Part No.: 19-0075-05
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand Attain庐 TR Micro Total Release Insecticide
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (Prosar) TRANSPORTATION: 800-424-9300 (Chemtrec)
IN CASE OF FIRE
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Extinguisher Media: Carbon Dioxide, Dry Chemical, Foam
Product Name: Prescription Treatment brand Attain TR
庐 庐
Special Fire Fighting Procedures: Fire fighting personnel should wear full protective equip-
Micro Total Release Insecticide ment and positive pressure self-contained breathing apparatus (SCBA) approved for firefighting.
EPA Reg. No.: 499-472
SECTION 6. ACCIDENTAL RELEASE MEASURES
Product Code: 09-1820 (12 x 2 oz)
EPA Signal Word: WARNING IN CASE OF SPILL OR LEAK
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc. If container begins to leak (through puncture, etc.), eliminate all ignition sources and allow to
3568 Tree Court Industrial Blvd. discharge completely in well ventilated area, then dispose of as directed below.
St. Louis MO 63122-6682 This product contains no Comprehensive Environmental Response, Compensation and
Liability Act (CERCLA) listed chemicals. Releases of this product are NOT reportable to the
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS National Response Center.
COMPOSITION INFORMATION Emergency Telephone Number of Chemtrec: 800-424-9300 (for transportation spills)
ACTIVE INGREDIENT (4.0%) % CAS NO. PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
Bifenthrin 4.0 82657-04-3 Eyes: Wear protective eyewear such as goggles or face shield.
OTHER INGREDIENTS* (96.0%) % CAS NO. Skin: Wear chemical-resistant gloves. Also wear long-sleeved shirt, long pants and shoes
plus socks. (Good practice requires that gross amounts of any chemical be removed from the
2-propanol proprietary 67-63-0
skin as soon as practical, especially before eating or smoking.)
N-Methylpyrrolidone 6.0 872-50-4
Inhalation: Use of a respirator may be appropriate when working with spills in enclosed or
Hydrocarbons C3-C4 proprietary 68476-40-4
confined spaces, or when prolonged exposure to product vapor or spray mist may occur. When
* All ingredients may not be listed. Ingredients not listed do not meet the reporting requirements of the OSHA
using a respirator, wear a NIOSH approved respirator with an organic vapor (OV) cartridge or
Hazard Communication Standard (HCS) as specified in 29 CFR 1910.1200.
canister with any R or P prefilter. See 29 CFR 1910.134 for respiratory protection, training and
EXPOSURE INFORMATION
testing requirements.
OSHA PEL ACGIH TLV
WASTE DISPOSAL METHOD
MATERIAL STEL TWA STEL TWA
Do not contaminate water, food or feed by storage or disposal of wastes. Take full or leaking
Bifenthrin NE NE NE NE
containers to a local disposal company for biological treatment or incineration. Review all local,
2-propanol NE 400 ppm 500 ppm 400 ppm
state and federal regulations concerning health and pollution to determine approved disposal
N-Methylpyrrolidone NE NE NE NE
procedures. NEVER PLACE WASTES DOWN ANY INDOOR OR OUTDOOR DRAIN OR SEWER.
Hydrocarbons C3-C4 NE NE NE 1,000 ppm
SECTION 7. HANDLING AND STORAGE
SECTION 3. HAZARDS IDENTIFICATION
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
SIGNS/SYMPTOMS OF EXPOSURE
Keep out of reach of children. WARNING 鈥? Causes substantial but temporary eye injury. Do not
Product causes substantial but temporary eye irritation. Prolonged or frequently repeated skin
get in eyes or on clothing. Wear goggles or face shield while handling. Harmful if swallowed.
contact may cause allergic reaction in some individuals.
Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash
ROUTES OF ENTRY
clothing before reuse. Prolonged or frequently repeated skin contact may cause allergic reactions
Primary: Inhalation Secondary: Skin Tertiary: Ingestion
in some individuals.
HAZARDOUS DECOMPOSITION PRODUCTS
USER SAFETY RECOMMENDATIONS
Thermal decomposition in open flame may result in carbon monoxide, carbon dioxide,
Users Should: Wash hands before eating, drinking, chewing gum, using tobacco or using the
hydrochloric acid, nitrogen oxide fumes and hydrofluoric acid.
toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
clean clothing. Remove PPE immediately after handling this product. Wash the outside of
Contents under pressure. Exposure to temperatures above 130掳F may cause bursting.
gloves before removing. As soon as possible, wash thoroughly and change into clean clothing.
OTHER PRECAUTIONS
SECTION 4. FIRST AID MEASURES Do not use this product in greenhouses with unvented or defective gas heating systems or
Have the product container or label with you when calling a poison control center or doctor or when open combustion exists. Do not place within 10 horizontal feet of any ignition source
going for treatment. Describe any symptoms and follow the advice given. such as pilot lights, other open flames or running electrical appliances that cycle off and on.
Eye Contact: Hold eyes open and rinse slowly and gently with water for 15 - 20 min. Remove All human occupants and pets must be removed before treatment. Greenhouse must be
contact lenses, if present, after the first 5 min, then continue rinsing eyes. Call a poison ventilated according to the requirements of the Worker Protection Standard before reentry.
control center or doctor for treatment advice. PHYSICAL AND CHEMICAL HAZARDS
Ingestion: Call a poison control center or doctor immediately for treatment advice. Have Extremely Flammable - Contents under pressure. Keep away from fire, sparks and heated
person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by surfaces. Do not puncture or incinerate container. Exposure to temperatures above 130掳F may
the poison control center or doctor. Do not give anything by mouth to an unconscious person. cause bursting. This product contains a highly flammable ingredient. It may cause a fire or
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, explosion if not used properly. Follow the 鈥淒irections for Use鈥? on the label very carefully.
then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison STORAGE
control center or doctor for further treatment advice. Do not contaminate water, food or feed. Store in a cool, dry area away from heat or open flame
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for and inaccessible to children.
15 - 20 min. Call a poison control center or doctor for treatment advice.
Note to Physician: None SECTION 8. EXPOSURE CONTROL/PERSONAL PROTECTION
Medical Conditions Generally Aggravated by Exposure: None known
Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hr.
Emergency Telephone Number of Prosar: 800-225-3320 (for medical emergencies)
PERSONAL PROTECTIVE EQUIPMENT (PPE)
Respiratory Protection: For prolonged exposure or if used in enclosed or confined areas,
SECTION 5. FIRE FIGHTING MEASURES a NIOSH approved respirator with an organic vapor (OV) cartridge or canister with any R
FIRE AND EXPLOSION or P prefilter may be used. See 29 CFR 1910.134 for respiratory protection, training and
Flash Point (TCC): < 20掳F testing requirements.
Flame Projection: > 18鈥? Protective Gloves: Chemical-resistant gloves are recommended if skin contact is likely.
Explosibility Limits of Propellant in Air (% by volume): (Good practice requires that gross amounts of any chemical be removed from the skin as soon
Lower (LEL) = 1.8% Upper (UEL) = 9.5% as practical, especially before eating or smoking.)
NFPA 30B Flammability: Level 3 Aerosol Eye Protection: Wear protective eyewear such as goggles or face shield.
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS Other Protective Equipment: Long-sleeved shirt, long pants, shoes plus socks
Contents under pressure. Exposure to temperatures above 130掳F may cause bursting.
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MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand Attain庐 TR Micro Total Release Insecticide
Restricted Entry Interval (REI): PPE required for early entry to treated areas that is
SECTION 13. DISPOSAL CONSIDERATION
permitted under the Worker Protection Standard and that involve contact with anything that has
Do not contaminate water, food or feed by disposal of container or waste. Dispose of container and
been treated, such as plants, soil or water, is: Coveralls, waterproof gloves, shoes plus socks
waste in accordance with all federal, state and local regulations.
and protective eyewear.
Container Disposal: Do not puncture or incinerate! Empty container by using the product
VENTILATION
according to the label directions. Offer empty container for recycling, if available, or place in
Local Exhaust: None required
trash if allowed by state and local regulations. If container is partly full, contact your local solid
Mechanical: None required
waste agency for disposal instructions.
Special: None required
Waste Disposal: Wastes resulting from the use of this product may be disposed of on site
Other: Ventilate greenhouse according to the requirements of the Worker Protection Standard
or at an approved waste disposal facility.
before reentry.
SECTION 14. TRANSPORT INFORMATION
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
SHIPMENT BY GROUND WITHIN U.S. (DOT CLASSIFICATION)
Appearance and Odor: Sprays as a clear liquid Odor: Characteristic solvent odor
Proper Shipping Description: Consumer Commodity, ORM-D
Solubility in Water: Slight Vapor Pressure: NE
Package Marking: Consumer Commodity, ORM-D
Viscosity: 2.25 cps at 77掳F Vapor Density: NE
Package Labeling: None required
Boiling Point: NE Freezing/Melting Point: NE
Certified Packaging: Not required
pH: 9.87 at 77掳F (1% in water) Specific Gravity: 0.8430 g/cm3 @ 68掳F
Product in unopened original packaging is compliant with all regulations for ground shipment with-
in the U.S. WMG disclaims any liability for claims or damages that may result from shipment by other
SECTION 10. STABILITY AND REACTIVITY
means. Packages offered or intended for other modes of transportation are subject to additional
REACTIVITY
requirements. Consult an appropriately trained Shipping Professional before offering for shipment.
Stability: Indefinite when used according to label directions.
Conditions to Avoid: Heat, sparks and open flame
SECTION 15. REGULATORY INFORMATION
Incompatibility (Materials to Avoid): Strong oxidizing agents, strong acids, aldehydes,
CERCLA
amines, chlorinated compounds
This product contains no CERCLA listed chemicals.
Hazardous Polymerization: Will not occur
SARA TITLE III SECTION 311/312 HAZARD CLASS
HAZARDOUS DECOMPOSITION PRODUCTS
This product has been reviewed according to the EPA 鈥淗azard Categories鈥? promulgated under
Thermal decomposition in open flame may result in carbon monoxide, carbon dioxide,
Section 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA
hydrochloric acid, nitrogen oxide fumes and hydrofluoric acid.
Title III) and is considered, under applicable definitions, to meet the following categories:
Immediate (Acute) Health Hazard
SECTION 11. TOXICOLOGICAL INFORMATION
Fire Hazard
ROUTES OF ENTRY
Release of Pressure (Puncture) Hazard
Primary: Inhalation Secondary: Skin Tertiary: Ingestion
SARA TITLE III SECTION 313 CHEMICALS
ACUTE
This product contains the following substances subject to the reporting requirements of Title
Eyes: Product causes moderate, but reversible eye irritation. Produced moderate conjunctival
III of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) and/or
irritation, clearing in 14 days (rabbits). Corneal opacity was observed, clearing in 17 days
40 CFR Part 372:
(rabbits). No iritis was observed.
Bifenthrin (CAS #82657-04-3) 4.0% by weight
Skin: Prolonged exposure may cause skin irritation. Acute dermal toxicity: LD50 > 5,000 mg/kg
N-Methylpyrrolidone (CAS #872-50-4) 6.0% by weight
(rabbits). Primary skin irritation Index = 0.1 (rabbits). Product is a dermal sensitizer when
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROP 65)
tested on guinea pigs.
This product contains N-Methylpyrrolidone, a chemical known by the state of California to be
Ingestion: Acute oral toxicity: LD50 > 1,300 mg/kg (rats).
a reproductive hazard.
Inhalation: Unlikely due to the product being pressurized and producing particles large
TSCA
enough not to be respirable. Acute inhalation toxicity: LC50 > 3.1 mg/L (rats).
All components of this product are listed or excluded from listing on the US Toxic Substance
CHRONIC/CARCINOGENICITY
Control Act (TSCA) Chemical Substance Inventory.
Neither this product nor any of its ingredients are classified as carcinogens by the National
Toxicity Program (NTP), the International Agency for Research on Cancer (IARC) or the
SECTION 16. OTHER INFORMATION
Occupational Safety and Health Administration (OSHA).
REPRODUCTIVE TOXICITY NFPA HEALTH RATING INFORMATION KEY: 4 = Severe
This product contains N-Methylpyrrolidone, a chemical known by the state of California to be HEALTH - 1 FLAMMABILITY - 4 REACTIVITY - 1 3 = High
a reproductive hazard. 2 = Moderate
HMIS HAZARD RATING SYSTEM 1 = Slight
SECTION 12. ECOLOGICAL INFORMATION HEALTH - 1 FLAMMABILITY - 4 REACTIVITY - 1 0 = Minimal
This product is highly toxic to fish and aquatic invertebrates. Keep out of lakes, streams or ponds.
Do not contaminate water when disposing of equipment wash waters. Apply this product only as
specified on the label.
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with
respect to the information contained herein.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable Effective Date: 04/30/08
NE - Not Established Review Date: 04/30/08
WHITMIRE MICRO-GEN
PEL - Permissible Exposure Limit Supersedes: 09/15/05
RESEARCH LABORATORIES, INC.
TLV - Threshold Limit Value Text ID #: 080626-5
STEL - Short Term Exposure Limit (15 min) Code #: 209-078
TWA - Time Weighted Average (8 hr) WMG Part No.: 19-0075-05
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