Part No.: 19-0137-02
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 ULD庐 BP-100 PLUS HYDROPRENE IGR
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (Prosar) TRANSPORTATION: 800-424-9300 (Chemtrec)
Medical Conditions Generally Aggravated by Exposure: None known
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Emergency Telephone Number of Prosar: 800-225-3320 (for medical emergencies)
Product Name: Prescription Treatment ULD BP-100 PLUS HYDROPRENE IGR
庐 庐
EPA Reg. No.: 499-504 SECTION 5. FIRE FIGHTING MEASURES
Product Code(s): 02-4970 (4 x 1 gal)
FIRE AND EXPLOSION
EPA Signal Word: CAUTION
Flash Point (TCC): 182掳F
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc.
Flame Projection: NA
3568 Tree Court Industrial Blvd.
Explodibility Limits in Air (% by volume) for petroleum distillate:
St. Louis MO 63122-6682
Lower (LEL) = 1.3% Upper (UEL) = 8.1%
NFPA 30B Flammability: NA
SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
COMPOSITION INFORMATION Material can accumulate static charges which can cause an incendiary electrical dis-
ACTIVE INGREDIENT (6.706%) % CAS NO. charge. Liquid runoff to sewers may create fire/explosion hazard.
Hydroprene* 0.706 IN CASE OF FIRE
*S-Hydroprene [Ethyl (2E,4E)-(7S)-3,7,11- 65733-18-8 Extinguisher Media: Foam, Dry Chemical, Water
trimethyl-2,4-dodecadienoate] ............ 85% Special Fire Fighting Procedures: Treat as an oil fire. Use water spray to cool fire
*RS-Hydroprene [Ethyl (2E,4E)-(7RS)-3,7,11- 41096-46-2 exposed surfaces and to protect personnel. Isolate 鈥渇uel鈥? supply from fire. Use foam, dry
trimethyl-2,4-dodecadienoate] ............ 15% chemical or water spray to extinguish fire. Avoid spraying water directly into storage con-
Pyrethrins 1.000 8003-34-7 tainers due to danger of boil over. This liquid is volatile and gives off invisible vapors.
Piperonyl Butoxide, Technical 2.000 51-03-6 Either the liquid or vapor may settle in low areas or travel some distance along the ground
n-Octyl Bicycloheptene Dicarboximide 3.000 113-48-4 or surface to ignition sources where they may ignite or explode.
OTHER INGREDIENTS* (93.294%)
SECTION 6. ACCIDENTAL RELEASE MEASURES
Petroleum Distillate > 10.0 64742-47-8
IN CASE OF SPILL OR LEAK
* All ingredients may not be listed. Ingredients not listed do not meet the reporting requirements of the
If container begins to leak (through puncture, etc.), eliminate all ignition sources. Do not
OSHA Hazard Communication Standard (HCS) as specified in 29 CFR 1910.1200.
let spilled or leaking material enter watercourse. May be toxic to aquatic life. Absorb with
EXPOSURE INFORMATION oil-dry or similar inert material. Sweep or scrape up and containerize.
OSHA PEL ACGIH TLV This product contains the Comprehensive Environmental Response, Compensation and
MATERIAL STEL TWA STEL TWA Liability Act (CERCLA) listed chemical Pyrethrins which has a reportable quantity (RQ)
Hydroprene NE NE NE NE of 1 lb. A release of more than 100 lbs of this product (approx. 15 gal) is reportable to
Pyrethrins NE NE 10 mg/m鲁 5 mg/m鲁 the National Response Center (800-424-8802).
Piperonyl Butoxide, Technical NE NE NE NE Emergency Telephone Number of Chemtrec: 800-424-9300 (for transportation spills)
n-Octyl Bicycloheptene Dicarboximide NE NE NE NE PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
Petroleum Distillate* NE 500 ppm NE NE Eyes: Use proper protection 鈥? safety glasses are recommended.
* TWA recommended by ingredient supplier = 166 ppm Skin: Wear chemical-resistant gloves. (Good practice requires that gross amounts of any
chemical be removed from the skin as soon as practical, especially before eating or smoking.)
SECTION 3. HAZARDS IDENTIFICATION Inhalation: Use of a respirator may be appropriate when working with spills in enclosed or
confined spaces, or when prolonged exposure to product vapor or spray mist may occur.
NOTES TO PHYSICIAN
When using a respirator, wear a NIOSH approved respirator with an organic vapor (OV) car-
Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia.
tridge or canister with any R or P prefilter. See 29 CFR 1910.134 for respiratory protection,
SIGNS/SYMPTOMS OF EXPOSURE
training and testing requirements.
Direct contact with eyes can cause irritation. Prolonged or repeated contact of product with
WASTE DISPOSAL METHOD
skin may cause irritation. Product spray mist, fog or vapor may cause irritation to nose,
Do not contaminate water, food or feed by storage or disposal of wastes. Take full or leaking
throat and lungs. If taken internally, aspiration of liquid product may cause pneumonitis.
containers to a local disposal company for biological treatment or incineration. Review all local,
ROUTES OF ENTRY
state and federal regulations concerning health and pollution to determine approved disposal
Primary: Inhalation Secondary: Skin Tertiary: Ingestion
procedures. NEVER PLACE WASTES DOWN ANY INDOOR OR OUTDOOR DRAIN OR SEWER.
HAZARDOUS DECOMPOSITION PRODUCTS
When exposed to fire, produces normal products of combustion.
SECTION 7. HANDLING AND STORAGE
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
Material can accumulate static charges which can cause an incendiary electrical dis-
Keep out of reach of children. CAUTION 鈥? Avoid contact with skin, eyes or clothing.
charge. Liquid runoff to sewers may create fire/explosion hazard.
Prolonged or frequently repeated skin contact may cause allergic reactions in some indi-
viduals. In case of contact, immediately flush eyes or skin with plenty of water. Get med-
SECTION 4. FIRST AID MEASURES
ical attention if irritation persist. Contains petroleum distillate.
Have the product container or label with you when calling a poison control center or doctor
OTHER PRECAUTIONS
or going for treatment. Describe any symptoms and follow the advice given.
Do not apply directly to food. Do not apply while food processing is underway. Food should
Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting
be removed or covered during treatment. All food processing surfaces and equipment should
unless told to do so by a poison control center or doctor. Do not give ANY liquid to the
be covered or washed with and effective cleaning compound followed by a potable water
person. Do not give anything by mouth to an unconscious person.
rinse. In the home, all food processing surfaces, dishes and utensils should be covered dur-
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambu-
ing treatment or thoroughly washed before use. Remove pets, birds, and cover fish aquari-
lance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a poi-
ums and turn off air pump motor before spraying. In health care facilities, remove patients
son control center or doctor for further treatment advice.
prior to treatment. Thoroughly ventilate treated area for two hours before returning patients.
Eye Contact: Hold eyes open and rinse slowly and gently with water for 15 - 20 min.
PHYSICAL AND CHEMICAL HAZARDS
Remove contact lenses, if present, after the first 5 min, then continue rinsing eyes. Call
Do not use or store near heat or open flame. Do not use this product in or on electrical equip-
a poison control center or doctor for treatment advice.
ment due to the possibility of shock. Some furniture finishes and particularly plastics can be
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of
damaged by petroleum based insecticides. To avoid damage, cover those items and do not spray
water for 15 - 20 min. Call a poison control center or doctor for treatment advice.
directly. If in doubt, test by applying this material to an inconspicuous area before spraying.
Note to Physician: Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia.
Page 1 of 2
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 ULD庐 BP-100 PLUS HYDROPRENE IGR
STORAGE SECTION 13. DISPOSAL CONSIDERATION
Do not contaminate water, food or feed. Keep container tightly closed. Store unused prod-
Do not contaminate water, food or feed by disposal of container or waste. Dispose of con-
uct in original container only in cool, dry area out of reach of children and animals.
tainer and waste in accordance with all federal, state and local regulations.
Container Disposal: Empty container by using the product according to the label direc-
SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION tions. Do not reuse this container! Place empty container in trash or offer for recycling if
PERSONAL PROTECTIVE EQUIPMENT (PPE) available. If container is partly filled, call your local solid waste agency for disposal
Respiratory Protection: None required for typical use exposure. See Section 6 for atypical instructions. NEVER PLACE UNUSED PRODUCT DOWN ANY INDOOR OR OUTDOOR
exposure. For prolonged exposure or if used in enclosed or confined areas, a NIOSH approved DRAIN OR SEWER.
respirator with an organic vapor (OV) cartridge or canister with any R or P prefilter may be Waste Disposal: Wastes resulting from the use of this product may be disposed of on
used. See 29 CFR 1910.134 for respiratory protection, training and testing requirements. site or at an approved waste disposal facility. NEVER PLACE WASTES DOWN ANY
Protective Gloves: None required. Chemical-resistant gloves are recommended if prolonged INDOOR OR OUTDOOR DRAIN!
or repeated skin contact is likely. (Good practice requires that gross amounts of any chemical
be removed from the skin as soon as practical, especially before eating or smoking.) SECTION 14. TRANSPORT INFORMATION
Eye Protection: Use proper protection 鈥? safety glasses are recommended.
DOT CLASSIFICATION (15 GALLONS OR LESS)
Other Protective Equipment: None required
Proper Shipping Description: Liquid Insecticide (Not Regulated)
VENTILATION
Hazard Class: NA
Local Exhaust: None required
DOT CLASSIFICATION (MORE THAN 15 GALLONS)
Mechanical: None required
Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S.
Special: None required
Hazard Class: 9
Other: Do not remain in treated areas after application and ventilate thoroughly before
UN I.D. NO.: UN 3082
occupants are allowed to reenter.
Packing Group: III
Proper Shipping Description: Environmentally Hazardous Substance, Liquid, NOS
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES (Pyrethrin), 9, UN 3082, PG III, RQ
Appearance: Clear yellow liquid Odor: Mild solvent odor Package Labeling: Class 9 (Misc. Hazard)
Solubility in Water: NE Vapor Pressure: NE Package Marking: Environmentally Hazardous Substance, Liquid, NOS (Pyrethrin),
Viscosity: NE Vapor Density: NE UN 3082, RQ
Boiling Point: NE Freezing/Melting Point: NE Other Requirements: UN approved packaging required
pH: NE Density: 0.802 g/ml @ 68掳F Product in unopened original packaging is compliant with all regulations for ground shipment
within the U.S. WMG disclaims any liability for claims or damages that may result from shipment
SECTION 10. STABILITY AND REACTIVITY by other means. Packages offered or intended for other modes of transportation are subject to
additional requirements. Consult an appropriately trained shipping professional before offering
REACTIVITY
for shipment.
Stability: Stable
Conditions to Avoid: None known
SECTION 15. REGULATORY INFORMATION
Incompatibility (Material to Avoid): Strong oxidizing agents.
Hazardous Polymerization: Will not occur CERCLA
HAZARDOUS DECOMPOSITION PRODUCTS This product contains the CERCLA listed chemical Pyrethrins which has a reportable
When exposed to fire, produces normal products of combustion. quantity (RQ) of 1 lb.
SARA TITLE III SECTION 311/312 HAZARD CLASS
SECTION 11. TOXICOLOGICAL INFORMATION This product has been reviewed according to the EPA 鈥淗azard Categories鈥? promulgated under
Section 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title
ROUTES OF ENTRY
III) and is considered, under applicable definitions, to meet the following categories:
Primary: Inhalation Secondary: Skin Tertiary: Ingestion
Acute Health Hazard
ACUTE
Flammability Hazard
Eyes: Direct contact with eyes may cause irritation.
SARA TITLE III SECTION 313 CHEMICALS
Skin: Prolonged or repeated contact of product with skin may cause irritation. Acute der-
This product contains the following substances subject to the reporting requirements of
mal LD50 > 2,000 mg/kg (rabbits).
Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title III)
Ingestion: If taken internally, Aspiration of liquid product can cause chemical pneu-
and/or 40 CFR Part 372:
monitis. Acute oral toxicity LD50 > 5,000 mg/kg (rats).
Piperonyl Butoxide, Technical (CAS #51-03-6) 2.0% by weight
Inhalation: Product spray mist, fog or vapor may cause irritation to nose, throat and
lungs if adequate ventilation is not employed. Acute inhalation LC50 > 7.7 mg/L (rats). TSCA
All components of this product are listed or excluded from listing on the US Toxic
CHRONIC / CARCINOGENICITY
Substance Control Act (TSCA) Chemical Substance Inventory.
Neither this product nor any of its ingredients are classified as carcinogens by the
National Toxicity Program (NTP), the International Agency for Research on Cancer (IARC)
SECTION 16. OTHER INFORMATION
or the Occupational Safety and Health Administration (OSHA).
HMIS HAZARD RATING INFORMATION KEY: 4 = Severe
SECTION 12. ECOLOGICAL INFORMATION HEALTH - 1 FLAMMABILITY - 2 REACTIVITY - 0 3 = High
2 = Moderate
This product is toxic to aquatic invertebrates. Do not apply directly to water, or to areas where HMIS HAZARD RATING INFORMATION
1 = Slight
surface water is present or to intertidal areas below the mean high water mark. Do not apply HEALTH - 1 FLAMMABILITY - 2 REACTIVITY - 0
0 = Minimal
where runoff is likely to occur. Do not contaminate water when disposing of rinsate or equip-
ment washwaters.
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with
respect to the information contained herein. For automatic MSDS updates, register at www.wmmg.com.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable Part No. 19-0137-02
WHITMIRE MICRO-GEN
NE - Not Established Effective Date: 04/04/07
PEL - Permissible Exposure Limit Review Date: 04/04/07
RESEARCH LABORATORIES, INC.
TLV - Threshold Limit Value Supersedes: 04/19/04
STEL - Short Term Exposure Limit (15 min) Text ID: 070604-20
TWA - Time Weighted Average (8 hr) Code #: 203-057
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