Chemicals:

Not applicable
Canadian Regulations:

National Pollutant Release Invento
CAS-No. NPRI ID#
Chemical Name Weight %
9016-45-9 1.00 - 5.00 178
Poly( oxy-l ,2-ethanediyl), .alpha.-(nonylphenyl)-
.omega.-hvdroxv-




WHMIS Classification DIB

DSL All components of this product are on the Canadian Domestic
Substances List (DSL) or are exempt.




---- -- ----
EXCEL POLYMERS LLC
EkEL
MATERIAL SAFETY DATA SHEET
/ \
POlYN\ERS
MASTERMIX DPG 5906-72
Version Number 1.1 Page 6 of 6
Print Date 11/3/2005
Revision Date 10/28/2005



National Inventories:

Listed
Australia AICS

Listed
China IECS

Listed
Europe EINECS
Listed
Japan ENCS
Listed
Korea KECI

Listed
Philippines PICCS

16. OTHER INFORMATION

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material when used in
combination with any other materials and/or in any particular process or processing conditions.




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