Part No.: 19-0767-03
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand 1600 X-clude庐 Timed Release Pyrethrum
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (Prosar) TRANSPORTATION: 800-424-9300 (Chemtrec)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION SECTION 5. FIRE FIGHTING MEASURES
Product Name: Prescription Treatment庐 brand 1600 X-clude庐 FIRE AND EXPLOSION
Timed Release Pyrethrum Flash Point (TCC): None (aerosol concentrate)
EPA Reg. No.: 499-239 Flame Projection: None
Product Code(s): 09-1620 (12 x 20 oz) Explosibility Limits of Propellant in Air (% by volume):
EPA Signal Word: CAUTION Lower (LEL) = 1.8% Upper (UEL) = 9.5%
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc. NFPA 30B Flammability: Level 1 Aerosol
3568 Tree Court Industrial Blvd. UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
St. Louis MO 63122-6682 Contents under pressure. Exposure to temperatures above 130掳F may cause bursting.
IN CASE OF FIRE
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS Extinguisher Media: Carbon Dioxide, Dry Chemical, Foam, Water
Special Fire Fighting Procedures: Fire fighting personnel should wear full protec-
COMPOSITION INFORMATION
tive equipment and positive pressure self-contained breathing apparatus (SCBA)
ACTIVE INGREDIENTS (2.836%) % CAS NO.
approved for firefighting.
Pyrethrins 0.300 8003-34-7
Piperonyl Butoxide, Technical 2.200 51-03-6
SECTION 6. ACCIDENTAL RELEASE MEASURES
n-Octyl Bicycloheptene Dicarboximide 0.336 113-48-4
IN CASE OF SPILL OR LEAK
OTHER INGREDIENTS* (97.164%) % CAS NO.
If container begins to leak (through puncture, etc.), eliminate all ignition sources and
Petroleum Distillate > 10.0 64742-47-8
allow to discharge completely in well ventilated area, then dispose of as directed below.
Hydrocarbons C3-C4 proprietary 68476-40-4
This product contains the Comprehensive Environmental Response, Compensation and
* All ingredients may not be listed. Ingredients not listed do not meet the reporting requirements of the
Liability Act (CERCLA) listed chemical Pyrethrins which has a reportable quantity (RQ)
OSHA Hazard Communication Standard (HCS) as specified in 29 CFR 1910.1200.
of 1 lb. A release of more than 333 lbs of this product (approx. 266 cans) is reportable
EXPOSURE INFORMATION
to the National Response Center (800-424-8802).
OSHA PEL ACGIH TLV
Emergency Telephone Number of Chemtrec: 800-424-9300 (for transportation spills)
MATERIAL STEL TWA STEL TWA
PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
Pyrethrins NE NE 10 mg/m鲁 5 mg/m鲁
Eyes: Use proper protection 鈥? safety glasses are recommended.
Piperonyl Butoxide, Technical NE NE NE NE
Skin: Wear chemical-resistant gloves (such as rubber or waterproof) long-sleeved shirt
n-Octyl Bicycloheptene Dicarboximide NE NE NE NE
and long pant, shoes plus socks (Good practice requires that gross amounts of any chem-
Petroleum Distillate* NE 500 ppm NE NE
ical be removed from the skin as soon as practical, especially before eating or smoking).
Hydrocarbons C3-C4 NE NE NE 1,000 ppm
Inhalation: Use of a respirator may be appropriate when working with spills in enclosed
* TWA recommended by ingredient supplier = 166 ppm
or confined spaces, or when prolonged exposure to product vapor or spray mist may
occur. When using a respirator, wear a NIOSH approved respirator with an organic vapor
SECTION 3. HAZARDS IDENTIFICATION (OV) cartridge or canister with any R or P prefilter. See 29 CFR 1910.134 for respiratory
protection, training and testing requirements.
NOTES TO PHYSICIAN
WASTE DISPOSAL METHOD
Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia.
Do not contaminate water, food or feed by storage or disposal of wastes. Take full or
SIGNS/SYMPTOMS OF EXPOSURE
leaking containers to a local disposal company for biological treatment or incineration.
A few cases of extrinsic asthma have been reported for Pyrethrum. Product may produce eye
Review all local, state and federal regulations concerning health and pollution to
irritation; avoid contact with eyes. Prolonged exposure may cause skin irritation; avoid
determine approved disposal procedures. NEVER PLACE WASTES DOWN ANY INDOOR
contact with skin.
OR OUTDOOR DRAIN OR SEWER.
ROUTES OF ENTRY
Primary: Skin Secondary: Ingestion Tertiary: Inhalation
SECTION 7. HANDLING AND STORAGE
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition in open flame will result in carbon dioxide and carbon monoxide. HAZARDS TO HUMANS AND DOMESTIC ANIMALS
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS Keep out of reach of children. CAUTION 鈥? Avoid breathing spray mist. Avoid contact with
Contents under pressure. Exposure to temperatures above 130掳F may cause bursting. eyes, skin or clothing. In case of contact flush eyes or skin with water. Wash thoroughly after
handling and before smoking or eating. Avoid contamination of food, utensils and food
preparation areas. Food should be removed or covered before treatment. All food contact
SECTION 4. FIRST AID MEASURES
surfaces and cooking utensils should be covered before treatment or thoroughly cleaned
Have the product container or label with you when calling a poison control center or doctor
before use. Remove pets and birds and cover aquariums before using.
or going for treatment. Describe any symptoms and follow the advice given.
USER SAFETY RECOMMENDATIONS
Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting
Users Should: Wash hands before eating, drinking, chewing gum, using tobacco or using the
unless told to do so by a poison control center or doctor. Do not give ANY liquid to the
toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on
person. Do not give anything by mouth to an unconscious person.
clean clothing. Remove PPE immediately after handling this product. Wash the outside of
Eye Contact: Hold eyes open and rinse slowly and gently with water for 15 - 20 min.
gloves before removing. As soon as possible, wash thoroughly and change into clean clothing.
Remove contact lenses, if present, after the first 5 min, then continue rinsing eyes. Call
OTHER PRECAUTIONS
a poison control center or doctor for treatment advice.
Do not use in greenhouses with unvented or defective gas heating systems or when open
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of
combustion exist. Do not remain in treated area.
water for 15 - 20 min. Call a poison control center or doctor for treatment advice.
PHYSICAL AND CHEMICAL HAZARDS
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambu-
Flammable - Contents under pressure. Do not puncture or incinerate container. Do not
lance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a
use or store near heat or open flame. Exposure to temperatures above 130掳F may cause
poison control center or doctor for further treatment advice.
bursting. Do not spray where electrical short circuits might result, such as wall outlets,
Note to Physician: Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia.
conduits, motors switches, etc. Do not spray directly into any electronic equipment such
Medical Conditions Generally Aggravated by Exposure: None known
as radios, televisions, computers, telephones, etc.
Emergency Telephone Number of Prosar: 800-225-3320 (for medical emergencies)
STORAGE
Do not contaminate water, food or feed. Store in a cool, dry place away from heat or open
flame and inaccessible to children. Do not store below 32掳F.
Page 1 of 2
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand 1600 X-clude庐 Timed Release Pyrethrum
SECTION 8. EXPOSURE CONTROL/PERSONAL PROTECTION SECTION 13. DISPOSAL CONSIDERATION
Do not contaminate water, food or feed by disposal of container or waste. Dispose of
PERSONAL PROTECTIVE EQUIPMENT (PPE)
container and waste in accordance with all federal, state and local regulations.
Respiratory Protection: None required for typical use exposure. See Section 6 for
Container Disposal: Do not puncture or incinerate! Empty container by using the
atypical exposure.
product according to the label directions. Offer empty container for recycling, if available,
Protective Gloves: Applicators and other handlers must wear chemical-resistant gloves
or place in trash if allowed by state and local regulations. If container is partly full,
(such as rubber or waterproof). (Good practice requires that gross amounts of any chemi-
contact your local solid waste agency for disposal instructions.
cal be removed from the skin as soon as practical, especially before eating or smoking.)
Waste Disposal: Wastes resulting from the use of this product may be disposed of on
Eye Protection: Use proper protection - safety glasses are recommended.
site or at an approved waste disposal facility.
Other Protective Equipment: Long-sleeved shirt, long pants and shoes plus socks
VENTILATION
SECTION 14. TRANSPORT INFORMATION
Local Exhaust: None required
Mechanical: None required SHIPMENT BY GROUND WITHIN U.S. (DOT CLASSIFICATION)
Special: None required Proper Shipping Description: Consumer Commodity, ORM-D
Other: Do not remain in treated area. Package Marking: Consumer Commodity, ORM-D
Package Labeling: None required
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Certified Packaging: None required
Product in unopened original packaging is compliant with all regulations for ground shipment within
Appearance: Beige-yellow liquid spray Odor: Characteristic Pyrethrin odor
the U.S. WMG disclaims any liability for claims or damages that may result from shipment by other
Solubility in Water: Disperses Vapor Pressure: NE
means. Packages offered or intended for other modes of transportation are subject to additional require-
Viscosity: NE Vapor Density: NE
ments. Consult an appropriately trained shipping professional before offering for shipment.
Boiling Point: NE Freezing/Melting Point: NE
Density: 0.995 g/cm3 @ 68掳F
pH: 6.0 - 7.0
SECTION 15. REGULATORY INFORMATION
SECTION 10. STABILITY AND REACTIVITY CERCLA
This product contains the CERCLA listed chemical Pyrethrins which has a reportable
REACTIVITY
quantity (RQ) of 1 lb.
Stability: Indefinite when stored and used according to label directions.
Conditions to Avoid: Do not spray into open flame or onto very hot sufaces. SARA TITLE III SECTION 311/312 HAZARD CLASS
Incompatibility (Material to Avoid): None known This product has been reviewed according to the EPA 鈥淗azard Categories鈥? promulgated under
Hazardous Polymerization: Will not occur Section 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA
Title III) and is considered, under applicable definitions, to meet the following categories:
HAZARDOUS DECOMPOSITION PRODUCTS
Immediate (Acute) Health Hazard
Thermal decomposition in open flame will result in carbon dioxide and carbon monoxide.
Fire Hazard
Release of Pressure (Puncture) Hazard
SECTION 11. TOXICOLOGICAL INFORMATION
SARA TITLE III SECTION 313 CHEMICALS
ROUTES OF ENTRY This product contains the following substances subject to the reporting requirements of
Primary: Skin Secondary: Ingestion Tertiary: Inhalation Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title III)
ACUTE and/or 40 CFR Part 372:
Eyes: Product may produce moderate conjunctival irritation, clearing in 7 days (rabbits). Piperonyl Butoxide, Technical (CAS #51-03-6) 2.2% by weight
Produced corneal opacity, clearing in 48 hr. No iritis was observed. TSCA
Skin: Product is not a skin irritant (rabbits). Acute dermal toxicity: LD50 > 2,000 mg/kg All components of this product are listed or excluded from listing on the US Toxic
(rabbits). Product is a dermal sensitizer when tested on guinea pigs. Substance Control Act (TSCA) Chemical Substance Inventory.
Ingestion: Acute oral toxicity LD50 > 5,000 mg/kg (rats).
Inhalation: Unlikely due to the product being pressurized and producing particles large
SECTION 16. OTHER INFORMATION
enough not to be respirable. A few cases of extrinsic asthma have been reported for
NFPA HEALTH RATING INFORMATION
pyrethrum. KEY: 4 = Severe
HEALTH - 1 FLAMMABILITY - 1 REACTIVITY - 1 3 = High
CHRONIC/CARCINOGENICITY
2 = Moderate
HMIS HAZARD RATING SYSTEM
Neither this product nor any of its ingredients are classified as carcinogens by the National
1 = Slight
HEALTH - 1 FLAMMABILITY - 1 REACTIVITY - 1
Toxicity Program (NTP), the International Agency for Research on Cancer (IARC) or the
0 = Minimal
Occupational Safety and Health Administration (OSHA).
SECTION 12. ECOLOGICAL INFORMATION
This product is toxic to fish, birds and other wildlife. Do not apply directly to water or to areas
where surface water is present, or to intertidal areas below the mean high water mark. Do not
contaminate water by cleaning of equipment or disposal of waste.
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with
respect to the information contained herein.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable Effective Date: 04/28/08
NE - Not Established Review Date: 04/28/08
WHITMIRE MICRO-GEN
PEL - Permissible Exposure Limit Supersedes: 05/25/05
RESEARCH LABORATORIES, INC.
TLV - Threshold Limit Value Text ID: 080716-4
STEL - Short Term Exposure Limit (15 min) Code #: 214-099
TWA - Time Weighted Average (8 hr) Part No. 19-0767-03
Page 2 of 2
|