MATERIAL SAFETY DATA SHEET
1 CHEMICAL PRODUCT & COMPANY IDENTIFICATION
TRADE NAME SURE SOL庐-205
SEE BELOW
CAS NUMBER
MSDS NUMBER 5123
PRODUCT CODE 9302
CAS# 64742-94-5 OR CAS# 68477-31-6
SYNONYM(S)
HEAVY AROMATIC SOLVENT NAPHTHA
MANUFACTURER / Koch Chemical Company
SUPPLIER PO Box 2608
Corpus Christi, TX
78403
TELEPHONE NUMBERS - 24 HOUR EMERGENCY ASSISTANCE
Koch Petroleum Group, LP.: 361-241-4811
Chemtrec: 800-424-9300
TELEPHONE NUMBERS - GENERAL ASSISTANCE
8-5 (M-F, CST) MSDS Assistance 316-828-8488
8-5 (M-F, CST) 361-241-4811
2 COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient Name CAS Number Concentration* Exposure Limits / Health Hazards
ALKYLNAPHTHALENES/ C10+ -- 93.9 % ND
ALKYLBENZENES AND
TETRALINS (CAS # 68477-31-6)
OR HEAVY AROMATIC SOLVENT
NAPHTHA (CAS # 64742-94-5)
FLUORENE 86-73-7 1.9 % ND
BIPHENYL 92-52-4 3.5 % 0.2 ppm 8-Hour TWA (OSHA)
0.2 ppm 8-Hour TWA (ACGIH)
NAPHTHALENE 91-20-3 0.7 % 10 ppm 8-Hour TWA (OSHA)
10 ppm 8-Hour TWA (ACGIH)
15 ppm 15-Min STEL (ACGIH)
*Values do not reflect absolute minimums and maximums; these values are typical which may vary from time to time.
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Trade Name SURE SOL庐-205
Material Id 5123
3 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HEALTH HAZARDS
WARNING!
MAY CAUSE ALLERGIC SKIN REACTION
MAY BE IRRITATING TO THE SKIN, EYES AND RESPIRATORY TRACT
ASPIRATION HAZARD IF SWALLOWED-CAN ENTER LUNGS AND CAUSE DAMAGE
OVEREXPOSURE MAY CAUSE CNS DEPRESSION
MAY ALSO CAUSE ADVERSE PERIPHERAL NERVOUS SYSTEM EFFECTS
MAY BE HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN
FLAMMABILITY HAZARDS
UNDEFINED (FLASH POINT > 200 F)
PER OSHA GUIDELINES, 29 CFR 1910.1200(c)
REACTIVITY HAZARDS
STABLE
POTENTIAL HEALTH EFFECTS, SKIN
May cause skin irritation. Contact may cause reddening, itching and inflammation. Repeated or prolonged skin
contact may cause drying, reddening, itching and cracking. Defatting agent.
May cause an allergic reaction in some individuals.
No significant effects are expected to occur following short term exposure. Repeated or prolonged contact with
large amounts of this material may result in absorption through the skin to produce toxic effects.
POTENTIAL HEALTH EFFECTS, EYE
May cause eye irritation. Exposure to vapors, fumes or mists may cause irritation. Direct contact may cause
irritation, redness, tearing and blurred vision. Prolonged or repeated exposure may cause irritation and
conjunctivitis.
POTENTIAL HEALTH EFFECTS, INHALATION
Breathing of the mists, vapors or fumes may irritate the nose, throat and lungs. Symptoms may include sore
throat, coughing, labored breathing, sneezing and burning sensation, depending on the concentration and
duration of exposure. Repeated or prolonged exposures may cause bronchitis and laryngitis.
May cause central nervous system depression or effects. Symptoms may include headache, excitation,
euphoria, dizziness, incoordination, drowsiness, light-headedness, blurred vision, fatigue, tremors, convulsions,
loss of consciousness, coma, respiratory arrest and death, depending on the concentration and duration of
exposure. Repeated or prolonged exposures may cause behavioral changes.
May produce signs of peripheral neuropathy, such as tingling or loss of feeling in the fingers, arms, feet and
legs.
Overexposure to this material may cause systemic damage including target organ effects listed under "Special
Toxic Effects."
Other specific symptoms of exposure are listed under "Special Toxic Effects."
POTENTIAL HEALTH EFFECTS, INGESTION
May cause irritation of the mouth, throat and gastrointestinal tract. Symptoms may include salivation, pain,
nausea, vomiting and diarrhea.
Aspiration into lungs may cause chemical pneumonia and lung damage.
Exposure may also cause central nervous system symptoms similar to those listed under "Inhalation" (see
Inhalation section).
Overexposure to this material may cause systemic damage including target organ effects listed under "Special
Toxic Effects."
Other specific symptoms of exposure are listed under "Special Toxic Effects."
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Trade Name SURE SOL庐-205
Material Id 5123
SPECIAL TOXIC EFFECTS
Acute or chronic overexposure to this material or its components may cause systemic toxicity, including
adverse effects to the following: kidney, liver, blood, bone marrow, spleen, brain, ureter, bladder, central and
peripheral nervous systems. Other systems or target organs include the following: cardiovascular, respiratory
and gastrointestinal systems.
Exposure to components of this material may cause the following specific symptoms, depending on the
concentration and duration of exposure: insomnia, sensory impairment, aching of limbs, fatigue, numbness,
flaccid paralysis, chest pain, laryangeal and bronchospasms.
This product contains components which may cause adverse reproductive and/or developmental effects.
Pregnant women may be at an increased risk from exposure. Consumption of alcoholic beverages may
enhance toxic effects.
Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage (sometimes referred to as solvent or painter's syndrome). Intentional misuse by
deliberately concentrating and inhaling this product may be harmful or fatal.
Pre-existing medical conditions which may be aggravated by exposure include disorders of the kidney, liver,
eye, skin, respiratory system and blood (glucose-6-phosphate deficiency).
4 FIRST AID MEASURES
SKIN
Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. Heated
material may cause thermal burns. Get medical attention if irritation develops or persists.
Place contaminated clothing in closed container for storage until laundered or discarded. If clothing is to be
laundered, inform person performing operation of contaminant's hazardous properties. Discard contaminated
leather goods.
EYE
Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be held away from the
eyeball to ensure thorough rinsing. Get medical attention if irritation persists.
Burns due to either hot or cold contact require immediate medical attention.
INHALATION
Remove to fresh air. If not breathing, institute cardiopulmonary resuscitation (CPR). If breathing is difficult,
ensure airway is clear and give oxygen. Keep affected person warm and at rest. GET IMMEDIATE MEDICAL
ATTENTION.
INGESTION
Do not induce vomiting because of danger of aspirating liquid into lungs, causing serious damage and
chemical pneumonitis. If spontaneous vomiting occurs keep head below hips to prevent aspiration and monitor
for breathing difficulty. Gastric lavage should be performed only by qualified medical personnel. GET
IMMEDIATE MEDICAL ATTENTION.
Keep affected person warm and at rest.
NOTES TO PHYSICIAN
Gastric lavage may be indicated if ingested. If spontaneous vomiting has occurred, the patient should be
monitored for symptoms of pneumonitis, as this effect may be delayed up to 48 hours.
Monitor for possible liver toxicity and central and peripheral neurotoxicity.
5 FIRE FIGHTING MEASURES
HAZARDOUS COMBUSTION PRODUCTS
Combustion may produce COx.
EXTINGUISHING MEDIA
Use water spray, dry chemical, alcohol foam, all purpose AFFF or carbon dioxide to extinguish fire.
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Trade Name SURE SOL庐-205
Material Id 5123
BASIC FIRE FIGHTING PROCEDURES
Evacuate area and fight fire from a safe distance.
Use water spray to cool adjacent structures and to protect personnel. Shut off source of flow if possible. Stay
away from storage tank ends. Withdraw immediately in case of rising sound from venting safety device or any
discoloration of storage tank due to fire.
Firefighters must wear MSHA/NIOSH approved positive pressure breathing apparatus (SCBA) with full face
mask and full protective equipment.
UNUSUAL FIRE & EXPLOSION HAZARDS
Fires involving this product may release carbon monoxide, carbon dioxide and irritating vapors.
Flash Point 215 F (101 C) TAG CLOSED CUP
AutoIgnition Temperature ND
Flammability Limits in Air, Lower, % by Volume ND
Flammability Limits in Air, Upper, % by Volume ND
6 ACCIDENTAL RELEASE MEASURES
EMERGENCY ACTION
Eliminate and/or shut off ignition sources and keep ignition sources out of the area. Keep unnecessary people
away; isolate hazard area and deny entry. Stay upwind. Isolate for 1/2 mile in all directions if tank, rail car or
tank truck is involved in release. Evacuate area endangered by release as required. (See Personal Protection
Information Section.)
ENVIRONMENTAL PRECAUTIONS
If product is released to the environment, take immediate steps to stop and contain release. Caution should be
exercised regarding personnel safety and exposure to the released product. Notify local authorities and the
National Response Center, if required.
SPILL OR LEAK PROCEDURE
Keep ignition sources out of area and shut off all ignition sources. Absorb spill with inert material (e. g. dry
sand or earth) then place in a chemical waste container. Large Spills: Dike far ahead of liquid spill for later
disposal. Stop leak when safe to do so.
See Exposure Controls/Personal Protection (Section 8).
7 HANDLING & STORAGE
HANDLING
Ground lines and equipment used during transfer to reduce the possibility of static spark-initiated fire or
explosion. Use non-sparking tools. Do not cut, grind, drill, weld or reuse containers unless adequate
precautions are taken against these hazards.
Do not eat, drink or smoke in areas of use or storage.
STORAGE
Store in tightly closed containers in a cool, dry, isolated, well-ventilated area away from heat, sources of
ignition and incompatibles. Avoid contact with strong oxidizers.
Empty containers may contain product residue. Do not reuse without adequate precautions.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Ventilation and other forms of engineering controls are the preferred means for controlling exposures.
EYE PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
Wear chemical safety goggles and face shield. Have eye washing facilities readily available where eye contact
can occur.
SKIN PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
Avoid skin contact with this material. Use appropriate chemical protective gloves when handling.
Use good personal hygiene.
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Trade Name SURE SOL庐-205
Material Id 5123
RESPIRATORY PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be
permissible under certain circumstances where airborne concentrations are expected to exceed exposure
limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator
if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances
where air purifying respirators may not provide adequate protection.
9 PHYSICAL & CHEMICAL PROPERTIES
ODOR AND APPEARANCE
CLEAR, LIGHT YELLOW COLORED LIQUID WITH A MODERATE "MOTH BALL" ODOR
Boiling Point 440 F (227 C)
Specific Gravity 0.99
Melting Point ND
Percent Volatile ND
Vapor Pressure ND
Vapor Density ND
Bulk Density ND
Solubility in Water ND
Octanol/Water Partn ND
Volatile Organic ND
Pour Point -10 F (-23 C)
pH Value ESSENTIALLY NEUTRAL
Freezing Point ND
Viscosity 2.4 cSt AT 100 F (38 C)
Evaporation Rate ND
Molecular Formula NA
Molecular Weight ND
Chemical Family HYDROCARBON MIXTURE
Odor Threshold ND
10 STABILITY & REACTIVITY
STABILITY/INCOMPATABILITY
Incompatible with oxidizing agents. See precautions under Handling & Storage (Section 7).
HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS
Combustion may produce COx.
11 TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA
See Special Toxic Effects (Section 3).
12 ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
ND
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Trade Name SURE SOL庐-205
Material Id 5123
13 DISPOSAL CONSIDERATIONS
WASTE DISPOSAL
This product, as supplied, when discarded or disposed of, will not be a hazardous waste according to Federal
regulations. Under the Resource Conservation and Recovery Act (RCRA), it is the responsibility of the user of
the product to determine, at the time of disposal, whether the material is a hazardous waste subject to RCRA.
The transportation, storage, treatment and disposal of RCRA waste material must be conducted in compliance
with 40 CFR 262, 263, 264, 268 and 270. Disposal can occur only in properly permitted facilities. Check state
and local regulations for any additional requirements as these may be more restrictive than federal laws and
regulations. Chemical additions, processing or otherwise altering this material may make the waste
management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. Disposal
of this material must be conducted in compliance with all federal, state and local regulations.
14 TRANSPORT INFORMATION
BILL OF LADING - BULK (U. S. DOT)
Environmentally Hazardous Substance, Liquid, N.O.S. (Solvent Naphtha), 9, UN3082, PG III, RQ, (Biphenyl,
Naphthalene), Marine Pollutant, (Methylnaphthalenes)
U. S. Department of Transportation (DOT) Requirements
General Transportation Information for Bulk Shipments
Proper Shipping Name Environmentally Hazardous Substance, Liquid, N.O.S. (Solvent Naphtha)
Hazard Class UN/NA Code
9 UN3082
PG III
Packaging Group
Labels Required Class 9, Marine Pollutant
Placards Required Class 9, UN3082, Marine Pollutant
See Regulatory Information (Section 15)
Reportable Quantity
General Transportation Information for Non-Bulk Shipments
Environmentally Hazardous Substance, N.O.S. (Solvent Naphtha)
Proper Shipping Name
Hazard Class UN/NA Code
9 UN3082
PG III
Packaging Group
Labels Required Class 9, Marine Pollutant
Placards Required Class 9, UN3082, Marine Pollutant
See Regulatory Information (Section 15)
Reportable Quantity
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Trade Name SURE SOL庐-205
Material Id 5123
15 REGULATORY INFORMATION
FEDERAL REGULATIONS
All known major components of this product are listed on the TSCA Inventory and/or are otherwise in
compliance with TSCA.
This product, as supplied, contains biphenyl, naphthalene and fluorene which are Hazardous Substances as
per 40 CFR Part 302.4. The reportable quantities for biphenyl, naphthalene and fluorene are 100, 100 and
5000 pound(s), respectively. Any release of this product that results in a release of biphenyl, naphthalene and
fluorene equal to or exceeding the reportable quantity must be reported to the National Response Center
(800-424-8802) and appropriate state and local regulatory agencies as described in 40 CFR Part 302.6 and 40
CFR 355.40, respectively. Failure to report may result in substantial civil and criminal penalties. Check state
and local regulations for any additional requirements as these may be more restrictive than federal laws and
regulations.
This product contains one or more components designated as hazardous substances or toxic pollutants
pursuant to the Federal Clean Water Act (40 CFR 116.4 Table A; 40 CFR 401.15). Any unpermitted
introduction of this product into a facility stormwater or wastewater discharge may constitute a violation of the
Clean Water Act. Facilities must notify the appropriate permitting agency prior to introducing this product into
the aforementioned discharges.
This product contains one or more substances listed as hazardous, toxic or flammable air pollutants under
Section 112 of the Clean Air Act.
There may be specific regulations at the local, regional or state/provincial level that pertain to this product.
STATE REGULATIONS
Based on available information this product does not contain any components or chemicals currently known to
the State of California to cause cancer, birth defects or reproductive harm at levels which would be subject to
Proposition 65. Reformulation, use or processing of this product may affect its composition and require
re-evaluation.
SARA TITLE III RATINGS
Immediate Hazard: X Delayed Hazard: X Fire Hazard: - Pressure Hazard: -
Reactivity Hazard: -
NFPA RATINGS
Health 1 Flammability 1 Reactivity 0 Special Hazards -
HMIS RATINGS
Health 1* Flammability 1 Reactivity 0
Following ingredients of this product are listed in SARA313
SARA Listed Ingredient Name CAS Number Maximum %
BIPHENYL 92-52-4 5.0
16 OTHER INFORMATION
DISCLAIMER
NOTICE: The information presented herein is based on data considered to be accurate as of the date of
preparation of this Material Safety Data Sheet. However, MSDS may not be used as a commercial
specification sheet of manufacturer or seller, and no warranty or representation, expressed or implied, is made
as to the accuracy or comprehensiveness of the foregoing data and safety information, nor is any authorization
given or implied to practice any patented invention without a license. In addition, no responsibility can be
assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to
recommended practices, or from any hazards inherent in the nature of the product
Completed On 6/1/99 Replaces Sheet Dated 12/31/98
Completed By Safety & Emergency Response, Koch Industries Inc.
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Trade Name SURE SOL庐-205
Material Id 5123
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