Part No.: 19-0119-06
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand 221L Residual Insecticide
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (Prosar) TRANSPORTATION: 800-424-9300 (Chemtrec)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION SECTION 5. FIRE FIGHTING MEASURES
Prescription Treatment庐 brand 221L Residual Insecticide
Product Name: FIRE AND EXPLOSION
Flash Point (TCC): 鈮? 65掳F
EPA Reg. No.: 499-473
Product Code(s): 02-0210 (12 x 17.5 oz) Flame Projection: >18'' with no flashback
EPA Signal Word: CAUTION Explodibility Limits in Air (% by volume):
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc. Lower (LEL) = NE Upper (UEL) = NE
3568 Tree Court Industrial Blvd. NFPA 30B Flammability: Level 3 Aerosol
St. Louis MO 63122-6682 UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
Contents under pressure. Exposure to temperatures above 130掳F may cause bursting.
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS IN CASE OF FIRE
Extinguisher Media: CO2, dry chemical, foam
COMPOSITION INFORMATION
Special Fire Fighting Procedures: Fire fighting personnel should wear full protec-
ACTIVE INGREDIENT (0.05%) % CAS NO.
tive equipment and positive pressure self-contained breathing apparatus.
位-Cyhalothrin 0.05 91465-08-6
OTHER INGREDIENTS* (99.95%) % CAS NO.
SECTION 6. ACCIDENTAL RELEASE MEASURES
2-propanol proprietary 67-63-0
Petroleum Distillate > 10.00 64742-47-8 IN CASE OF SPILL OR LEAK
* All ingredients may not be listed. Ingredients not listed do not meet the reporting requirements of the If container begins to leak (through puncture, etc.), eliminate all ignition sources and
OSHA Hazard Communication Standard (HCS) as specified in 29 CFR 1910.1200. allow to discharge completely in a well ventilated area, then dispose of as directed below.
This product contains no Comprehensive Environmental Response, Compensation and
EXPOSURE INFORMATION
Liability Act (CERCLA) listed chemicals. Releases of this product are NOT reportable to
OSHA PEL ACGIH TLV
the National Response Center.
MATERIAL STEL TWA STEL TWA
Emergency Telephone Number of Chemtrec: 800-424-9300 (for transportation spills)
位-Cyhalothrin NE NE NE NE
PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
2-propanol NE 400 ppm 500 ppm 400 ppm
Eyes: Use proper protection 鈥? safety glasses are recommended.
Petroleum Distillate* NE 500 ppm NE NE
Skin: Wear chemical-resistant gloves. (Good practice requires that gross amounts of any
* TWA recommended by ingredient supplier = 166 ppm
chemical be removed from the skin as soon as practical, especially before eating or
smoking.)
SECTION 3. HAZARDS IDENTIFICATION Inhalation: Use of a respirator may be appropriate when working with spills in enclosed
NOTES TO PHYSICIAN or confined spaces, or when prolonged exposure to product vapor or spray mist may
No specific antidote is available. Treat the patient symptomatically. Contains petroleum occur. When using a respirator, wear a NIOSH approved respirator with an organic vapor
distillate 鈥? vomiting may cause aspiration pneumonia. (OV) cartridge or canister with any R or P prefilter. See 29 CFR 1910.134 for respiratory
protection, training and testing requirements.
SIGNS/SYMPTOMS OF EXPOSURE
WASTE DISPOSAL METHOD
Product causes moderate eye irritation. Prolonged exposure may cause skin irritation.
Do not contaminate water, food or feed by storage or disposal of wastes. Take full or leak-
ROUTES OF ENTRY
ing containers to a local disposal company for biological treatment or incineration.
Primary: Skin Secondary: Ingestion Tertiary: Inhalation
Review all local, state and federal regulations concerning health and pollution to
HAZARDOUS DECOMPOSITION PRODUCTS
determine approved disposal procedures. NEVER PLACE WASTES DOWN ANY INDOOR
Thermal decomposition in open flame may result in halogen acids and carbon dioxide.
OR OUTDOOR DRAIN OR SEWER.
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
Contents under pressure. Exposure to temperatures above 130掳F may cause bursting.
SECTION 7. HANDLING AND STORAGE
SECTION 4. FIRST AID MEASURES HAZARDS TO HUMANS AND DOMESTIC ANIMALS
Keep out of reach of children. CAUTION - Harmful if swallowed. Causes moderate eye
Have the product container or label with you when calling a poison control center or doctor
irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after
or going for treatment. Describe any symptoms and follow the advice given.
handling.
Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting
OTHER PRECAUTIONS
unless told to do so by a poison control center or doctor. Do not give ANY liquid to the
Do not apply this product in hospital patient rooms while occupied or in any rooms occu-
person. Do not give anything by mouth to an unconscious person.
pied by the elderly or infirm. Do not apply to classrooms when in use. Do not apply
Eye Contact: Hold eyes open and rinse slowly and gently with water for 15 - 20 min.
directly to food.
Remove contact lenses, if present, after the first 5 min, then continue rinsing eyes. Call
PHYSICAL OR CHEMICAL HAZARDS
a poison control center or doctor for treatment advice.
Flammable. Contents under pressure. Keep away from heat, sparks and open flame.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of
Do not puncture or incinerate container. Exposure to temperatures above 130掳F may
water for 15 - 20 min. Call a poison control center or doctor for treatment advice.
cause bursting. Do not spray on plastic, painted or varnished surfaces. Do not spray
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an
directly into electronic equipment such as radios, televisions, computers, etc.
ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a
STORAGE
poison control center or doctor for further treatment advice.
Do not contaminate water, food or feed. Store in a cool, dry place away from heat or open
Note to Physician: No specific antidote is available. Treat the patient symptomatically.
flame and inaccessible to children.
Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia.
Medical Conditions Generally Aggravated by Exposure: None known
Emergency Telephone Number of Prosar: 800-225-3320 (for medical emergencies)
Page 1 of 2
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand 221L Residual Insecticide
SECTION 8. EXPOSURE CONTROL/PERSONAL PROTECTION SECTION 12. ECOLOGICAL INFORMATION
This product is toxic to fish, birds and other wildlife. Do not apply directly to water, or to areas
PERSONAL PROTECTIVE EQUIPMENT (PPE)
where surface waster is present or to intertidal areas below the mean high water mark. Do not
Respiratory Protection: None required when used according to label directions. For
contaminate water by cleaning of equipment or disposal of equipment wash waters. Apply
prolonged exposure or if used in enclosed or confined areas, a NIOSH approved respi-
this product only as specified on the label. Spray will damage plant foliage.
rator with an organic vapor (OV) cartridge or canister with any R or P prefilter may be
used. See 29 CFR 1910.134 for respiratory protection, training, and testing requirements.
SECTION 13. DISPOSAL CONSIDERATION
Protective Gloves: Chemical-resistant gloves are recommended if prolonged or
repeated skin contact is likely. (Good practice requires that gross amount of any chemi- Do not contaminate water, food or feed by disposal of container or waste. Dispose of
cal be removed from the skin as soon as practical, especially before eating or smoking.) container and waste in accordance with all federal, state and local regulations.
Eye Protection: Use proper protection - safety glasses are recommended. Container Disposal: Do not puncture or incinerate! Empty container by using the
Other Protective Equipment: None required product according to the label directions. Offer empty container for recycling, if available,
VENTILATION or place in trash if allowed by state and local regulations. If container is partly full,
Local Exhaust: None required contact your local solid waste agency for disposal instructions.
Mechanical: None required Waste Disposal: Wastes resulting from the use of this product may be disposed of on
Special: None required site or at an approved waste disposal facility.
Other: Provide adequate ventilation of treatment area.
SECTION 14. TRANSPORT INFORMATION
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
SHIPMENT BY GROUND WITHIN U.S. (DOT CLASSIFICATION)
Appearance: Clear mist Odor: Slight odor Proper Shipping Description: Consumer Commodity ORM-D
Solubility in Water: NA Vapor Pressure: 90 - 100 psig Package Marking: Consumer Commodity ORM-D
Viscosity: 1 cps @ 77掳F Vapor Density: NE Package Labeling: None required
Boiling Point: NE Freezing/Melting Point: NE Certified Packaging: None required
pH: 10.5 @ 77掳F (1% in water) Density: 0.78 g/ml @ 68掳F (H2O = 1.0) Product in unopened original packaging is compliant with all regulations for ground
shipment within the U.S. WMG disclaims any liability for claims or damages that may result
SECTION 10. STABILITY AND REACTIVITY from shipment by other means. Packages offered or intended for other modes of transportation
are subject to additional requirements. Consult an appropriately trained shipping
REACTIVITY
professional before offering for shipment.
Stability: Indefinite when used according to label directions.
Conditions to Avoid: Do not spray into open flame or onto very hot surfaces.
SECTION 15. REGULATORY INFORMATION
Incompatibility (Materials to Avoid): Strong oxidizing agents
Hazardous Polymerization: Will not occur CERCLA
HAZARDOUS DECOMPOSITION PRODUCTS This product contains no CERCLA listed chemicals.
Thermal decomposition in open flame may result in halogen acids and carbon dioxide. SARA TITLE III SECTION 311/312 HAZARD CLASS
This product has been reviewed according to the EPA 鈥淗azard Categories鈥? promulgated
SECTION 11. TOXICOLOGICAL INFORMATION under Section 311 and 312 of the Superfund Amendment and Reauthorization Act of
1986 (SARA Title III) and is considered, under applicable definitions, to meet the follow-
ROUTES OF ENTRY
ing categories:
Primary: Skin Secondary: Ingestion Tertiary: Inhalation
Immediate (Acute) Health Hazard
ACUTE
Fire Hazard
Eyes: Product causes moderate eye irritation in rabbits. Corneal opacity, iritis, and
Release of Pressure (Puncture) Hazard
conjunctivitis were observed, all were reversible within 10 days.
SARA TITLE III SECTION 313 CHEMICALS
Skin: Product is slightly irritating to the skin of rabbits. Acute dermal LD50 > 5,000 mg/kg
This product contains no substances subject to the reporting requirements of Section
(rabbits). Primary skin irritation index = 1.83 (rabbits). Product is not a sensitizer when
313 of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) or
tested on guinea pigs.
40 CFR Part 372 in concentrations above the de minimis concentration level.
Ingestion: Acute oral toxicity LD50 > 5,000 mg/kg (rats).
TSCA
Inhalation: Unlikely due to product being pressurized and producing particles large
All components of this product are listed or excluded from listing on the US Toxic
enough not to be respirable. Acute inhalation toxicity LC50 > 2.40 mg/L (rats).
Substance Control Act (TSCA) Chemical Substance Inventory.
CHRONIC / CARCINOGENICITY
Neither this product nor any of its ingredients are classified as carcinogens by the National
SECTION 16. OTHER INFORMATION
Toxicity Program (NTP), the International Agency for Research on Cancer (IARC) or the
Occupational Safety and Health Administration (OSHA). NFPA HEALTH RATING INFORMATION KEY: 4 = Severe
HEALTH - 1 FLAMMABILITY - 2 REACTIVITY - 1 3 = High
2 = Moderate
HMIS HAZARD RATING SYSTEM
1 = Slight
HEALTH - 1 FLAMMABILITY - 2 REACTIVITY - 1
0 = Minimal
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made
with respect to the information contained herein.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570. For automatic MSDS
updates, register at www.wmmg.com.
WHITMIRE MICRO-GEN
NA - Not Applicable Effective Date: 12/06/07
RESEARCH LABORATORIES, INC.
NE - Not Established Review Date: 12/06/07
PEL - Permissible Exposure Limit Supersedes: 7/28/06
TLV - Threshold Limit Value Text ID: 080424-2
STEL - Short Term Exposure Limit (15 min) Code(s) #: 191-047, 214-100
Page 2 of 2
TWA - Time Weighted Average (8 hr) Part No.: 19-0119-06
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