MATERIAL SAFETY DATA SHEET
Prescription Treatment 庐 brand 1600 X-clude 庐 Timed Release Pyrethrum
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (PROSAR) TRANSPORTATION: 800-424-9300 (CHEMTREC)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION SECTION 5. FIRE FIGHTING MEASURES
FIRE AND EXPLOSION
Product Name: Prescription Treatment庐 brand 1600 X-clude庐 Timed Release Pyrethrum
EPA Reg. No.: 499-239 Flash Point (TOC): None (aerosol concentrate)
Product Code(s) 09-1620 (12 x 20 oz.) Explodibility Limits in Air (% by volume):
EPA Signal Word: CAUTION Lower (LEL) = 1.8% Upper (UEL) = 9.5%
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc. NFPA 30B Flammability: Level 1 Aerosol
3568 Tree Court Industrial Blvd. UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
St. Louis MO 63122-6682
Contents under pressure. Exposure to temperatures above 130掳F may cause bursting.
IN CASE OF FIRE
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Extinguisher Media: CO2, Dry Chemical, Foam, H2O
COMPOSITION INFORMATION Special Fire Fighting Procedures: None required 鈥? water based formulation
ACTIVE INGREDIENTS (2.836%) % CAS NO.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Pyrethrins 0.300% 8003-34-7
Piperonyl Butoxide, Technical 2.200% 51-03-6
IN CASE OF SPILL OR LEAK
n-Octyl Bicycloheptene Dicarboximide 0.336% 113-48-4
If container begins to leak (through puncture, etc.), eliminate all ignition sources and allow to
OTHER INGREDIENTS* (97.164%) % CAS NO. discharge completely in well ventilated area, then dispose of as directed below.
Petroleum Distillate proprietary 64742-47-8 This product contains the Comprehensive Environmental Response, Compensation, and Liability Act
Nonylphenol Ethoxylate proprietary 9016-18-5 (CERCLA) listed chemical Pyrethrins which has a reportable quantity (RQ) of 1 lb. A release of more
Propane proprietary 74-98-6 than 333 lbs. of this product (approximately 266 cans) is reportable to the National Response Center
(800-424-8802).
Isobutane proprietary 75-28-5
Emergency Telephone Number of Chemtrec: (800) 424-9300 (for transportation spills)
* All ingredients may not be listed. Ingredients not listed do not meet the reporting requirements of the
PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
OSHA Hazard Communication Standard (HCS) as specified in 29 CFR 1910.1200.
Eyes: Use proper protection 鈥? safety glasses are recommended.
EXPOSURE INFORMATION
Skin: Wear chemical resistant gloves. (Good practice requires that gross amounts of any chemical be
OSHA PEL ACGIH TLV
removed from the skin as soon as practical, especially before eating or smoking.)
Material STEL TWA STEL TWA Inhalation: Use of a respirator may be appropriate when working with spills in enclosed or confined
10 mg/m3 5 mg/m3 spaces, or when prolonged exposure to product vapor or spray mist may occur. When using a
Pyrethrins NE NE
respirator, wear a NIOSH approved respirator with an organic vapor (OV) cartridge or canister with any
Piperonyl Butoxide, NE NE NE NE
R or P prefilter.
Technical
WASTE DISPOSAL METHOD
n-Octyl Bicycloheptene NE NE NE NE
Dicarboximide Do not contaminate water, food or feed by storage or disposal of wastes. Take full or leaking containers
to a local disposal company for biological treatment or incineration. Review all local, state, and federal
Petroleum Distillate* NE 500 ppm NE NE
regulations concerning health and pollution to determine approved disposal procedures. NEVER
Nonylphenol Ethoxylate NE NE NE NE
PLACE WASTES DOWN ANY INDOOR OR OUTDOOR DRAIN OR SEWER.
Propane NE NE NE 1,000 ppm
Isobutane NE NE NE 1,000 ppm SECTION 7. HANDLING AND STORAGE
* TWA recommended by ingredient supplier = 166 ppm
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
Keep out of reach of children. CAUTION: May cause eye irritation. May be absorbed through the skin.
SECTION 3. HAZARDS IDENTIFICATION
Avoid contact with skin, eyes or clothing. Wash thoroughly with soap and water after handling and
NOTES TO PHYSICIAN before smoking or eating. Remove contaminated clothing and wash before reuse.
Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia. PHYSICAL OR CHEMICAL HAZARDS
SIGNS/SYMPTOMS OF EXPOSURE Flammable: Contents under pressure. Keep away from heat, sparks and open flame. Do not puncture
or incinerate container. Exposure to temperatures above 130掳F may cause bursting. Do not spray
A few cases of extrinsic asthma have been reported for Pyrethrum. Product may produce eye irritation;
directly into any electronic equipment such as radios, televisions, computers, etc. Do not use this
avoid contact with eyes. Prolonged exposure may cause skin irritation; avoid contact with skin.
product in electrical equipment (where there is exposed wiring or contact points) due to the possibility
ROUTES OF ENTRY
of short circuits and shock hazard. Product should only be used when can temperature is above 60掳F.
Primary: Ingestion Secondary: Skin Tertiary: Inhalation
If can temperature is below 60掳F, store at room temperature until a temperature above 60掳F is reached.
HAZARDOUS DECOMPOSITION PRODUCTS STORAGE
Thermal decomposition in open flame will result in possible toxic substances.
Do not contaminate water, food or feed by storage. Store in a cool, dry area away from heat or open
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS flame and inaccessible to children.
Contents under pressure. Exposure to temperatures above 130掳F may cause bursting.
SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION
SECTION 4. FIRST AID MEASURES
Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours.
Have the product container or label with you when calling a poison control center or doctor or going PERSONAL PROTECTIVE EQUIPMENT (PPE)
for treatment. Describe symptoms and follow the advice given.
Respiratory Protection: None required for typical use exposure. See Section 6 for atypical
Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting unless told to exposures.
do so by a poison control center or doctor. Do not give ANY liquid to the person. Do not give anything
Protective Gloves: None required. Chemical resistant gloves are recommended if prolonged or
by mouth to an unconscious person.
repeated skin contact is likely. (Good practice requires that gross amount of any chemical be removed
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give from the skin as soon as practical, especially before eating or smoking.)
artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor
Eye Protection: None required. Use of safety glasses is recommended.
for further treatment advice.
Other Protective Equipment: None required
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
VENTILATION
minutes. Call a poison control center or doctor for treatment advice.
Local Exhaust: None required
Eye Contact: Hold eyes open and rinse slowly and gently with water for 15-20 minutes. Remove
Mechanical: Provide adequate ventilation of treatment area.
contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control
center or doctor for treatment advice. Special: None required
Note to Physician: Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia. Other: None required
Medical Conditions Generally Aggravated by Exposure: None known
Emergency Telephone Number of Prosar: 800-225-3320 (for medical emergencies.)
Page 1 of 2
MATERIAL SAFETY DATA SHEET
Prescription Treatment 庐 brand 1600 X-clude 庐 Timed Release Pyrethrum
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES SECTION 14. TRANSPORT INFORMATION
Appearance: Beige-yellow liquid spray Odor: Characteristic Pyrethrin odor SHIPMENT BY GROUND WITHIN U.S. (DOT CLASSIFICATION)
Proper Shipping Description: Consumer Commodity, ORM-D
Solubility in Water: Disperses Vapor Pressure: 50 psig @ 70掳F
Package Marking: Consumer Commodity, ORM-D
Viscosity: NE Vapor Density: NA
Package Labeling: None required
Boiling Point: NA Freezing/Melting Point: NE
Certified Packaging: Not required
pH: 6.0 鈥? 7.0 Density: 0.995 g/ml @ 20掳C Other Requirements or Instructions: None required
SHIPMENT BY WATER (IMDG CLASSIFICATION)
SECTION 10. STABILITY AND REACTIVITY Proper Shipping Description: Aerosols, 2.1, UN 1950
REACTIVITY Package Marking: Dangerous Goods in Limited Quantities of class 2.1
Package Labeling: None required
Stability: Stable
Certified Packaging: Not required
Conditions to Avoid: Do not spray into open flame or onto very hot surfaces.
Other Requirements or Instructions: None required
Incompatibility (Material to Avoid): None known
SHIPMENT BY AIR (IATA CLASSIFICATION)
Hazardous Polymerization: Will not occur
HAZARDOUS DECOMPOSITION PRODUCTS Proper Shipping Description: Aerosols, Flammable, 2.1, UN 1950
Package Marking: Aerosols, Flammable, UN 1950, LTD. QTY.
Thermal decomposition in open flame will result in possible toxic substances.
Package Labeling: Class 2, Flammable Gas
SECTION 11. TOXOLOGICAL INFORMATION Certified Packaging: Not required
Other Requirements or Instructions: Complete air bill with packing instruction 鈥淵203, ERG code 10L鈥?
ROUTES OF ENTRY
Primary: Inhalation Secondary: Skin Tertiary: Ingestion
SECTION 15. REGULATORY INFORMATION
ACUTE
CERCLA
Eyes: Product causes substantial but temporary eye irritation (Category II).
This product contains the CERCLA listed chemical Pyrethrins which has a reportable quantity (RQ) of 1 lb.
Skin: Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
SARA TITLE III SECTION 311/312 HAZARD CLASS
Primary skin irritation index average score = 0.1 (essentially non-irritating 鈥? Categor IV). Product was
considered 鈥渟ensitizing鈥? when tested on guinea pigs. Acute dermal toxicity (rabbits) LD50 > 5,000 This product has been reviewed according to the EPA 鈥淗azard Categories鈥? promulgated under Section
mg/kg (Category IV). 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is
Ingestion: Acute oral toxicity (rats) LD50 > 1,300 mg/kg (Category III). considered, under applicable definitions, to meet the following categories:
Inhalation: Unlikely due to product being pressurized and producing particles large enough not to Acute Health Hazard
be respirable. Acute inhalation toxicity (rats) LC50 > 3.1 mg/L (Category IV). Fire Hazard
CHRONIC / CARCINOGENICITY Release of Pressure (Puncture) Hazard
Neither this product nor any of its ingredients are classified as carcinogens by the National Toxicity SARA TITLE III SECTION 313 CHEMICALS
Program (NTP), the International Agency for Research on Cancer (IARC) or the Occupational Safety This product contains the following substances subject to the reporting requirements of Title III of the
and Health Administration (OSHA). Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) and/or 40 CFR Part 372:
REPRODUCTIVE TOXICITY Piperonyl Butoxide (CAS #51-03-6) 2.2% by weight
This product contains N-Methylpyrrolidone, a chemical known by the state of California to be a TSCA
reproductive hazard.
All components of this product are listed or excluded from listing on the US Toxic Substance Control
Act (TSCA) Chemical Substance Inventory.
SECTION 12. ECOLOGICAL INFORMATION
SECTION 16. OTHER INFORMATION
This product is toxic to fish, birds and other wildlife. Do not apply directly to water, to areas where
surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate
NFPA HEALTH RATING INFORMATION KEY:
water by cleaning of equipment or disposal of wastes.
HEALTH 鈥? 1 FLAMMABILITY 鈥? 1 REACTIVITY 鈥? 1 4 = Severe
SECTION 13. DISPOSAL CONSIDERATION HMIS HAZARD RATING INFORMATION1 = SLIGHT 3 = Serious
HEALTH 鈥? 1 FLAMMABILITY 鈥? 1 REACTIVITY 鈥? 1 2 = Moderate
Do not contaminate water, food or feed by disposal. Dispose of container and wastes in accordance
1 = Slight
with all federal, state and local regulations.
0 = Minimal
Container Disposal: Do not puncture or incinerate! Empty container by using the product according
to the label directions. Offer empty container for recycling, if available, or place in trash if allowed by
state and local regulations. If container is partly full, contact your local solid waste agency or call
1-800-CLEANUP for disposal instructions.
Waste Disposal: Wastes resulting from the use of this product may be disposed of on site or at an
approved waste disposal facility.
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made
with respect to the information contained herein. For automatic MSDS updates, register at www.wmmg.com.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen customer service department at 800-777-8570.
NA 鈥? Not Applicable Effective Date: 05/25/05
NE 鈥? Not Established Review Date: NA
PEL 鈥? Permissible Exposure Limit Supersedes: 11/26/03
TLV 鈥? Threshold Limit Value Code: 214-099
STEL 鈥? Short Term Exposure Limit (15 min.) Text ID: 060119-3
TWA 鈥? Time Weighted Average (8 hrs.) WMG Part No: 19-0767-02
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