MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand
WHITMIRE MICRO-GEN (800) 777-8570 (8:00 A.M. to 4:30 P.M. CST)
RESEARCH LABORATORIES, INC. EMERGENCY PHONE NUMBERS:
ULD庐 BP-50
3568 TREE COURT IND. BLVD. MEDICAL: (800) 225-3320 PROSAR
Contact Insecticide
ST. LOUIS, MO 63122 TRANSPORTATION: (800) 424-9300 CHEMTREC
EFFECTIVE: FEBRUARY 7, 2000 EPA REG. NO.: 499-453
Formula 1
SECTION 6: SPILL OR LEAK PROCEDURES (cont聮d.)
SECTION 1: HAZARDOUS INGREDIENTS
Waste Disposal Method: Do not contaminate water, food or feed by disposal. Pesticide Dis-
ACGIH ACGIH OSHA
posal: Wastes resulting from the use of this product may be disposed of on site or at an ap-
Active Ingredients: TLV/TWA STEL PEL OTHER
Pyrethrins: 0.5% (CAS #8003-34-7) 5mg/m3 NE NE proved waste disposal facility. Container Disposal: Triple rinse (or equivalent). Then offer for
Piperonyl Butoxide, Technical: 5.0% recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other proce-
(CAS #51-03-6) NE NE NE dures approved by state and local authorities.
Inert Ingredients: In case of spillage, this product is subject to reporting requirements of the Comprehensive
Petroleum Distillate: 94.50% Environmental Response, Compensation, and Liability Act (CERCLA).
(CAS #64742-47-8) NE NE NE 300 ppm
SECTION 7: SPECIAL PROTECTION INFORMATION
Supplier Rec.
Respiratory Protection: Use a respiratory device as recommended by NIOSH/MSHA for
All components of this product are listed or excluded from listing on the US Toxic Substances
protection against organic vapors and pesticides.
Control Act (TSCA) Chemical Substance Inventory.
Ventilation:
SECTION 2: PHYSICAL DATA Local Exhaust: Ventilate area before reentering. Do not remain in enclosed areas without
appropriate respiratory protection.
Boiling Point: > 200oF Evaporation Rate (Butyl acetate = 1): NE
Protective Gloves: If prolonged or repeated contact is possible; any impervious material.
Specific Gravity (H20 = 1): 0 .8 Solubility in Water: Negligible
Eye Protection: Chemical worker聮s splash proof goggles.
Vapor Pressure (mmHg): < 0.1 Appearance and Odor: Clear yellow liquid/
Other Protective Equipment: Rubber boots, full legged pants, long sleeve shirts. Launder
Vapor Density (Air = 1): 6 mild solvent odor.
contaminated equipment or clothing before reuse.
Viscosity: 3.04 Melting Point: NE
SECTION 8: SPECIAL PRECAUTIONS
SECTION 3: FIRE AND EXPLOSION HAZARD DATA
Precautions to be taken in handling and storage: Hazards to Humans and Domestic Animals:
Flashpoint (Method Used): 191oF (TCC)
Keep out of reach of children. CAUTION: Harmful if swallowed or absorbed through skin.
Flammable Limits: LEL: 1.3; UEL: 8.1 @ 77oF (for petroleum distillate)
Causes moderate eye irritation. Avoid contact with eyes, skin or clothing. Prolonged or
Extinguishing Media: Foam; Dry Chemical; Water
frequently repeated skin contact may cause allergic reaction in some individuals. Wash
Firefighting Procedures: Treat as an oil fire. Use water spray to cool fire exposed surfaces and to
thoroughly with soap and water after handling. Do not apply directly to food. Foods should be
protect personnel. Isolate 聯fuel聰 supply from fire. Use foam, dry chemical or water spray to
removed or covered during treatment. All food processing surfaces and equipment should be
extinguish fire. Avoid spraying water directly into storage containers due to danger of boilover.
covered during treatment or washed with an effective cleaning compound followed by a
This liquid is volatile and gives off invisible vapors. Either the liquid or vapor may settle in low
potable water rinse. Do not apply while food processing is underway. In the home, all food
areas or travel some distance along the ground or surface to ignition sources where they may
processing surfaces, dishes and utensils should be covered during treatment, or thoroughly
ignite or explode.
washed before use. Remove pets, birds, cover fish aquariums and turn off air pump motor
Unusual Fire and Explosion Hazards: Static Discharge, material can accumulate static
before spraying. Environmental Hazards: This product is toxic to fish. Keep out of lakes,
charges which can cause an indendiary electrical discharge. Liquid runoff to sewers may
streams or ponds. Do not apply where runoff is likely to occur. Do not apply when weather
create fire/explosion hazard.
conditions favor drift from areas treated. Do not contaminate water when disposing of
NFPA Flammability: Class III A Combustible Liquid
equipment washwaters. Apply this product only as specified on its label. Physical and
SECTION 4: HEALTH HAZARD DATA Chemical Hazards: Do not use or store near heat or open flame. Note: Some furniture finishes,
and particularly plastics, can be damaged by petroleum based insecticides. To avoid damage,
Threshold Limit Value: NE
cover those items and do not spray directly. If in doubt, test by applying this material to an
Routes of Entry:
inconspicuous area before spraying. Storage: Do not contaminate water, food or feed by
Inhalation? Skin? Ingestion?
storage. Store in a cool, dry area away from children, heat, sparks or open flame.
X X
Health Hazard (Acute and Chronic) - Signs and Symptoms of Exposure:
SECTION 9: HEALTH RATING INFORMATION (NFPA)
Eye: Direct contact of product with eyes can cause irritation. Product produced minimal
Health - 1 Flammability - 2 Reactivity - 0
irritation in albino rabbits reversible in 24 hours.
Skin: Prolonged or repeated contact of product with skin may cause irritation. Acute dermal
SECTION 10: SARA TITLE III/SEC. 313 SUPPLIER NOTIFICATION
toxicity LD50 > 2000mg/kg.
Ingestion & Inhalation: Product spray mist, fog or vapor may cause irritation to nose, throat This product contains the following toxic chemicals subject to the reporting requirements of
and lungs if adequate ventilation is not employed. If taken internally, aspiration of liquid Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 and of 40
product can cause chemical pneumonitis. Acute oral toxicity LD50 > 5000mg/kg. Acute CFR 372:
inhalation LC50 = 7.0mg/L. CAS# Chemical Name % by weight
Carcinogenicity: 51-03-6 Piperonyl Butoxide 5.0
NTP? IARC Monograph? OSHA Regulated?
SECTION 11: DOT SHIPPING INFORMATION
No No No
Emergency and First Aid Procedures:
< 25 gal.:
If Swallowed: Contains petroleum distillate. Call a physician or poison control center
Proper Shipping Name: Liquid Insecticide (Not Regulated).
immediately. Do not induce vomiting - vomiting may cause aspiration pneumonia.
Hazard Class: NA
If Inhaled: Remove victim to fresh air and apply respiration if needed.
If on Skin: Remove contaminated clothing, wash promptly with soap and water.
> 25 gal.:
If in Eyes: Flush eyes with plenty of water.
Proper Shipping Name: Environmentally Hazardous Substances, Liquid, NOS (Pyrethrin)
Medical Conditions Generally Aggravated by Exposure: None known.
Hazard Class: 9 UN I.D. No.: UN 3082 Packing Group: III RQ (1 lb.)
SECTION 5: REACTIVITY DATA
Stability: Stable.
Conditions to Avoid: None known.
Incompatibility (Materials to Avoid): Strong oxidizing agents.
NA - Not Applicable Product Code: 02-4912 (4 x 1 gallon)
Hazardous Decomposition Products: When exposed to fire, produces normal products of
NE - Not Established 02-4915 (2 x 2.5 gallon)
combustion.
PEL - Permissible Exposure Limit 02-4914 (1 x 55 gallon)
Hazardous Polymerization: Will not occur.
ACL - Acceptable Ceiling Level Prepared by: Dana M. Thomas
SECTION 6: SPILL OR LEAK PROCEDURES MPC - Maximum Peak Concentration
Steps to be taken in case material is released or spilled: Eliminate all ignition sources. Do
not let spilled or leaking material enter watercourse. May be toxic to aquatic life. Absorb with
oil-dry or similar inert material. Sweep or scrape up and containerize. Wear/use appropriate
protective equipment.
Emergency Telephone Number of Chemtrec: (800) 424-9300
(for transportation spills)
P/N 19-0782
SLBP50
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